4-((Trimethylsilyl)Oxy)Pent-3-En-2-One 4-((三甲基硅烷基)氧基)戊-3-烯-2-酮

CAS 13257-81-3 MFCD00009853

化学结构图

13257-81-3
SMILES: C/C(=C\C(C)=O)/O[Si](C)(C)C

化学属性

Mol. FormulaC8H16O2Si
Mol. Weight172.30
Refractive index1.4490 to 1.4520
Boiling Point58°C/4mmHg(lit.)
Density0.912 g/mL at 25 °C(lit.)
Flash Point35°C(lit.)

别名和识别编码

Chemical Name4-((Trimethylsilyl)Oxy)Pent-3-En-2-One
Synonym 4-(三甲基硅氧基)-3-戊烯-2-酮 乙酰丙酮烯醇三甲基硅烷酯 TMS acac 乙酰丙酮烯醇三甲基硅烷酯 TMS acac
CAS Number13257-81-3
PubChem Substance ID87577331
EC Number236-252-5
Beilstein Registry Number4(4)4003
MDL NumberMFCD00009853
Reaxys-RN1759078
Chemical Name Translation4-((三甲基硅烷基)氧基)戊-3-烯-2-酮
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分类

  • {SA} Analytical Reagents, Analytical/Chromatography, Derivatization Reagents, Derivatization Reagents GC, Reagents for Silylation, Silylation Reagents
  • {SNA} Building Blocks, Chemical Synthesis, Enol Ethers, Organic Building Blocks, Oxygen Compounds

相关文献及参考

  • Beil. 4 ,IV,4003
  • Aldrich MSDS 1 , 1801:A / Corp MSDS 1 (2), 3501:C / FT-IR 2 (3), 4397:D / FT-IR 1 (2), 1114:A / FT-NMR 1 (3), 682:B / RegBook 1 (2), 2983:B / Structure Index 1 , 472:E:5 / Vapor Phase 3 , 1657:C

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xi
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P370+P378
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning {} {} {} {} {} {} {} {TCI}
UN Number 1993
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Packing GroupIII
Hazard Class3

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Silylation Reagents - Derivatization Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Enol Ethers - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Enol Ethers - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Silicon Compounds for Organic Synthesis 硅化合物
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Fluka Reagents

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