3-Methyl-3-oxetanemethanol 3-甲基-3-羟甲基氧杂环丁烷
CAS 3143-02-0 MFCD00010273
化学结构图
SMILES: CC1(CO)COC1
化学属性
| Mol. Formula | C5H10O2 |
|---|---|
| Mol. Weight | 102.13 |
| Refractive index | 1.4430 to 1.4470 |
| Boiling Point | 80 °C at 40 mmHg |
| Density | 1.024 |
| Flash Point | 97°C |
| TSCA | No |
别名和识别编码
| Chemical Name | 3-Methyl-3-oxetanemethanol |
|---|---|
| CAS Number | 3143-02-0 |
| Alfabeta Name | METHYLOXETANYLMETHANOL 33()--- |
| MDL Number | MFCD00010273 |
| Synonym | 3-Methyl-3-oxetanemethanol {LY} 3-Methyl-3-oxetanemethanol {} {LY} 3-Methyl-3-oxetanemethanol {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {} {} {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {} {} {} {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} |
| PubChem Substance ID | 137837 |
| Beilstein Registry Number | 102773 |
| EC Number | 000-000-0 |
| Reaxys-RN | 102773 |
| Chemical Name Translation | 3-甲基-3-羟甲基氧杂环丁烷 |
| InChIKey | NLQMSBJFLQPLIJ-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00174216 |
| InChI | InChI=1S/C5H10O2/c1-5(2-6)3-7-4-5/h6H,2-4H2,1H3 |
| Canonical SMILES | C(C1(COC1)C)O |
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分类
- {SNA} Alcohols, Asymmetric Synthesis, Building Blocks, C2 to C6, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Organic Building Blocks, Oxetanes, Oxygen Compounds
相关文献及参考
- Beilstein:17(3/4)1128
- Reacts with nucleophiles to give 2-substituted 2-methyl-1,3-propanediols; e.g. dialkylamines, on heating under pressure at 180o, give 2-(N,N-dialkylaminomethyl)-2-methylpropane-1,3-diols, and aqueous hydrogen halides give the corresponding 2-halomethyl compounds: Liebigs Ann. Chem., 365 (1973).
- Valuable protecting agent for carboxylic acids, introduced by Corey. The oxetane ester, formed from the acid chloride, rearranges with BF3 etherate to the bridged 2,6,7-trioxabicyclo[2.2.2]octane [OBO] orthoester, stable to strong bases and nucleophiles, e.g. Grignards, but readily cleaved by mild acid, followed by saponification of the ester: J. Am. Chem. Soc., 103, 4618 (1991); 106, 2735 (1984); Tetrahedron Lett., 23, 1651 (1982); 24, 5571 (1983); 27, 2199 (1986):
安全信息
Warnings
IRRITANT
GHS Symbol
WGK Germany3
Hazard statements
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H302 Harmful if swallowed 吞食有害
Personal Protective Equipment
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
Signal word
Warning
Safety Statements
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Hazard Codes
Xi
Risk Statements
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Storage condition
Store at room temperature
{LY} Store at room temperature
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其他信息
- 3-甲基-3-羟甲基氧杂环丁烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 M1136 3-甲基-3-氧杂环丁烷甲醇 3-Methyl-3-oxetanemethanol 5G 284元 2011/04/16 M1136 3-甲基-3-氧杂环丁烷甲醇 3-Methyl-3-oxetanemethanol 25G 851元 2010/06/21 240840100 3-甲基-3-羟甲基氧杂环丁烷 3-Methyl-3-oxetanemethanol 98% 10 GR 492元
- 3-甲基-3-羟甲基氧杂环丁烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M1136 3-甲基-3-氧杂环丁烷甲醇 3-Methyl-3-oxetanemethanol 5G 260元 2014/06/02 M1136 3-甲基-3-氧杂环丁烷甲醇 3-Methyl-3-oxetanemethanol 25G 785元 2010/06/21 240840100 3-甲基-3-羟甲基氧杂环丁烷 3-Methyl-3-oxetanemethanol 98% 10 GR 492元
- Alfa Aesar:3-甲基-3-氧杂环丁烷甲醇,97% 3-Methyl-3-oxetanemethanol, 97%(3143-02-0)
- TCI Shanghai:3-甲基-3-氧杂环丁烷甲醇 3-Methyl-3-oxetanemethanol,>;96.0%(GC)(3143-02-0)
- Sigma Aldrich:3143-02-0(sigmaaldrich)
- MOL 文件:3143-02-0.mol
- Acros Organics:3-Methyl-3-oxetanemethanol, 98%(3143-02-0)
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