Aluminum sec-butoxide 仲丁醇铝

CAS 2269-22-9 MFCD00009327

化学结构图

2269-22-9
SMILES: CCC(C)O.[AlH6]

化学属性

Mol. FormulaC12H27AlO3
Mol. Weight246.33
Density0.96
Boiling Point200-206
Refractive index1.4390
Flash Point26°C(lit.)
SolubilityHydrolyzes in water. Soluble in aromatic hydrocarbons, alcohols
TSCAYes
Autoignition Point763 °F
Stability易吸潮
Appearance colorless to light amber liq.

别名和识别编码

Chemical NameAluminium Tri-Sec-Butoxide
MDL NumberMFCD00009327
PubChem Substance ID61289
Synonym Aluminum-tri-sec-butoxide {LY} Aluminum-tri-sec-butoxide sec-butyl alcohol {} {LY} Aluminum-tri-sec-butoxide {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {} {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {} {} {}
CAS Number2269-22-9
EC Number218-871-2
Beilstein Registry Number3910908
Reaxys-RN3910908
Chemical Name Translation仲丁醇铝
LabNetwork Molecule IDLN01739880
InChIInChI=1S/3C4H9O.Al/c3*1-3-4(2)5;/h3*4H,3H2,1-2H3;/q3*-1;+3
Canonical SMILESCCC(C)[O-].[Al+3].[3]
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分类

  • {SNA} Aluminum, Micro/NanoElectronics, Solution Deposition Precursors, 材料科学
  • {SNA} Aluminum, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors
  • Aluminum, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors
  • {uni_hamburg} no charge; 1fragment

产品应用

  • 用作活性催化剂及载体，无机膜、醛-酮的还原剂、醛-酮的氧化剂，油墨油漆的胶凝剂，织物防水剂，铝复合润滑脂等。

相关文献及参考

  • Short: EINECS
  • Short: IV/20B
  • Beilstein: 1,IV,1569

安全信息

WGK Germany3
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312
  • P301+P312+P330
  • P301+P317
  • P302+P352
  • P302+P352+P312+P361+P364
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P317
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P361+P364
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H312 Harmful in contact with skin 皮肤接触有害
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H351 Suspected of causing cancer 怀疑致癌
Hazard Codes
GHS Symbol
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
UN Number 1992
Risk Statements
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Flammables area Moisture Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nit
Packing GroupIII
Hazard Class3/6.1

其他信息

  • 海关编码:29051900
  • MOL 文件:2269-22-9.mol
  • Acros Organics:仲丁醇铝 Aluminium tri-sec-butoxide, 97%(2269-22-9)
  • 见水分解。无色或淡黄色粘稠液体，易溶于乙醇、异丙醇、甲苯等，易燃、易吸湿，遇水分解成氢氧化铝和仲丁醇
  • MSDS 信息:Aluminium tri-sec-butoxide(2269-22-9).msds
  • 外观性质:见水分解。无色或淡黄色粘稠液体，易溶于乙醇、异丙醇、甲苯等，易燃、易吸湿，遇水分解成氢氧化铝和仲丁醇沸点: 200-206℃闪点: 27℃密度: 0.9671 沸点: 200-206℃折光率:1.4390
  • 用途一:用作活性催化剂及载体，无机膜、醛-酮的还原剂、醛-酮的氧化剂，油墨油漆的胶凝剂，织物防水剂，铝复合润滑脂等。
  • TCI Shanghai:仲丁醇铝 Aluminum sec-Butoxide,>;98.0%(T)(2269-22-9)
  • 图谱信息:仲丁醇铝(2269-22-9)核磁图( 13 CNMR) 仲丁醇铝(2269-22-9)红外图谱(IR1) 仲丁醇铝(2269-22-9)质谱(MS)
  • 仲丁醇铝价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0244 仲丁醇铝 Aluminum sec-Butoxide 25G 158元 2014/06/02 A0244 仲丁醇铝 Aluminum sec-Butoxide 500G 690元 2010/06/21 191210050 仲丁醇铝 Aluminium tri-sec-butoxide 97% 5 GR 237元
  • Sigma Aldrich:2269-22-9(sigmaaldrich)
  • F:3-10-23
  • 敏感性:Moisture Sensitive
  • Alfa Aesar:仲丁氧基铝,97% Aluminum sec-butoxide, 97%(2269-22-9)
  • TSCA:Yes

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. ACS - Analytical Reagents for General Use
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Lewis Acids 路易斯酸
  4. Aluminum - Lewis Acids
  1. Materials Science 材料科学
  2. Micro/NanoElectronics - Materials Science
  3. Solution Deposition Precursors - Micro/NanoElectronics
  4. Aluminum - Solution Deposition Precursors
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organoaluminum
  1. Alkoxide
  2. Aluminum
  1. CVD & ALD Precursors
  2. Aluminum
  1. Metal Alkoxides for CVD & ALD
  2. Aluminum
  1. CVD & ALD Precursors
  2. Aluminum
  1. Metal Alkoxides for CVD & ALD
  2. Aluminum

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