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• 试剂商城
• 直接询价

分类

• {SNA} Chemical Synthesis, Monomers, Others, Polymer Science, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents, Vinyl Ethers, 材料科学
• {SNA} Chemical Synthesis, Other Protecting and Derivatizing Reagents, Protecting and Derivatiz
• {SA} Chemical Synthesis, Materials Science, Monomers, Others, Polymer Science, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents, Vinyl Ethers
• {SNA} Chemical Synthesis, Others, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents
• {uni_hamburg} no charge; ether; 1fragment

产品应用

• A useful vinyl ether for proteomics research and organic synthesis.

相关文献及参考

• Short: II/24C
• In the presence of Montmorillonite K10, an addition reaction with diethyl acetals gives the ß-ethoxy acetal of the bis-homologated aldehyde, providing, on acid cleavage, an effective route to the corresponding ɑß-unsaturated aldehyde: Synthesis, 137 (1981).
• Short: II/14a
• Also used in the protection of phenols as EE ethers which can be cleaved by acid-catalyzed methanolysis: J. Am. Chem. Soc., 119, 8071 (1997).
• Beilstein:1,433
• Short: II/24B
• Acid-catalyzed reaction with alcohols gives 1-ethoxyethyl (EE) ethers, useful as protected derivatives, e.g. in reactions with organometallics. Possible catalysts include: tosic acid: J. Am. Chem. Soc., 101, 7104 (1979); Org. Synth., 76, 199 (1998), PPTS: Tetrahedron Lett., 28, 4303 (1987), or dichloroacetic acid: J. Org. Chem., 37, 1947 (1972). Cleavage of this mixed acetal occurs in dilute acid, more readily than THP ether (see 3,4-Dihydro-2H-pyran, L02731). Protection of cyanohydrins allows use as acyl anion equivalents: Org. Synth. Coll., 7, 381 (1990):

安全信息

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 8160 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >20 mL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 11/15/1971

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 16000 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 31,343,1949

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 324 gm/m3/15M
TOXIC EFFECTS :
   Behavioral - general anesthetic
REFERENCE :
   ANESAV Anesthesiology.  (Lippincott/Harper, Journal Fulfillment Dept., 2350
   Virginia Ave., Hagerstown, MD 21740)  V.1-    1940- Volume(issue)/page/year:
   11,455,1950

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        :

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 17900 ppm
REFERENCE :
   ANESAV Anesthesiology.  (Lippincott/Harper, Journal Fulfillment Dept., 2350
   Virginia Ave., Hagerstown, MD 21740)  V.1-    1940- Volume(issue)/page/year:
   50,426,1979

其他信息

• 乙烯基乙醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 E0193 乙烯基乙醚(含稳定剂氢氧化钾) Ethyl Vinyl Ether (stabilized with KOH) 50
• 下游产品:(1-甲基-3-三氟甲基-1H-吡唑-4-基)甲胺 --> 1-甲基-3-三氟甲基-1H-吡唑-4-羧酸 --> 1-苯基-3-三氟甲基-1H-吡唑-5-羧酸 --> 3-溴-7-(三氟甲基)咪唑并[1,2-a]嘧啶 --> (1-叔丁基-3-三氟甲基-1H-吡唑-4-基)甲醇 --> (1-甲基-3-三氟甲基-1H-吡唑-4-基)甲醇 --> 1-甲基-3-三氟甲基-1H-吡唑-4-胺 --> 1-叔丁基-3-三氟甲基-1H-吡唑-4-胺 --> 1-甲基-3-三氟甲基-1H-吡唑-4-羧酸乙酯 --> 1-叔丁基-3-三氟甲基-1H-吡唑-4-羧酸乙酯 --> 1-苯基-3-三氟甲基-4-溴-1H-吡唑 --> 1-叔丁基-3-三氟甲基-1H-吡唑-4-羧酸 --> 2-肼基-4-三氟甲基嘧啶 --> 1-苯基-3-三氟甲基吡唑 --> 2-甲基-5-三氟甲基-2H-吡唑-3-羧酸 --> 2-氯-4-三氟甲基嘧啶 --> 米力农 --> 1-叔丁基-3-三氟甲基-1H-吡唑-5-羧酸 --> 1-苯基-5-三氟甲基-1H-吡唑-4-醛 --> 1-甲基-3-三氟甲基-4-溴-1H-吡唑 --> 磺胺嘧啶 --> 1-叔丁基-3-三氟甲基-4-溴-1H-吡唑 --> 戊二醛 --> 3-氯-5-氟苯胺 --> 1-甲基-3-三氟甲基-1H-吡唑 --> 1-苯基-5-三氟甲基-4-溴-1H-吡唑 --> 1-甲基
• TCI Shanghai:乙烯基乙醚(含
• {
• 检测方法:GC
• 海关编码:29091900
• 乙烯基乙醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 E0193 乙烯基乙醚(含稳定剂氢氧化钾) Ethyl Vinyl Ether (stabilized with KOH) 500ML 550元 2014/06/02 E0193 乙烯基乙醚(含稳定剂氢氧化钾) Ethyl Vinyl Ether (s
• MOL 文件:109-92-2.mol
• Sigma Aldrich:109-92-2(sigma
• {Chemica
• 刺激数据:皮肤- 兔子 500 毫克 轻度
• MSDS 信息:乙烯基乙醚(109-92-2).msds
• Acros Organics:乙烯基乙基醚 Ethyl vinyl ether, stabi
• 爆炸物危险特性:与空气混合可爆
• 类别:易燃液体
• 图谱信息:乙烯基乙醚(109-92-2)Raman光谱 乙烯基乙醚(109-92-2)红外图谱(IR2) 乙烯基乙醚(109-92-2)核磁图( 13 CNMR) 乙烯基乙醚(109-92-2)质谱(MS) 乙烯基乙醚(109-92-2)核磁图( 1 HNMR) 乙烯基乙醚(109-92-2)红外图谱(IR1)
• 用途一:医药上用作麻醉剂、镇痛剂，也用作精细化学品的中间体
• 用途一
• 可燃性危险特
• 方法一:由电石发生乙炔，乙炔再与乙醇在氢氧化钾催化剂存在下，经加压反应制得。
• 乙烯基乙醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 E0193 乙烯基乙醚(含稳定剂氢氧化钾) Ethyl Vinyl Ether (stabilized with KOH) 500ML 550元 2014/06/02 E0193 乙烯基乙醚(含稳定剂氢氧化钾) Ethyl Vinyl Ether (stabilized with KOH) 25ML 175元 2010/06/21 119080010 乙烯基乙醚 Ethyl vinyl ether 99%, stabilized 1 LT 671元
• 图谱信息:乙烯基乙醚(109-92-2)Raman光谱 乙烯基乙