Aluminum sec-butoxide 仲丁醇铝

CAS 2269-22-9 MFCD00009327

化学结构图

2269-22-9
SMILES: CCC(C)O.[AlH6]

化学属性

Mol. FormulaC12H27AlO3
Mol. Weight246.33
Density0.96
Boiling Point200-206
Refractive index1.4390
Flash Point26°C(lit.)
SolubilityHydrolyzes in water. Soluble in aromatic hydrocarbons, alcohols
TSCAYes
Autoignition Point763 °F
Stability易吸潮
Appearance colorless to light amber liq.

别名和识别编码

Chemical NameAluminium Tri-Sec-Butoxide
MDL NumberMFCD00009327
PubChem Substance ID61289
Synonym Aluminum-tri-sec-butoxide {LY} Aluminum-tri-sec-butoxide sec-butyl alcohol {} {LY} Aluminum-tri-sec-butoxide {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {} {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Aluminum-tri-sec-butoxide {} {} {} {} {} {} {} {}
CAS Number2269-22-9
EC Number218-871-2
Beilstein Registry Number3910908
Reaxys-RN3910908
Chemical Name Translation仲丁醇铝
LabNetwork Molecule IDLN01739880
InChIInChI=1S/3C4H9O.Al/c3*1-3-4(2)5;/h3*4H,3H2,1-2H3;/q3*-1;+3
Canonical SMILESCCC(C)[O-].[Al+3].[3]
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分类

  • {SNA} Aluminum, Micro/NanoElectronics, Solution Deposition Precursors, 材料科学
  • {SNA} Aluminum, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors
  • Aluminum, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors
  • {uni_hamburg} no charge; 1fragment

产品应用

  • 用作活性催化剂及载体,无机膜、醛-酮的还原剂、醛-酮的氧化剂,油墨油漆的胶凝剂,织物防水剂,铝复合润滑脂等。

相关文献及参考

  • Short: EINECS
  • Short: IV/20B
  • Beilstein: 1,IV,1569

安全信息

WGK Germany3
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312
  • P301+P312+P330
  • P301+P317
  • P302+P352
  • P302+P352+P312+P361+P364
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P317
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P361+P364
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H312 Harmful in contact with skin 皮肤接触有害
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H351 Suspected of causing cancer 怀疑致癌
Hazard Codes
GHS Symbol
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
UN Number 1992
Risk Statements
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用(指明具体的消防器材种类,如果用水增加危险,注明“禁止用水”
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Flammables area Moisture Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nit
Packing GroupIII
Hazard Class3/6.1

其他信息

  • 海关编码:29051900
  • MOL 文件:2269-22-9.mol
  • Acros Organics:仲丁醇铝 Aluminium tri-sec-butoxide, 97%(2269-22-9)
  • 见水分解。无色或淡黄色粘稠液体,易溶于乙醇、异丙醇、甲苯等,易燃、易吸湿,遇水分解成氢氧化铝和仲丁醇
  • MSDS 信息:Aluminium tri-sec-butoxide(2269-22-9).msds
  • 外观性质:见水分解。无色或淡黄色粘稠液体,易溶于乙醇、异丙醇、甲苯等,易燃、易吸湿,遇水分解成氢氧化铝和仲丁醇沸点: 200-206℃闪点: 27℃密度: 0.9671 沸点: 200-206℃折光率:1.4390
  • 用途一:用作活性催化剂及载体,无机膜、醛-酮的还原剂、醛-酮的氧化剂,油墨油漆的胶凝剂,织物防水剂,铝复合润滑脂等。
  • TCI Shanghai:仲丁醇铝 Aluminum sec-Butoxide,>;98.0%(T)(2269-22-9)
  • 图谱信息:仲丁醇铝(2269-22-9)核磁图( 13 CNMR) 仲丁醇铝(2269-22-9)红外图谱(IR1) 仲丁醇铝(2269-22-9)质谱(MS)
  • 仲丁醇铝价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0244 仲丁醇铝 Aluminum sec-Butoxide 25G 158元 2014/06/02 A0244 仲丁醇铝 Aluminum sec-Butoxide 500G 690元 2010/06/21 191210050 仲丁醇铝 Aluminium tri-sec-butoxide 97% 5 GR 237元
  • Sigma Aldrich:2269-22-9(sigmaaldrich)
  • F:3-10-23
  • 敏感性:Moisture Sensitive
  • Alfa Aesar:仲丁氧基铝,97% Aluminum sec-butoxide, 97%(2269-22-9)
  • TSCA:Yes

系列性分类


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