• 原料直供
• 试剂商城
• 直接询价

分类

• {SNA} Analytical Reagents for General Use, Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, E-H, Puriss p.a., Esters, Organic Building Blocks, Puriss p.a., 分析/色谱, 分析试剂
• {SNA} Alphabetical L
• {SNA} Analytical Reagents, Analytical Reagents for General Use, Analytical/Chromatography, Building Blocks, C6 to C7, Carbonyl Compounds, Chemical Synthesis, E-H, Puriss p.a., Esters, Organic Building Blocks, Puriss p.a.
• {uni_hamburg} no charge; ester; ketone; 1fragment
• {SNA} Alphabetical Listings,
• {SNA} Building Blocks, C6 to C7, Carbonyl Compounds,
• {SNA} Building Blo
• {SNA}

产品应用

• 溶剂。有机合成。检定铊。测定氧化钙、氢氧化钙和铜。测定高铁的络合指示剂。气相色谱固定液(最高使用混度50℃,溶剂为丙酮),分离分析低级烃异构物,分离正、异-1-丁烯和顺、反-2-丁烯。

相关文献及参考

• Merck: 14,3758
• Many techniques have been devised for the decarboalkoxylation of substituted ß-ketoesters (compare Diethyl­ malonate, A15468); for reviews, see: Synthesis, 805, 893 (1982). Enolisable ß-keto esters can be decarboalkoxylated by heating in toluene in the presence of a catalytic amount of DMAP. Other bases are ineffective: J. Org. Chem., 54, 3474 (1989).
• Merck: 14,3758 Beilstein:3(4)1528
• Under the conditions of the classical acetoacetic ester route to methyl ketones [see, e.g.: Org. Synth. Coll., 1, 248, 351 (1941)], varying amounts of O-alkylation occur. Regioselective C-alkylation can be obtained by phase-transfer procedures: J. Org. Chem., 39, 3271 (1974). For improved alkylation using TBAB, see: Org. Prep. Proced. Int., 26, 469 (1994).
• Short: II/27B
• For use in diazo transfer reactions, see 4-Acetamidobenzenesulfonyl­ azide, L15916.

安全信息

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >20 mL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 3/12/1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 5105 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPMSAE Journal of Pharmaceutical Sciences.  (American Pharmaceutical Assoc.,
   2215 Constitution Ave., NW, Washington, DC 20037)  V.50-    1961-
   Volume(issue)/page/year: 60,1810,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3980 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 31,60,1949

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 21 mg/disc
REFERENCE :
   OIGZDE Osaka-shi Igakkai Zasshi.  Journal of Osaka City Medical Association.
    (Osaka-shi Igakkai, c/o Osaka-shiritsu Daigaku Igakubu, 1-4-54 Asahi-cho,
   Abeno-ku, Osaka, 545, Japan) V.24-    1975- Volume(issue)/page/year:
   34,267,1985

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 200 ug/plate
REFERENCE :
   OIGZDE Osaka-shi Igakkai Zasshi.  Journal of Osaka City Medical Association.
    (Osaka-shi Igakkai, c/o Osaka-shiritsu Daigaku Igakubu, 1-4-54 Asahi-cho,
   Abeno-ku, Osaka, 545, Japan) V.24-    1975- Volume(issue)/page/year:
   34,267,1985

其他信息

• 图谱信息:乙酰乙酸乙酯(141-97-9)红外图谱(IR1) 乙酰乙酸乙酯(141-97-9)Raman光谱 乙酰乙酸乙酯(141-97-9)质谱(MS) 乙酰乙酸乙酯(141-97-9)红外图谱(IR2) 乙酰乙酸乙酯(141-97-9)核磁图( 1 HNMR) 乙酰乙酸乙酯(141-97-9)核磁图( 13 CNMR)