Hexabutylditin 六正丁基二锡
CAS 813-19-4 MFCD00009417
化学结构图
SMILES: CCCC[Sn](CCCC)(CCCC)[Sn](CCCC)(CCCC)CCCC
化学属性
| Mol. Formula | C₂₄H₅₄Sn₂ |
|---|---|
| Mol. Weight | 580.11 |
| Refractive index | n20/D 1.512(lit.) |
| Density | 1.148 |
| Flash Point | - |
| TSCA | No |
| Boiling Point | - |
| Stability | 对空气敏感，对湿度敏感 |
| pH | :A |
别名和识别编码
| Chemical Name | Hexabutylditin |
|---|---|
| Synonym | 1,1,1,2,2,2-Hexabutyl-distannane BIS[TRIBUTYLTIN(IV)] Bis(tri-n-butyltin) Bis(tributyltin) Bis-(tributylzinn) Distannane, hexabutyl- Distannane,hexabutyl- HEXABUTYLDISTANNANE HEXABUTYLDITIN 97+% Hexa-n-butyldistannane Hexa-n-butylditin, min. 95% Hexa-n-butylditin,min.95% Hexabutyldistannane, Hexabutylditin Hexabutyldistannane; Hexabutylditin Hexabutylditin {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} |
| CAS Number | 813-19-4 |
| PubChem Substance ID | 6327815 |
| EC Number | 212-383-3 |
| Beilstein Registry Number | 3605476 |
| MDL Number | - |
| Chemical Name Translation | 六正丁基二锡 |
| InChIKey | REDSKZBUUUQMSK-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00009522 |
| InChI | InChI=1S/6C4H9.2Sn/c6*1-3-4-2;;/h6*1,3-4H2,2H3;; |
| Canonical SMILES | - |
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分类
- Chemical Synthesis, Organoditins, Organometallic Reagents, Organotin
- {uni_hamburg} no charge; metal-organic; 1fragment
- {SNA} Chemical Synthesis, Organoditins, Organometallic Reagents, Organotin
产品应用
- 用于甲锡烷化芳基卤的试剂．
相关文献及参考
- Brings about the deoxygenation of amine oxides: Synthesis, 55 (1987), and the photo-desulfurisation of 1,3-dithiole-2-thiones to tetrathiafulvalenes: J. Am. Chem. Soc., 98, 7440 (1976).
- Source of on thermolysis or photolysis of tributylstannyl radicals, avoiding the problems sometimes attributable to the hydrogen donor capability of Tri-n-butyltin hydride, A13298.ɑ-Iodo-ketones or esters with a suitably-placed double bond undergo radical cyclizations on UV irradiation in the presence of a catalytic amount of the distannane: Tetrahedron Lett., 28, 2477 (1987); J. Org. Chem., 54, 1826, 3140 (1989). Compare analogous reductive cyclizations using the tin hydride. Improved conditions have been developed for generation of the tributylstannyl radical by mild UV irradiation in the presence of a triplet sensitizer (e.g. 4'-Methoxyacetophenone, A11162), allowing selective C-C bond forming reactions to be performed under free-radical conditions: Synlett, 287 (1993).
- Short: III/35C4
- Tetrahedron Lett. 29 , 6893, (1988)
- Source of on thermolysis or photolysis of tributylstannyl radicals, avoiding the problems sometimes attributable to the hydrogen donor capability of Tri-n-butyltin hydride, A13298.ɑ-Iodo ketones or esters with a suitably-placed double bond undergo radical cyclizations on UV irradiation in the presence of a catalytic amount of the distannane: Tetrahedron Lett., 28, 2477 (1987); J. Org. Chem., 54, 1826, 3140 (1989). Compare analogous reductive cyclizations using the tin hydride. Improved conditions have been developed for generation of the tributylstannyl radical by mild UV irradiation in the presence of a triplet sensitizer (e.g. 4'-Methoxyacetophenone, A11162), allowing selective C-C bond forming reactions to be performed under free-radical conditions: Synlett, 287 (1993).
- Brings about the deoxygenation of amine oxides: Synthesis, 55 (1987), and the photo-desulfurization of 1,3-dithiole-2-thiones to
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H301 Toxic if swallowed 吞食有毒
- H312 Harmful in contact with skin 皮肤接触有害
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H319 Causes serious eye irritation 严重刺激眼睛
- H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P310
- P305+P351+P338
- P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- R21 Harmful in contact with skin 与皮肤接触有害
- R25 Toxic if swallowed 吞咽有毒
- R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
- R48/23/25
- R50/53
- S35 This material and its container must be disposed of in a safe way 该物料及其容器必须以安全方式处置；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
其他信息
- Sigma Aldrich:813-19-4(sigmaaldrich)
- 六正丁基二锡价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 351510100 六正丁基二锡 Hexa-n-butylditin 98% 10 GR 764元 2010/06/21 351510500 六正丁基二锡 Hexa-n-butylditin 98% 50 GR 2633元 2010/05/25 A12007 六正丁基锡, 98+% Hexa-n-butylditin, 98% 250g 5292元
- 敏感性:Air & Moisture Sensitive
- TCI Shanghai:六正丁基二锡 Bis(tributyltin),>;90.0%(GC)(813-19-4)
- TSCA:No
- F:1-10
- Alfa Aesar:六正丁基锡,98+% Hexa-n-butylditin, 98%(813-19-4)
- Acros Organics:六正丁基二锡 Hexa-n-butylditin, 98%(813-19-4)
- 用途一:用于甲锡烷化芳基卤的试剂．
- MOL 文件:813-19-4.mol
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