Tert-Butyl Glycidyl Ether 叔丁基缩水甘油醚

CAS 7665-72-7 MFCD00010050

化学结构图

7665-72-7
SMILES: CC(C)(C)OCC1CO1

化学属性

Mol. FormulaC7H14O2
Mol. Weight130.18
Refractive index1.4160 to 1.4180
Density0.9145
Boiling Point150-152 °C at 760 mmHg
Flash Point44°C(lit.)
Melting Point-70 °C

别名和识别编码

Chemical NameTert-Butyl Glycidyl Ether
Synonym tert-Butyl glycidyl ether {LY} tert-Butyl glycidyl ether {} {LY} tert-Butyl glycidyl ether {} {} {LY} tert-Butyl glycidyl ether {} {} {} {LY} tert-Butyl glycidyl ether {} {} {} {} {LY} tert-Butyl glycidyl ether {} {} {} {} {} {LY} tert-Butyl glycidyl ether {} {} {} {} {} {} {LY} tert-Butyl glycidyl ether {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} tert-Butyl glycidyl ether {} {} {} {} {} {} {} {} {LY} tert-Butyl glycidyl ether {} {} {} {} {} {} {} {} {} {LY} tert-Butyl glycidyl ether {} {} {} {} {} {} {} {} {} {} {LY} tert-Butyl glycidyl ether {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} tert-Butyl glycidyl ether {} {} {} {} {} {} {} {} {} {} {} {} {LY} tert-Butyl glycidyl ether {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} tert-Butyl glycidyl ether {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} tert-Butyl glycidyl ether {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} tert-Butyl glycidyl ether {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number7665-72-7
PubChem Substance ID87564728
EC Number231-640-0
Beilstein Registry Number17(5)3,11
MDL NumberMFCD00010050
Reaxys-RN103483
Chemical Name Translation叔丁基缩水甘油醚
Wiswesser Line NotationT3OTJ B1OX1&1&1
InChIInChI=1S/C7H14O2/c1-7(2,3)9-5-6-4-8-6/h6H,4-5H2,1-3H3
LabNetwork Molecule IDLN01740602
Canonical SMILESO1CC1COC(C)(C)C
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分类

  • {SNA} Epoxide Monomers, Monomers, Polymer Science, 材料科学
  • {SNA} Epoxide Monomers, Materials Science, Monomers, Polymer Science

相关文献及参考

  • Beil. 17 ,V,3,11
  • Aldrich MSDS 1 , 322:B / Corp MSDS 1 (1), 632:D / FT-IR 1 (1), 232:C / FT-IR 2 (1), 367:C / FT-NMR 1 (1), 373:B / RegBook 1 (1), 251:A / Structure Index 1 , 34:C:2 / Vapor Phase 3 , 306:C

安全信息

GHS Symbol
WGK Germany2
Hazard Codes
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSRR0475000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P352+P333+P313+P362+P364
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P337+P313
  • P370+P378
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
UN Number 1993 3271
Risk Statements
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R10 Flammable 易燃
  • R36 Irritating to eyes 刺激眼睛
  • R22 Harmful if swallowed 吞咽有害
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Safety Statements
Packing GroupIII
Hazard Class3
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton,
   G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82.
   Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985.
   Volume(issue)/page/year: 2A,2202,1981

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 1250 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 249,55,1991

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 333 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 172,105,1986

TYPE OF TEST            : Body fluid assay
TEST SYSTEM             : Rodent - mouse Bacteria - Salmonella typhimurium
DOSE/DURATION           : 500 mg/kg/5D (Intermittent)
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 2,284,1980

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 1 umol/L
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 26(1),43,1982

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 3300 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 231,205,1990

Storage condition

其他信息

  • 可燃性危险特性:热分解排出有毒辛辣刺激烟雾
  • 储运特性:库房通风低温干燥
  • F:9-21
  • TCI Shanghai:叔丁基缩水甘油醚 tert-Butyl Glycidyl Ether,>;96.0%(GC)(7665-72-7)
  • MOL 文件:7665-72-7.mol
  • 毒性分级:中毒
  • 急性毒性:口服-大鼠 LD50: 2000 毫克/公斤
  • 叔丁基缩水甘油基醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1840 叔丁基缩水甘油醚 tert-Butyl Glycidyl Ether 500ML 1400元 2014/06/02 B1840 叔丁基缩水甘油醚 tert-Butyl Glycidyl Ether 25ML 278元
  • 灭火剂:水, 干粉, 二氧化碳, 泡沫
  • 上游原料:氢氧化钠 --> 乙醚 --> 二氯甲烷 --> 叔丁醇 --> 环氧氯丙烷 --> 三氟化硼乙醚
  • 类别:有毒物质
  • 图谱信息:叔丁基缩水甘油基醚(7665-72-7)核磁图( 13 CNMR) 叔丁基缩水甘油基醚(7665-72-7)质谱(MS) 叔丁基缩水甘油基醚(7665-72-7)红外图谱(IR1) 叔丁基缩水甘油基醚(7665-72-7)核磁图( 1 HNMR)
  • 用途一:用作活性稀释剂
  • Sigma Aldrich:7665-72-7(sigmaaldrich)

系列性分类


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