Tris(2-ethylhexyl) phosphate 磷酸三(2-乙基己基)酯

CAS 78-42-2 MFCD00009491

化学结构图

78-42-2
SMILES: CCCCC(CC)COP(=O)(OCC(CC)CCCC)OCC(CC)CCCC

化学属性

Mol. FormulaC24H51O4P
Mol. Weight434.64
Refractive index1.4420 to 1.4440
Boiling Point405.5 °C at 760 mmHg
Density0.92
Flash Point204°C(lit.)
TSCAYes
Vapor Pressure2.1 mmHg ( 20 °C)
Melting Point-70 °C
Solubility<0.1 G/100 ML AT 18 ºC
Stability对湿度敏感

别名和识别编码

Chemical NameTris(2-ethylhexyl) phosphate
Synonym Tris(2-ethylhexyl) phosphate {LY} Tris(2-ethylhexyl) phosphate {} {LY} Tris(2-ethylhexyl) phosphate {} {} {LY} Tris(2-ethylhexyl) phosphate {} {} {} {LY} Tris(2-ethylhexyl) phosphate {} {} {} {} {LY} Tris(2-ethylhexyl) phosphate {} {} {} {} {} {LY} Tris(2-ethylhexyl) phosphate {} {} {} {} {} {} {LY} Tris(2-ethylhexyl) phosphate {} {} {} {} {} {} {} {LY} Tris(2-ethylhexyl) phosphate {} {} {} {} {} {} {} {} {LY} Tris(2-ethylhexyl) phosphate {} {} {} {} {} {} {} {} {} {LY} Tris(2-ethylhexyl) phosphate {} {} {} {} {} {} {} {} {} {} {LY} Tris(2-ethylhexyl) phosphate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(2-ethylhexyl) phosphate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(2-ethylhexyl) phosphate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(2-ethylhexyl) phosphate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(2-ethylhexyl) phosphate {} {} {}
CAS Number78-42-2
PubChem Substance ID87575134
EC Number201-116-6
Beilstein Registry Number1715839
MDL NumberMFCD00009491
Reaxys-RN1715839
Chemical Name Translation磷酸三(2-乙基己基)酯
Wiswesser Line Notation4Y2&1OPO&O1Y4&2&O1Y4&2
LabNetwork Molecule IDLN00199869
Canonical SMILESO=P(OCC(CC)CCCC)(OCC(CC)CCCC)OCC(CC)CCCC
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分类

  • {SNA} Ion Sensor Materials, Plasticizer for ISE, 分析/色谱
  • {SNA} Analytical/Chromatography, Ion Sensor Materials, Plasticizer for ISE
  • Building Blocks, Chemical Synthesis, Organic Building Blocks, Organic Phosphates/Phosphites, Phosphorus Compounds
  • {uni_hamburg} no charge; 1fragment

产品应用

  • 萃取剂。增塑剂。

相关文献及参考

  • Short: EINECS
  • Short: IV/18A
  • Beilstein: 1,IV,1786

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xi
RTECSMP0770000
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Signal word Warning
Risk Statements
  • R20 Harmful by inhalation 吸入有害
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R38 Irritating to skin 刺激皮肤
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at r 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 520 gm/kg/2Y-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
REFERENCE :
   EVHPAZ EHP, Environmental Health Perspectives.  (U.S. Government Printing
   Office, Supt of Documents, Washington, DC 20402)  No.1-    1972-
   Volume(issue)/page/year: 65,271,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 20 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,1133,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - m

TYPE OF TEST            :

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 40 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   29ZWAE "Practical Toxicology of Plastics," Lefaux, R., Cleveland, OH,
   Chemical Rubber Co., 1968  Volume(issue)/page/year: -,337,1968

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 37 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 30,63,1948

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 7600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-

其他信息

  • TCI Shanghai:三(2-乙基己基)磷酸酯 Tris(2-ethylhexyl) Phosphate,>;98.0%(GC)(78-42-2)
  • 海关编码:29190090
  • Alfa Aesar:磷酸三辛基酯 Trioctyl phosphate(78-42-2)
  • 磷酸三辛酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P1022 磷酸三(2-乙基己基)酯 Tris(2-ethylhexyl) Phosphate 500ML 524元 2014/06/02 P1022 磷酸三(2-乙基己基)酯 Tris(2-ethylhexyl) Phosphate 25ML 175元 2010/05/25 15808 磷酸三辛基酯 Trioctyl phosphate 250g 532元
  • 用途一:可在蒽醌法生产过氧化氢中代替氢化萜松醇，使产品浓度高、质量好、自身消耗少，还可用作PVC的耐寒增塑剂
  • 上游原料:三氯氧磷 --> 2-乙基己醇
  • 溶于矿物油、汽油、乙醇和苯，不溶于水。有毒。有致癌可能性和刺激性。
  • 蒸气压:2.1 mm Hg ( 20 °C)
  • 外观性质:无色粘稠液体。
  • 用途二:萃取剂。增塑剂。
  • MSDS 信息:磷酸三(-2-乙基己基)酯(78-42-2).msds
  • 下游产品:过氧化氢
  • MOL 文件:78-42-2.mol
  • Sigma Aldrich:78-42-2(sigmaaldrich)

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Ion Sensor Materials
  3. Plasticizer for ISE - Ion Sensor Materials
  1. Analytical & Chromatography 分析化学与色谱
  2. Ion Sensor Materials
  3. Plasticizer for ISE - Ion Sensor Materials
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Organic Phosphates/Phosphites - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphonates/Phosphinates - Phosphorus Compounds
  1. Materials Science 材料科学
  2. Plasticizer

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