((4R,5R)-2,2-Dimethyl-1,3-Dioxolane-4,5-Diyl)Dimethanol 2,3-o-异亚丙基-d-苏醇

CAS 73346-74-4 MFCD00009761

化学结构图

73346-74-4
SMILES: CC1(C)O[C@@H](CO)[C@H](CO)O1 |&1:4,7|

化学属性

Mol. FormulaC7H14O4
Mol. Weight162
Melting Point47.0 to 52.0 deg-C
Boiling Point96°C/0.7mmHg(lit.)
Flash Point>110°(230°F)
TSCANo
Refractive index-4 ° (C=5, Acetone)

别名和识别编码

Chemical Name((4R,5R)-2,2-Dimethyl-1,3-Dioxolane-4,5-Diyl)Dimethanol
CAS Number73346-74-4
Synonym (-)-2,3-O-亚异丙基-D-苏 2,3-O-isopropylidene threitol 2,2-O-ISOPROPYLIDENE-D-THREITOL,99% (-)-2,3-O-异亚丙基-D-苏糖醇 (4R,5R)-(-)-2,2-二甲基-1,3-二氧戊环-4,5-二甲醇 (4R,5R)-4,5-双(羟甲基)-2,2-二甲基-1,3-二氧戊环 (4S,5R)-(-)-4,5-BIS(HYDROXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE (-)-2,3-O-Isopropylidene-D-threitol (4R,5R)-(-)-2,2-Dimethyl-1,3-dioxolane-4,5-dimethanol, (4R,5R)-4,5-Bis(hydroxymethyl)-2,2-dimethyl-1,3-dioxolane 2,3-DI-O-ISOPROPYLIDENE-D-THREITOL (4R,5R)- 1,3-Dioxolane-4,5-dimethanol, 2,2-dimethyl-, (4R,5R)- (-)-2,3-O-ISOPROPYLIDINE-D-THREITOL 2,3-O-ISOPROPYLIDENE-D-THREITOL 2,3-O-异亚丙基-D-苏醇 (-)-2,3-O-异丙亚基-D-苏醇 (4R,5R)-(-)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DIMETHANOL (4R,5R)-4,5-BIS(HYDROXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE (4R,5R)-2,2-Dimethyl-1,3-dioxolane-4,5-dimethanol 2,3-O-异丙二烯-D-苏醇 (4R,5R)-(-)-4,5-BIS(HYDROXYMETHYL)-2,2-DIMETHYL-1,3-DIOXOLANE (-)-2,3-O-ISOPROPYLIDENE-D-THREITOL (4R-TRANS) 1,3-DIOXOLANE-4,5-DIMETHANOL-2,2-DIMETHYL BUTANOIC ACID (-)-2,3-O-Isopropylidene-D-threitol, (4R,5R)-4,5-Bis(hydroxymethyl)-2,2-dimethyl-1,3-dioxolane D(-)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DIMETHANOL (4R,5R)-4,5-双(羟甲基)-2,2-二甲基-1,3-二氧戊环 (4R,5R)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DIMETHANOL (4R,5R)-2,2-二甲基-1,3-二氧戊环-4,5-二甲醇 (4R-TRANS)-2,2-DIMETHYL-1,3-DIOXOLANE-4,5-DIMETHANOL (4R,5R)-(-)-2,2-二甲基-1,3-二氧戊环-4,5-二甲醇 (-)-2,3-O-异亚丙基-D-苏糖醇 (-)-2,3-O-亚异丙基-D-苏力糖醇 (+)-2,3-O-ISOPROPYLIDINE-D-THREITOL
MDL NumberMFCD00009761
PubChem Substance ID87571728
Beilstein Registry Number19(3/4)971
EC Number277-391-1
Reaxys-RN1798
Chemical Name Translation2,3-o-异亚丙基-d-苏醇
InChIKeyINVRLGIKFANLFP-UHFFFAOYSA-N
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分类

  • {SNA} Carbohydrate Chemistry, Carbohydrate Derivatives, Chemical Biology, Chemical Synthesis
  • Chiral Reagents
  • Heterocycles
  • {SA} Alcohols, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks

产品应用

  • Used in the synthesis of the optically active enantiomorphic 2,3-butanediols

相关文献及参考

  • Chiral intermediate: J. Am. Chem. Soc., 94, 6429 (1972).
  • Haines, A.H., et al.: J. Med. Chem., 32, 742 (1989),

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Storage condition <;0 <0°C 0-6°C Hygroscopic
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;

其他信息

  • Acros Organics:(-)-2,3-O-Isopropylidene-D-threitol, 99%(73346-74-4)
  • 比旋光度:-3.1 ° (c=5, CHCl3 26 °C)
  • F:3-10
  • MSDS 信息:(-)-2,3-O-Isopropylidene-D-threitol(73346-74-4).msds
  • (-)-2,3-O-亚异丙基-D-苏力糖醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 I0375 (-)-2,3-O-异亚丙基-D-苏糖醇 (-)-2,3-O-Isopropylidene-D-threitol 5G 1960元 2014/06/02 I0375 (-)-2,3-O-异亚丙基-D-苏糖醇 (-)-2,3-O-Isopropylidene-D-threitol 1G 649元 2010/06/21 221022500 (-)-2,3-O-亚异丙基-D-苏力糖醇 (-)-2,3-O-Isopropylidene-D-threitol 99% 250 MG 211元
  • TCI Shanghai:(-)-2,3-O-异亚丙基-D-苏糖醇 (-)-2,3-O-Isopropylidene-D-threitol,>;97.0%(GC)(73346-74-4)
  • 海关编码:29329970
  • 敏感性:Hygroscopic
  • Alfa Aesar:2,3-O-异亚丙基-D-苏醇,98% (-)-2,3-O-Isopropylidene-D-threitol, 98%(73346-74-4)
  • MOL 文件:73346-74-4.mol
  • Sigma Aldrich:73346-74-4(sigmaaldrich)

系列性分类


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