1,1’-(Azodicarbonyl)dipiperidine (ADDP) 偶氮二甲酰二哌啶
CAS 10465-81-3 MFCD00010111
化学结构图
SMILES: O=C(/N=N/C(=O)N1CCCCC1)N1CCCCC1
化学属性
| Mol. Formula | C12H20N4O2 |
|---|---|
| Mol. Weight | 252 |
| Melting Point | 134.0 to 137.0 deg-C |
| TSCA | No |
| Density | 1.422 |
别名和识别编码
| Chemical Name | 1,1’-(Azodicarbonyl)dipiperidine (ADDP) |
|---|---|
| Synonym | Azodicarboxylic acid dipiperidine diazenedicarboxylic acid bis(N,N-piperidide) Bis(piperidinocarbonyl)diazene ADDP (1,1-Aza dicarbonyl di piperidine) ADD, ADDP, Azodicarboxylic dipiperidide 1,1-IAZODICARBONYL)DIPIPERIDINE 1,1'-(AZODICARBONYL)DIPIPERIDINE sr4077 Bis(piperidinocarbonyl)diimide ADDP Diphenylpiperidylcarboxylate 1,1'-(偶氮二羰基)二哌啶,97% 1,1'-(azodicarbonyl)piperidine ADD, Azodicarboxylic acid dipiperidide 1,1'-(Azodicarbonyl)bispiperidine 1,1'-(Azobiscarbonyl)dipiperidine 偶氮二甲酰二哌啶 AZODICARBOXYLIC DIPIPERIDIDE 1,1'-Azobis(N,N-pentamethyleneformamide) ADD NSC 356027 SR 4077 偶氮二甲酰二哌啶 AZODICARBOXYLIC ACID DIPIPERIDYL ESTER 1,1'-(偶氮二羰基)二哌啶 AZODICARBOXYLIC ACID DIPIPERIDIDE 1,1′-Azobis(N,N-pentamethyleneformamide) ADD NSC 356027 SR 4077 偶氮二甲酰二哌啶 Azodicarboxylic |
| MDL Number | MFCD00010111 |
| PubChem Substance ID | 87562542 |
| Beilstein Registry Number | 20(1)17 |
| CAS Number | 10465-81-3 |
| EC Number | 250-023-7 |
| Reaxys-RN | 261917 |
| Chemical Name Translation | 偶氮二甲酰二哌啶 |
| InChIKey | OQJBFFCUFALWQL-BUHFOSPRSA-N |
| LabNetwork Molecule ID | LN00225199 |
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分类
- {SNA} C-X Bond Formation (Non-Halogen), Chemical Synthesis, Mitsunobu, Synthetic Reagents
产品应用
- 广泛用于 Mitsunobu 反应的试剂
- 用于研究芳基硼酸通过铜催化加成得到偶氮二甲酸衍生物，从而生成芳基取代酰肼的反应。
相关文献及参考
- Reagent for the Mitsunobu reaction (see Diethyl azodicarboxylate, L19348), used in combination with tri-n-butylphosphine as a more powerful system than DEAD for higher pKa nucleophiles: Tetrahedon Lett., 34, 1639 (1993); Tetrahedron, 61, 6218 (2005). Has also been utilized in a selective method for converting primary and secondary alcohols to carbonyl compounds, by reaction of the alcohol with a Grignard reagent, followed by oxidation of the intermediate magnesio-derivative with ADDP: J. Org. Chem., 38, 1652 (1973); Bull. Chem. Soc. Jpn., 2773 (1977).
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P312+P330
- P302+P352+P312+P362+P364
- P304+P340+P312
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H302+H312+H332
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- 偶氮二甲酰二哌啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 A1051 1,1'-(偶氮二羰基)二哌啶 1,1'-(Azodicarbonyl)dipiperidine 5G 862元 2011/04/16 A1051 1,1'-(偶氮二羰基)二哌啶 1,1'-(Azodicarbonyl)dipiperidine 25G 2860元 2010/05/25 H27719 1,1'-(偶氮二羰基)二哌啶,97% 1,1'-(Azodicarbonyl)dipiperidine, 97% 5g 1023元
- TCI Shanghai:偶氮二甲酰二哌啶 1,1'-(Azodicarbonyl)dipiperidine,>;98.0%(N)(10465-81-3)
- MOL 文件:10465-81-3.mol
- 图谱信息:偶氮二甲酰二哌啶(10465-81-3)质谱(MS)
- Sigma Aldrich:10465-81-3(sigmaaldrich)
- Alfa Aesar:1,1'-(偶氮二羰基)二哌啶,97% 1,1'-(Azodicarbonyl)dipiperidine, 97%(10465-81-3)
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