tert-Butyl ethyl ether 叔丁基乙基醚

CAS 637-92-3 MFCD00009225

化学结构图

637-92-3
SMILES: CCOC(C)(C)C

化学属性

Mol. Formula(CH3)3COCH2CH3
Mol. Weight102
Refractive index1.3740 to 1.3770
Boiling Point70°C
Density0.742
Melting Point-97
Flash Point-19°C(lit.)
TSCAYes
Vapor Pressure155 mmHg ( 25 °C)

别名和识别编码

Chemical Nametert-Butyl ethyl ether
CAS Number637-92-3
PubChem Substance ID12512
EC Number211-309-7
Beilstein Registry Number1,381
MDL NumberMFCD00009225
Reaxys-RN1731469
Merck Number3774
Synonym (CH3)3CO(CH2CH3) 1,1-Dimethylethyl ethyl ether 1,1-dimethylethylethylether 2-Ethoxy-2-methylpropane 2-ethoxy-2-methyl-propan 2-ethoxy-2-methyl-propane 2-ethoxy-2-methylpropane 2-methyl-2-ethoxypropane tert-Butyl ethyl ether tert-Butylethylether tert.-Butyl-ethylether ETBE ETHYL TERTIARY BUTYL ETHER ETHYL-TERT-BUTYL ETHER Ether, tert-butyl ethyl Ether, tert-butyl ethyl Ethyl 1,1-dimethylethyl ether Ethyl tert-butyl ether Ethyl tert-butyl oxide Ethyl tert-butyl ether Ethyl tert-butyl oxide Ethyl-tert.-butylether Propane, Propane, 2-ethoxy-2-methyl-
Chemical Name Translation叔丁基乙基醚
LabNetwork Molecule IDLN00225712
InChIInChI=1S/C6H14O/c1-5-7-6(2,3)4/h5H2,1-4H3
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分类

  • {uni_hamburg} no charge; ether; 1fragment
  • {SA} Building Blocks, C2 to C7, Chemical Synthesis, Ethers, Organic Building Blocks, Oxygen Compounds
  • {SNA} Alphabetical Index of Analytical Standards, A-B, Alpha Sort, Analytical Standards, Analytical/Chromatography, B, BI - BZ, Chromatography, Environmental Standards, Volatiles/ Semivolatiles
  • Building Blocks, C2 to C8, Chemical Synthesis, Ethers, Organic Building Blocks, Oxygen Compounds

相关文献及参考

  • Merck: 14,3774 Beilstein:1,381
  • Short: II/24B
  • Merck: 14,3774
  • Short: II/2

安全信息

GHS Symbol
WGK Germany1
Hazard Codes F
Hazard statements
  • H224 Extremely flammable liquid and vapour 极端易燃液体和蒸气
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H331 Toxic if inhaled 吸入中毒
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSKN4730200
Precautionary statements
  • P203
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P318
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S37 Wear suitable gloves 戴适当手套；
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
UN Number 1179
Packing GroupII
Hazard Class3
Storage condition Flammables area 
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 123 gm/m3/15M
TOXIC EFFECTS :
   Behavioral - general anesthetic
REFERENCE :
   ANESAV Anesthesiology.  (Lippincott/Harper, Journal Fulfillment Dept., 2350
   Virginia Ave., Hagerstown, MD 21740)  V.1-    1940- Volume(issue)/page/year:
   11,455,1950

其他信息

  • 图谱信息:叔丁基乙醚(637-92-3)红外图谱(IR1) 叔丁基乙醚(637-92-3)核磁图( 13 CNMR) 叔丁基乙醚(637-92-3)质谱(MS) 叔丁基乙醚(637-92-3)核磁图( 1 HNMR)
  • MOL 文件:637-92-3.mol
  • Acros Organics:乙基叔丁基醚 tert-Butyl ethyl ether, 97%(637-92-3)
  • F:23
  • 叔丁基乙醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1542 叔丁基乙醚 tert-Butyl Ethyl Ether 25ML 403元 2011/04/16 B1542 叔丁基乙醚 tert-Butyl Ethyl Ether 500ML 1510元 2010/06/21 403530250 叔丁基乙醚 tert-Butyl ethyl ether 97% 25 GR 2084元
  • Alfa Aesar:叔丁基乙醚,99% tert-Butyl ethyl ether, 99%(637-92-3)
  • 用途一:用于分析检测标准品。
  • TCI Shanghai:叔丁基乙醚 tert-Butyl Ethyl Ether,>;95.0%(GC)(637-92-3)
  • 蒸气压:155 mm Hg ( 25 °C)
  • 外观性质:无色透明液体，水中溶解度:1.2 g/100mL (20°C)密度:0.75熔点:-94℃沸点:70℃折光率:1.3750闪点:-19℃
  • Sigma Aldrich:637-92-3(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  6. C2 to C8 - Ethers
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Volatiles/ Semivolatiles - Environmental Standards
  6. Alpha Sort - Volatiles/ Semivolatiles
  7. A-B - Alpha Sort
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. B - Alphabetic
  5. BI - BZ - B
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Epoxides

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