Dicarbonylacetylacetonato Rhodium(I) 二羰基乙酰丙酮铑(I)
CAS 14874-82-9 MFCD00009884
化学结构图
SMILES: [C-]#[O+].[C-]#[O+].C/C(=C/C(C)=O)/O[Rh]
化学属性
| Mol. Formula | Rh(CO)2(C5H7O2) |
|---|---|
| Mol. Weight | 258.03 |
| Melting Point | 154-156 °C(lit.) |
| Solubility | Soluble in acetone |
| TSCA | No |
| Density | 0.94 |
| Appearance | greenish-red xtl. |
别名和识别编码
| Chemical Name | Dicarbonylacetylacetonato Rhodium(I) |
|---|---|
| Synonym | dicarbonyl(pentane-2,4-dionato-O,O')rhodium Acetylacetonatobis(carbonyl)rhodium Rhodium acetylacetonate dicarbonyl (Acetylacetonato)dicarbonylrhodium (I) Rhodium, dicarbonyl(2,4-pentanedionato-κO,κO' Dicarbonylacetylacetonatorhodium(I) (Acetylacetonato)dicarbonylrhodium(I) Rhodium(I) dicarbonyl acetylacetonate Dicarbonyl(2,4-pentanedionato)rhodium Dicarbonyl-acetylacetonato-rhodium(I) Dicarbonyl-(pentan-2,4-dionato)rhodium(I) Rhodium, dicarbonyl(2,4-pentanedionato)- Rh(CO)2acac 乙酰丙酮二羰基铑(I) 二羰基乙酰丙酮化铑(I) 二羰基乙酰丙酮铑(I) Dicarbonylacetylacetona Rhodium dicarbonylacetylacetonate Dicarbonylrhodium(I) acetylacetonate Rhodium biscarbonyl acetylacetonate |
| MDL Number | MFCD00009884 |
| PubChem Substance ID | 24857317 |
| CAS Number | 14874-82-9 |
| EC Number | 238-947-9 |
| Chemical Name Translation | 二羰基乙酰丙酮铑(I) |
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分类
- {SA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium
- Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Rhodium, Solution Deposition Precursors
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Rhodium, Solution Deposition Precursors, 材料科学
- {uni_hamburg} no charge; metal-organic; oxygen heterocycle; other heterocycle; 6RingOnly; 6ring; metal carbonyl; 1fragment; zwitterion
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium
相关文献及参考
- Miyaura has utilized this complex, in combination with a chelating phosphine ligand, for the conjugate addition of arylboronic acids to enones, to give saturated ketones: Organometallics, 16, 4339 (1997). Addition of aryl- and alkenylboronic acids to aldehydes to give secondary alcohols can also be brought about under similar conditions: Angew. Chem. Int. Ed., 37, 3279 (1998):
- An extension of these reactions to the addition of potassium alkenyl- and aryltrifluoroborates to aldehydes and enones has also been reported: Org. Lett., 1, 1683 (1999).
- Short: EINECS
- Short: IV/20B
- Catalyst for hydroformylation of alkenes with CO/H2 at atmospheric pressure to give enals: Angew. Chem. Int. Ed., 34, 1760 (1995).
- Short: III/5a
安全信息
WGK Germany3
GHS Symbol
Precautionary statements
Hazard statements
- H315 Causes skin irritation 会刺激皮肤
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H319 Causes serious eye irritation 严重刺激眼睛
- H301 Toxic if swallowed 吞食有毒
- H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes
T
Xi
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Signal word
Danger
Safety Statements
UN Number
UN2926
Risk Statements
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R25 Toxic if swallowed 吞咽有毒
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
- R44 Risk of explosion if heated under confinement 密封下加热有爆炸危险
- R11 Highly flammable 非常易燃
- R36 Irritating to eyes 刺激眼睛
- R53 May cause long-term adverse effects in the aquatic environment 对水生环境有长期的有害作用
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