Trioctylamine 三辛胺

CAS 1116-76-3 MFCD00009560

化学结构图

1116-76-3
SMILES: CCCCCCCCN(CCCCCCCC)CCCCCCCC

化学属性

Mol. FormulaC24H51N
Mol. Weight353.68
Density0.809
Refractive index1.4480 to 1.4500
Boiling Point363.5±10.0 °C at 760 mmHg
Flash Point184°C(lit.)
TSCAYes
Melting Point34 °C
Stability对光敏感
Solubility溶于乙醇和乙醚，极微溶于水。
Appearance 无色油状液体。熔点-34℃，沸点365.812℃。相对密度（20/4℃）0.811，折光率（nD20）1.449。熔于醇和醚，微溶于甲醇，易溶于非极性溶剂，极微溶于水。有氨的气味，呈碱性。

别名和识别编码

Chemical NameTrioctylamine
Synonym Trioctylamine {LY} Trioctylamine {} {LY} Trioctylamine {} {} {LY} Trioctylamine {} {} {} {LY} Trioctylamine {} {} {} {} {LY} Trioctylamine {} {} {} {} {} {LY} Trioctylamine {} {} {} {} {} {} {LY} Trioctylamine {} {} {} {} {} {} {} {LY} Trioctylamine {} {} {} {} {} {} {} {} {LY} Trioctylamine {} {} {} {} {} {} {} {} {} {LY} Trioctylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trioctylamine {} {} {} {} {} {} {} {} {} {} {} {LY} Trioctylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trioctylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trioctylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trioctylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trioctylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trioctylamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00009560
CAS Number1116-76-3
EC Number214-242-1
Beilstein Registry Number1210618
PubChem Substance ID14227
Reaxys-RN1210618
Chemical Name Translation三辛胺
Wiswesser Line Notation8N8&8
LabNetwork Molecule IDLN00195011
InChIInChI=1S/C24H51N/c1-4-7-10-13-16-19-22-25(23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3
Canonical SMILESCCCCCCCCN(CCCCCCCC)CCCCCCCC
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分类

  • {SA} Amines, Building Blocks, C20 to C30+, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
  • {SNA} Amines, Building Blocks, C20 to C30+, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Amines, Building Blocks, C20 to C30+, Chemical Reagents, Chemical Synthesis, Development Quantities for Research, Nitrogen Compounds, Organic Building Blocks

产品应用

  • 胺类萃取剂，对钍、铀等锕系元素有较好的萃取性能，而且对有色金属、稀有、稀散金属和铂系元素能在不同体系下进行萃取分离。用于生产相转移催化剂、橡胶添加剂以及缓蚀剂。

相关文献及参考

  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: III/47 Title: Optical Constants: Refractive Indices of Pure Liquids and Binary Liquid Mixtures Author: Wohlfarth, Ch. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/47 Year: 2008 Keyword: binary liquid mixtures; inorganic liquid; optical constant; organic liquid; organoarsenic liquid; organoboron liquid; organometallic liquid; organophosphorus liquid; organosilicon liquid; organovanadic liquid; pure liquids; refractive index ISBN: 978-3-540-75289-9 (Print) ISBN: 978-3-540-75291-2 (Online) Internet Resource: DOI:10.1007/978-3-540-75291-2 RefComment: VII, 298 p., Hardcover RefComment: Written for scientists and engineers in the fields of physics, chemistry, and physical chemistry Abstract: This Landolt-Börnstein volume III/47 is a supplement to the volumes III/38 A/B "Optical Constants" and provides refractive index data published in the years 1995-2006. Included in this volume are refractive indices of inorganic, organometallic, organononmetallic, and organic liquids as well as their binary liquid mixtures at different wavelengths, temperatures, and pressures. Not all published data could be included in the printed version, but the electronic version contains

安全信息

Signal word Warning
GHS Symbol
WGK Germany2
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S29 Do not empty into drains 不要排入下水道；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R51/53
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P203
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P318
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSRG8225000
Packing GroupIII
UN Number UN3082 3082
Storage condition 2-8°C {LY} 2-8°C Air Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Hazard Codes Xi;N Xi,N Xi
Hazard Class9 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HYDRDA Hydrometallurgy.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1975-  Volume(issue)/page/year: 3,201,1978

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 62500 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 4,323,1952

其他信息

  • 用途二:用作贵金属萃取剂。在冶金工业中，用来萃取分离钴、镍、锕系和镧系元素。
  • F:10-23
  • 有氨的气味。对空气敏感。易溶于非极性溶剂，溶于乙醇和乙醚，极微溶于水。最小致死量(小鼠，腹腔)63mg/kg。有刺激性。
  • 敏感性:Air Sensitive
  • 上游原料:酸性氧化铝 --> 正辛醇
  • Sigma Aldrich:1116-76-3(sigmaaldrich)
  • MSDS 信息:Tri-n-octylamine(1116-76-3).msds
  • TCI Shanghai:三正辛胺[离子对色谱用试剂] Tri-n-octylamine [Reagent for Ion-Pair Chromatography],>;98.0%(GC)(T)(1116-76-3)
  • 用途一:用作表面活性剂和萃取剂
  • 图谱信息:三辛胺(1116-76-3)核磁图( 13 CNMR) 三辛胺(1116-76-3)质谱(MS) 三辛胺(1116-76-3)红外图谱(IR2) 三辛胺(1116-76-3)核磁图( 1 HNMR) 三辛胺(1116-76-3)红外图谱(IR1)
  • 三辛胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K9283001 三正辛胺pract～95％ 100ml 696元 2011/04/16 T0502 三正辛胺 Tri-n-octylamine 500ML 697元 2011/04/16 T0502 三正辛胺 Tri-n-octylamine 25ML 172元
  • Alfa Aesar:三正辛胺,98% Tri-n-octylamine, 98%(1116-76-3)
  • 用途三:胺类萃取剂，对钍、铀等锕系元素有较好的萃取性能，而且对有色金属、稀有、稀散金属和铂系元素能在不同体系下进行萃取分离。用于生产相转移催化剂、橡胶添加剂以及缓蚀剂。
  • 方法一:以正辛醇为原料，在三氯化铝催化剂存在下进行氨化。反应在缩合釜中进行，将氨通入釜中，在400℃反应。然后赶除过剩的正辛醇，滤除催化剂，即得成品三辛胺。原料消耗（kg/t）正辛醇 1217三氧化铝 685
  • 下游产品:别腐烂
  • MOL 文件:1116-76-3.mol
  • 有氨的气味。对空气敏感。易溶于非极性溶剂。最小致死量(小鼠，腹腔)63mg/kg。有刺激性。
  • 海关编码:29211980
  • Acros Organics:三正辛胺 Tri-n-octylamine, 98%(1116-76-3)
  • 存储注意事项:空气敏感

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. HPLC
  3. Buffers & Reagents - HPLC
  4. Ion Pair Reagents 离子对试剂
  1. C14 to C16 - Amines
  1. C17 to C40+ - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amines 胺

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