p-Xylylenediamine 1,4-苯二甲胺

CAS 539-48-0 MFCD00009821

化学结构图

539-48-0
SMILES:

化学属性

Mol. FormulaC8H12N2
Mol. Weight136.20
Flash Point134°C
TSCAYes
Melting Point60-63°C
Boiling Point230 °C at 10 mmHg
Appearance 无色液体,有杏仁味。久露空气中呈黄色。相对密度1.055,沸点248℃,折射率1.5700,粘度与苯二甲酸二丁酯近似。溶于水和有机溶剂。
Density1.052
Stability对空气及湿度敏感

别名和识别编码

Chemical Namep-Xylylenediamine
MDL NumberMFCD00009821
CAS Number539-48-0
Synonym 1,4-Phenylenedimethanamine {LY} 1,4-Phenylenedimethanamine {} {LY} 1,4-Phenylenedimethanamine {} {} {LY} 1,4-Phenylenedimethanamine {} {} {} {LY} 1,4-Phenylenedimethanamine {} {} {} {} {LY} 1,4-Phenylenedimethanamine {} {} {} {} {} {LY} 1,4-Phenylenedimethanamine {} {} {} {} {} {} {LY} 1,4-Phenylenedimethanamine {} {} {} {} {} {} {} {LY} 1,4-Phenylenedimethanamine {} {} {} {} {} {} {} {} {LY} 1,4-Phenylenedimethanamine {} {} {} {} {} {} {} {} {} {LY} 1,4-Phenylenedimethanamine {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Phenylenedimethanamine {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Phenylenedimethanamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Phenylenedimethanamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Phenylenedimethanamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1,4-Phenylenedimethanamine
EC Number208-719-3
Beilstein Registry Number2206190
PubChem Substance ID87567597
Reaxys-RN2206190
Chemical Name Translation1,4-苯二甲胺
Wiswesser Line NotationZ1R D1Z
LabNetwork Molecule IDLN00195001
Canonical SMILESNCC1=CC=C(CN)C=C1
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分类

  • {SNA} Amine Monomers, Materials Science, Monomers, Polymer Science, Primary Amines
  • {SNA} Amine Monomers, Monomers, Polymer Science, Primary Amines, 材料科学

产品应用

  • 主要用于制造耐热、无毒、水下施工、加热快速固化的高性能环氧树脂固化剂,是聚氨酯树脂、合成功能性环氧树脂的原料,也用于橡胶助剂、光敏塑料、农药、涂料、尼龙制品、纤维整理剂、防锈剂、螯合剂、润滑剂、纸加工等方面也有应用。

相关文献及参考

  • Beilstein: 13,IV,296

安全信息

RTECSPF9000000
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Packing GroupII
UN Number
Risk Statements
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Air Sensitive {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from
GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Precautionary statements
  • P303+P361+P353+P310+P363
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P405 Store locked up. 上锁保管。
  • P304+P340
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P305+P351+P338
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
Signal word
Hazard Codes C
Hazard Class8

其他信息

  • 上游原料:二甲苯 --> 对二甲苯 --> 粗苯 --> 对苯二腈 --> 苯二甲胺
  • 用途一:用于环氧树脂、光敏尼龙、聚氨酯涂料等
  • 方法一:由间、对二甲苯的混合物作原料,经空气和氨进行氨氧化反应生成间、对苯二甲腈。再经水洗、烘干后,在4.5MPa压力和90℃下,在乙醇和氢氧化钾溶剂中进行催化加氢。反应液除去触媒,回收乙醇,减压蒸馏即得间、对混合苯二甲胺。
  • TCI Shanghai:对苯二甲胺 p-Xylylenediamine,>;99.0%(GC)(T)(539-48-0)
  • 敏感性:Air Sensitive
  • Alfa Aesar:对二亚甲苯二胺,97% p-Xylylenediamine, 97%(539-48-0)
  • Sigma Aldrich:539-48-0(sigmaaldrich)
  • 1,4-苯二甲胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D1018 对二亚甲苯二胺 p-Xylylenediamine 500G 6030元 2014/06/02 D1018 对二亚甲苯二胺 p-Xylylenediamine 25G 803元 2010/05/25 L02995 对二亚甲苯二胺, 97% p-Xylylenediamine, 97% 2g 265元
  • MOL 文件:539-48-0.mol
  • 无色液体,有杏仁味。久露空气中呈黄色。粘度与苯二甲酸二丁酯近似。溶于水和有机溶剂。
  • 图谱信息:1,4-苯二甲胺(539-48-0)质谱(MS) 1,4-苯二甲胺(539-48-0)核磁图( 1 HNMR) 1,4-苯二甲胺(539-48-0)核磁图( 13 CNMR) 1,4-苯二甲胺(539-48-0)红外图谱(IR1) 1,4-苯二甲胺(539-48-0)红外图谱(IR2)
  • F:2-10
  • 用途二:主要用于制造耐热、无毒、水下施工、加热快速固化的高性能环氧树脂固化剂,是聚氨酯树脂、合成功能性环氧树脂的原料,也用于橡胶助剂、光敏塑料、农药、涂料、尼龙制品、纤维整理剂、防锈剂、螯合剂、润滑剂、纸加工等方面也有应用。

系列性分类


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