(+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane 异丙烯-2,3-二羟-1,4-双二丙基膦丁烷

CAS 37002-48-5 MFCD00009760

化学结构图

37002-48-5
SMILES: CC1(C)O[C@H](CP(C2C=CC=CC=2)C2C=CC=CC=2)[C@@H](CP(C2C=CC=CC=2)C2C=CC=CC=2)O1

化学属性

TSCANo
Mol. FormulaC31H32O2P2
Mol. Weight498.55
Appearance white pwdr.
Stabilityair sensitive
Melting Point87-91°C

别名和识别编码

Chemical Name(+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane
Synonym (+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane (4S-反式)-[(2,2-二甲基-1,3-二氧戊环-4,5-二基)双(亚甲基)]双(二苯基膦) (+)-1,4-双(二苯基膦)-1,4-二脱氧-2,3-O-异亚丙基-D-苏糖醇 (+)-DIOP (4S,5S)-4,5-双(二苯基膦甲基)-2,2-二甲基-1,3-二氧戊环 (4S-反式)-[(2,2-二甲基-1,3-二氧戊环-4,5-二基)双(亚甲基)]双(二苯基膦) (S,S)-DIOP (+)-2,3-O-异丙烯基-2,3-二羟基-1,4-双(二苯基膦)丁烷 (+)-DIOP (+)-1,4-双(二苯基膦)-1,4-二脱氧-2,3-O-异亚丙基-D-苏糖醇 (4S,5S)-4,5-双(二苯基膦甲基)-2,2-二甲基-1,3-二氧戊环 (4S-反式)-[(2,2-二甲基-1,3-二氧戊环-4,5-二基)双(亚甲基)]双(二苯基膦) (S,S)-DIOP
PubChem Substance ID87564055
Beilstein Registry Number1630280
EC Number253-307-9
Reaxys-RN5148912
Chemical Name Translation异丙烯-2,3-二羟-1,4-双二丙基膦丁烷
MDL NumberMFCD00009760
CAS Number37002-48-5
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DIOP, Privileged Ligands and Complexes
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DIOP, Privileged Ligands and Complexes

相关文献及参考

  • Morimoto, T. et al. Tetrahedron Asymmetry 6 , 23, (1995)
  • Morimoto, T. at al. Tetrahedron Asymmetry 6 , 75, (1995)
  • Matsumoto, Y. et al. Tetrahedron 50 , 335, (1994)
  • Sato, Y. et al. Tetrahedron 50 , 371, (1994)
  • Gladiali, S. Pinna, L. Tetrahedron Asymmetry 1 , 693, (1990)
  • Fieser 4 ,273 / Fieser 5 ,360 / Fieser 6 ,309 / Fieser 9 ,259 / Fieser 11 ,277 / Fieser 13 ,153
  • Aldrich MSDS 1 , 1121:B / Corp MSDS 1 (1), 2037:A / FT-IR 2 (2), 3322:C / FT-IR 1 (2), 542:A / FT-NMR 1 (2), 1662:B / NMR-Reference 2 (2), 879:D / RegBook 1 (2), 2267:J / Sigma FT-IR 1 (2), 671:B / Structure Index 1 , 355:E:3
  • Ligand for the in situ preparation of chiral hydrogenation catalysts: J. Am. Chem. Soc., 94, 6429 (1972); Helv. Chim. Acta, 57, 2487 (1974); J. Org. Chem., 44, 3741 (1979).
  • Ligand for the in situ preparation of chiral hydrogenation catalysts: J. Am. Chem. Soc., 94, 6429 (1972); Helv. Chim. Acta, 57, 2487 (1974); J. Org. Chem., 44, 3741 (1979).

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338+P337+P313
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word
Safety Statements
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Air Sensitive

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. DIOP - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. DIOP - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Dioxanes & Dioxolanes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes
  5. Cinchona Alkaloids
  1. Functional Group 官能团索引
  2. phosphine
  1. Phosphine
  2. Phosphorus
  1. Ligands
  2. Phosphorus
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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