Tri-n-Propyl Borate 硼酸三丙酯

CAS 688-71-1 MFCD00009366

化学结构图

688-71-1
SMILES: CCCOB(OCCC)OCCC

化学属性

Mol. FormulaC9H21BO3
Mol. Weight188
Density0.857
Refractive index1.3930 to 1.3960
Flash Point32°C(lit.)
SolubilitySoluble in organic solvents. Decomposes in water
TSCAYes
Boiling Point180
Melting Point<0°C

别名和识别编码

Chemical NameTri-n-Propyl Borate
Synonym (n-C3H7O)3B BORIC ACID TRI-N-PROPYL ESTER BORIC ACID TRIPROPYL ESTER BORON N-PROPOXIDE BORON-TRI-N-PROPOXIDE Boric acid (H3BO3), tripropyl ester PROPYL BORATE Propyl Borate Propyl borate, (PrO)3 B Propyl orthoborate TRI-N-PROPYL BORATE TRIPROPYL BORATE Tri-n-propyl borate Tripropoxyborane Tripropyl borate Tripropyl orthoborate Tripropylborate,98% boric acid tripropyl ester boricacid(h3bo3),tripropylester n-Propyl borate n-Propylborat 三(丙氧)硼 硼酸三丙酯 硼酸三正丙酯 硼酸丙酯 碰栓丙酯
MDL NumberMFCD00009366
CAS Number688-71-1
EC Number211-703-9
PubChem Substance ID12711
Reaxys-RN1701561
Beilstein Registry Number1701561
Chemical Name Translation硼酸三丙酯
Wiswesser Line Notation3OBO3&O3
InChIKeyLTEHWCSSIHAVOQ-UHFFFAOYSA-N
LabNetwork Molecule IDLN01740265
InChIInChI=1S/C9H21BO3/c1-4-7-11-10(12-8-5-2)13-9-6-3/h4-9H2,1-3H3
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分类

  • {SNA} Boronic Acids and Derivatives, Chemical Synthesis, Organoborates, Organometallic Reagents
  • {uni_hamburg} no charge; 1fragment

产品应用

  • 溶剂。半导体硼扩散源。

相关文献及参考

  • Short: IV/1a
  • Short: IV/18A
  • Beilstein:1(4)1436
  • Short: III/38A
  • Short: IV/16

安全信息

RTECSED5785000
Packing GroupIII
UN Number 1993
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
Storage condition Moisture Sensitive 密封阴凉保存。
GHS Symbol
WGK Germany2
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word Warning
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P337+P313
  • P370+P378
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard Class3
Hazard Codes 3 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2080 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   14KTAK "Boron, Metallo-Boron Compounds and Boranes," Adams, R.M., ed., New
   York, John Wiley & Sons, Inc., 1964  Volume(issue)/page/year: -,693,1964

其他信息

  • 硼酸三丙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80137260 硼酸三丙酯 20ml 15元 2011/04/16 B0134 硼酸三丙酯 Tripropyl Borate 500ML 2330元 2011/04/16 B0134 硼酸三丙酯 Tripropyl Borate 25ML 332元
  • 图谱信息:硼酸三丙酯(688-71-1)Raman光谱 硼酸三丙酯(688-71-1)核磁图( 13 CNMR) 硼酸三丙酯(688-71-1)核磁图( 1 HNMR) 硼酸三丙酯(688-71-1)红外图谱(IR1)
  • MOL 文件:688-71-1.mol
  • 下游产品:3-苄氧基苯硼酸 --> 4-甲基-1-萘硼酸
  • TCI Shanghai:硼酸三丙酯 Tripropyl Borate,>;99.0%(T)(688-71-1)
  • 毒性分级:中毒
  • Alfa Aesar:硼酸三丙酯,98% Tri-n-propyl borate, 98%(688-71-1)
  • 刺激数据:眼- 兔子 100 毫克 轻度
  • 用途一:溶剂。半导体硼扩散源。
  • 类别:易燃液体
  • 储运特性:包装完整、轻装轻放; 库房通风、远离明火、高温、与氧化剂分开存放
  • MSDS 信息:硼酸三丙酯(688-71-1).msds
  • Sigma Aldrich:688-71-1(sigmaaldrich)
  • 外观性质:无色液体, 有类似丙醇的气味。
  • 可燃性危险特性:遇明火、高温、强氧化剂可燃; 燃烧产生有毒硼化物烟雾
  • 急性毒性:口服- 小鼠 LD50: 2080 毫克/ 公斤
  • 敏感性:Moisture Sensitive
  • 遇水迅速分解。能与乙醇、乙醚、苯等有机溶剂混溶。易燃。
  • 灭火剂:泡沫、二氧化碳、干粉、砂土、雾状水
  • TSCA:Yes

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Boron 硼
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Organoborates - Boronic Acids and Derivatives

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