4-Fluorophenylmagnesium Bromide 4-氟苯基溴化镁
CAS 352-13-6 MFCD00009667
化学结构图
SMILES: Fc1ccc([Mg]Br)cc1
化学属性
| Mol. Formula | C6H4BrFMg |
|---|---|
| Mol. Weight | 199.31 |
| Density | 1.01 |
| TSCA | Yes |
| Melting Point | 5 |
| Flash Point | -20°C(lit.) |
| Stability | 对湿度敏感 |
别名和识别编码
| Chemical Name | 4-Fluorophenylmagnesium Bromide |
|---|---|
| CAS Number | 352-13-6 |
| EC Number | 250-023-7 |
| Beilstein Registry Number | 636802 |
| MDL Number | MFCD00009667 |
| PubChem Substance ID | 2734897 |
| Synonym | 4-氟苯基溴化镁 溶液 4-氟苯基溴化镁 |
| Reaxys-RN | 636802 |
| Chemical Name Translation | 4-氟苯基溴化镁 |
| InChIKey | QYBFFRXNNFXREA-UHFFFAOYSA-M |
| LabNetwork Molecule ID | LN00220943 |
| InChI | InChI=1S/C6H4F.BrH.Mg/c7-6-4-2-1-3-5-6;;/h2-5H;1H;/q-1;;+2/p-1 |
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分类
- {SNA} Aryl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents
相关文献及参考
- Beilstein: 16,II,650
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
- S8 Keep container dry 保持容器干燥；
- R11 Highly flammable 非常易燃
- R19 May form explosive peroxides 可能生成易爆的过氧化物质
- R14 Reacts violently with water 遇水会猛烈反应
- R34 Causes burns 会导致灼伤
- R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P370+P378
- P403+P235
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P303+P361+P353
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P405 Store locked up. 上锁保管。
- P403+P233
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H302 Harmful if swallowed 吞食有害
- H351 Suspected of causing cancer 怀疑致癌
- H335 May cause respiratory irritation 可能导致呼吸道刺激
其他信息
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