Tributylamine (剧毒品,不能销售)三正丁胺

CAS 102-82-9 MFCD00009431

化学结构图

102-82-9
SMILES: CCCCN(CCCC)CCCC

化学属性

Mol. Formula[CH3(CH2)3]3N
Mol. Weight185.35
Density0.778 g/mL at 25 °C(lit.)
Refractive indexn20/D 1.428(lit.)
Autoignition Point410 °F
Vapor Density6.38 (vs air)
Boiling Point216 °C(lit.)
Vapor Pressure0.3 mmHg ( 20 °C)
Melting Point-70 °C(lit.)
Flash Point71°(159°F)
Solubility不溶于水,溶于醇、醚。
TSCAYes
Stability易吸潮

别名和识别编码

Chemical NameTributylamine
CAS Number102-82-9
EC Number203-058-7
Beilstein Registry Number1698872
MDL NumberMFCD00009431
Synonym ai3-15424 tris-n-butylamine 三丁胺, N,N-二丁基-1-丁胺,N,N-二丁基-1-丁胺,三正丁基胺 TRIBUTYLAMINE PURE Tributilamina TNBA N-Dibutyl-1-butanamine n,n-dibutyl-1-butanamin N,N-二丁基-1-丁胺 tributylamine tributylamine,[liquid] 三丁基胺 三丁胺 Tris[N-butylamine] TRI-N-BUTYLAMINE Tri-n-butylamine 1-Butanamine,N,N-dibutyl- tris(1-butyl)amine tri(n-butyl)amine amine,tributyl Tris-n-butylamine tris(1n-butyl)amine (n-C4H9)3N 1-Butanamine, N,N-dibutyl- N,N-Dibutyl-1-butanamine N,N-DIBUTYL-1-BUTANAMINE 三丁胺;N,N-二丁基-1-丁胺;N,N-二丁基-1-丁胺;三正丁基胺 三正丁基胺 三正丁胺 TRIBUTYLAMINE TRIBUTYLAMINE REAGENTPLUSTM >=99% TBA
Merck Number9618
PubChem Substance ID57653405
Reaxys-RN1698872
Chemical Name Translation(剧毒品,不能销售)三正丁胺
Wiswesser Line Notation4N4&4
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • {SNA} Analytical Reagents, Analytical Reagents for General Use, Analytical/Chromatography, Puriss p.a. ACS, T-Z, Puriss p.a. ACS
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Analytical Reagents for General Use, Puriss p.a. ACS, T-Z, Puriss p.a. ACS, 分析/色谱, 分析试剂

产品应用

  • 生产医药、农药、染料、矿物浮选剂、乳化剂以及精细化学品的中间体等。

相关文献及参考

  • Short: III/47
  • Merck:14,9618 Beilstein:4,157
  • Merck:14,9618
  • Short: III/38A
  • Short: III/38B

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染;
  • S4 Keep away from living quarters 远离生活区;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
Risk Statements
  • R51/53
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R22 Harmful if swallowed 吞咽有害
  • R23/24 Toxic by inhalation and in contact with skin 吸入及皮肤接触都有毒
  • R24 Toxic in contact with skin 与皮肤接触有毒
  • R26 Very toxic by inhalation 吸入极毒
  • R38 Irritating to skin 刺激皮肤
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P304+P340+P310
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P304+P340
  • P302+P350
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P337+P313
  • P403+P233
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P302+P352+P310
  • P301+P312+P330
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P301+P310+P330
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P405 Store locked up. 上锁保管。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
RTECSYA0350000
Hazard Codes T+ T,N
UN Number 2542 UN2542 UN 2542 6.1/PG 2
Packing GroupII
Storage condition Store at RT. 充氩保存 Hygroscopic
Hazard statements
  • H310+H330
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Class6.1
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 615 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 42(12),36,1977

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 107 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - excitement
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 28(11),50,1984

TYPE OF TEST            : LCL

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 114 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 42(12),36,1977

TYPE OF TEST            : LD50 - Lethal dose, 50 pe

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 888 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - excitement
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Z

Restrict 剧毒 {} 剧毒化学品

其他信息

  • 无色至微黄色液体,有类似氨的气味,不溶于水,水中溶解度:0.386 g/l (25°C);易吸湿。溶于大多数有机溶剂,极溶于醇、醚。
  • MSDS 信息:三正丁胺(102-82-9).msds
  • 毒性分级:中毒
  • 三正丁胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 81013227 三正丁胺 250ml 18.6元 2011/04/16 T0357 三丁胺 Tributylamine 25ML 102元 2011/04/16 T0357 三丁胺 Tributylamine 500ML 284元
  • 图谱信息:三正丁胺(102-82-9)Raman光谱 三正丁胺(102-82-9)红外图谱(IR1) 三正丁胺(102-82-9)质谱(MS) 三正丁胺(102-82-9)核磁图( 13 CNMR) 三正丁胺(102-82-9)红外图谱(IR2)
  • 外观性质:无色液体,有类似氨的气味。
  • 储运特性:库房通风低温干燥; 与酸、氧化剂分开存放
  • 用途一:用作萃取剂和溶剂
  • TCI Shanghai:三丁胺 Tributylamine,>;98.0%(GC)(T)(102-82-9)
  • F:10
  • 爆炸物危险特性:与空气混合可爆
  • MOL 文件:102-82-9.mol
  • 海关编码:29211980
  • Alfa Aesar:三正丁基胺,98% Tri-n-butylamine, 98%(102-82-9)
  • 用途三:全氟三丁胺、四丁基氯化铵、四丁基溴化铵等精细化学品的原料。
  • 可燃性危险特性:可燃
  • Sigma Aldrich:102-82-9(sigmaaldrich)
  • 灭火剂:干粉、二氧化碳、抗醇泡沫
  • 敏感性:Hygroscopic
  • 上游原料:正丁胺 --> 二正丁胺 --> 酸性白土
  • 蒸气压:0.3 mm Hg ( 20 °C)
  • 类别:腐蚀物品
  • 下游产品:正丁胺 --> (1R,2R)-双[(2-甲氧基苯基)苯基磷]乙烷 --> 二正丁胺 --> 聚胞苷酸 --> 四丁基硫酸氢铵 --> 灭草松 --> 水胺硫磷 --> 异丙氧磷 --> 全氟三丁胺
  • Acros Organics:三丁胺 Tributylamine, 99%(102-82-9)
  • 蒸气密度:6.38 (vs air)
  • 急性毒性:口服-大鼠 LD50: 114 毫克/公斤; 口服-小鼠 LD50: 114 毫克/公斤
  • 方法一:将丁醇、氨、氢气按配比通入填充铜镍酸性白土催化剂的反应塔中,在200℃左右反应,将反应气体冷凝,得到含一丁胺、二丁胺、三丁胺的混合物,通过精馏分离出三个产品。
  • 用途四:生产医药、农药、染料、矿物浮选剂、乳化剂以及精细化学品的中间体等。
  • 不溶于水,水中溶解度:0.386 g/l (25°C);易吸湿。溶于大多数有机溶剂,极溶于醇、醚。
  • 用途二:用于石油添加剂、溶剂、医药中间体、杀虫剂、乳化剂、塑料增塑剂、矿物浮选剂及表面活性剂等

系列性分类


相关产品推荐