Bis(2-ethylhexyl) phosphite 亚磷酸二(2-乙基己基)酯

CAS 3658-48-8 MFCD00009490

化学结构图

3658-48-8
SMILES: CCCCC(CC)CO[P+](=O)OCC(CC)CCCC

化学属性

Mol. FormulaC16H35O3P
Mol. Weight306.42
Refractive indexn20/D 1.442(lit.)
Density0.916 g/mL at 25 °C(lit.)
Flash Point>;230 °F

别名和识别编码

Chemical NameBis(2-Ethylhexyl)Phosphite
CAS Number3658-48-8
PubChem Substance ID6327514
EC Number222-904-6
MDL NumberMFCD00009490
Synonym Bis(2-ethylhexyl) phosphonate {LY} Bis(2-ethylhexyl) phosphonate {} {LY} Bis(2-ethylhexyl) phosphonate {} {} {LY} Bis(2-ethylhexyl) phosphonate {} {} {} {LY} Bis(2-ethylhexyl) phosphonate {} {} {} {} {LY} Bis(2-ethylhexyl) phosphonate {} {} {} {} {} {LY} Bis(2-ethylhexyl) phosphonate {} {} {} {} {} {} {LY} Bis(2-ethylhexyl) phosphonate {} {} {} {} {} {} {} {LY} Bis(2-ethylhexyl) phosphonate {} {} {} {} {} {} {} {} {LY} Bis(2-ethylhexyl) phosphonate {} {} {} {} {} {} {} {} {} {LY} Bis(2-ethylhexyl) phosphonate {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Bis(2-ethylhexyl) phosphonate {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(2-ethylhexyl) phosphonate {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(2-ethylhexyl) phosphonate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(2-ethylhexyl) phosphonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(2-ethylhexyl) phosphonate {} {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation亚磷酸二(2-乙基己基)酯
Wiswesser Line Notation4Y2&1OPHO&O1Y4&2
Beilstein Registry Number1711893
InChIInChI=1S/C16H34O3P/c1-5-9-11-15(7-3)13-18-20(17)19-14-16(8-4)12-10-6-2/h15-16H,5-14H2,1-4H3/q+1
Canonical SMILESO=P(OCC(CCCC)CC)OCC(CCCC)CC
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分类

  • Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds

相关文献及参考

  • Corp MSDS 1 (1), 436:C / FT-IR 1 (1), 913:D / FT-IR 2 (1), 1555:A / FT-NMR 1 (1), 1472:B / NMR-Reference 2 (2), 865:C / RegBook 1 (1), 1097:J / Sax 6 , 480 / Structure Index 1 , 169:B:9

安全信息

GHS Symbol
WGK Germany2
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSSZ6840000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 620 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 18,464,1958

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 4500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ALBRW* Albright & Wilson Inc.  (P.O. Box 26229, Richmond, VA 23260-6229)
   Volume(issue)/page/year: #OPB-3,1984

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 11900 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ALBRW* Albright & Wilson Inc.  (P.O. Box 26229, Richmond, VA 23260-6229)
   Volume(issue)/page/year: #OPB-3,1984

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - acute pulmonary edema
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 18,464,1958

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOS

Storage condition

其他信息

  • MOL 文件:3658-48-8.mol
  • 储运特性:库房通风低温干燥
  • 灭火剂:二氧化碳、砂土、水、泡沫
  • 毒性分级:中毒
  • Sigma Aldrich:3658-48-8(sigmaaldrich)
  • 用途一:用作阻燃剂
  • 刺激数据:眼睛-兔子 25 毫克 轻度
  • 可燃性危险特性:明火可燃; 受热分解有毒磷化物气体
  • 急性毒性:腹腔-大鼠 LD50: 1500 毫克/公斤; 腹腔-小鼠 LDL0: 620 毫克/公斤
  • 类别:有毒物品

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Organic Phosphates/Phosphites - Phosphorus Compounds

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