4-Chlorophenylmagnesium bromide, 1.0 M solution in 2-MeTHF, J&Kseal; 4-氯苯基溴化镁
CAS 873-77-8 MFCD00009926
化学结构图
SMILES: Clc1ccc([Mg]Br)cc1
化学属性
| Mol. Formula | C6H4BrClMg |
|---|---|
| Mol. Weight | 215.76 |
| Density | 0.85 |
| TSCA | No |
| Stability | 对湿度,空气,热和光线敏感 |
| Danger-Level | - |
| pH | -:- |
| Redox | - |
别名和识别编码
| Chemical Name | 4-Chlorophenylmagnesium bromide, 1.0 M solution in 2-MeTHF, J&Kseal; |
|---|---|
| CAS Number | 873-77-8 |
| EC Number | 250-023-7 |
| Beilstein Registry Number | 2384789 |
| MDL Number | MFCD00009926 |
| PubChem Substance ID | 101888 |
| Synonym | 4-氯苯基溴化镁 溶液 4-氯苯基溴化镁 |
| Chemical Name Translation | 4-氯苯基溴化镁 |
| InChIKey | CDEMHJCJMMOFMB-UHFFFAOYSA-M |
| LabNetwork Molecule ID | LN01322714 |
| InChI | InChI=1S/C6H4Cl.BrH.Mg/c7-6-4-2-1-3-5-6;;/h2-5H;1H;/q-1;;+2/p-1 |
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分类
- {SNA} Aryl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents
相关文献及参考
- Beilstein: 16,937
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S8 Keep container dry 保持容器干燥；
- R11 Highly flammable 非常易燃
- R19 May form explosive peroxides 可能生成易爆的过氧化物质
- R14 Reacts violently with water 遇水会猛烈反应
- R34 Causes burns 会导致灼伤
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P316
- P317
- P301+P330+P331
- P233 Keep container tightly closed. ?保持容器密闭。
- P302+P361+P354
- P403+P235
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P405 Store locked up. 上锁保管。
- P303+P361+P353
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P354+P338
- P242 Use only non-sparking tools. 只能使用无火花工具。
- P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P304+P340
- P370+P378
- P264+P265
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H302 Harmful if swallowed 吞食有害
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
其他信息
- 和水剧烈反应。
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