Diethyl Phenyl Orthoformate 原甲酸二乙基苯酯

CAS 14444-77-0 MFCD00009228

化学结构图

14444-77-0
SMILES: CCOC(OC1C=CC=CC=1)OCC

化学属性

Mol. FormulaC11H16O3
Mol. Weight196
Density1.014 g/mL at 25 °C(lit.)
Refractive index1.4780 to 1.4820
Boiling Point104°C/9.8mmHg
Flash Point65°C(lit.)
TSCANo
Melting Point-26°

别名和识别编码

Chemical NameDiethyl Phenyl Orthoformate
Synonym Diethoxy-phenoxymethan Orthoameisensäure-diethyl-phenylester Orthoformic acid diethyl phenyl ester Orthoameisensäurediethylphenylester Orthoameisensäurediethyl-phenylester {uni_hamburg} diethyl phenyl orthoformate (diethoxymethoxy)benzene 二乙基苯基甲烷 diethoxymethoxy-benzene Benzene, (diethoxymethoxy)- Diethyl-phenylorthoformiat orthoformic acid diethyl ester-phenyl ester
MDL NumberMFCD00009228
Beilstein Registry Number1872634
EC Number238-421-9
CAS Number14444-77-0
PubChem Substance ID87574186
Chemical Name Translation原甲酸二乙基苯酯
Reaxys-RN1872634
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; orthoester; 1fragment
  • {SNA} Acetals/Ketals/Ortho Esters, Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds

相关文献及参考

  • Reacts with Grignard reagents to give aldehyde acetals in good yield: Chem. Ber., 103, 643 (1970). For application to acetylenic Grignards, see: J. Org. Chem., 49, 2031 (1984).
  • Short: EINECS
  • Short: III/38B

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P332+P313
  • P370+P378
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word Warning
Risk Statements
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Moisture Sensitive
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Hazard Codes Xi
Packing GroupIII

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Acetals/Ketals/Ortho Esters - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Orthoesters
  1. Functional Group 官能团索引
  2. orthocarboxylic acid derivative
  1. Functional Group 官能团索引
  2. orthoester

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