3-Methyl-3-oxetanemethanol 3-甲基-3-羟甲基氧杂环丁烷

CAS 3143-02-0 MFCD00010273

化学结构图

3143-02-0
SMILES: CC1(CO)COC1

化学属性

Mol. FormulaC5H10O2
Mol. Weight102.13
Refractive index1.4430 to 1.4470
Boiling Point80 °C at 40 mmHg
Density1.024
Flash Point97°C
TSCANo

别名和识别编码

Chemical Name3-Methyl-3-oxetanemethanol
CAS Number3143-02-0
Alfabeta NameMETHYLOXETANYLMETHANOL 33()---
MDL NumberMFCD00010273
Synonym 3-Methyl-3-oxetanemethanol {LY} 3-Methyl-3-oxetanemethanol {} {LY} 3-Methyl-3-oxetanemethanol {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {} {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {} {} {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {} {} {} {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Methyl-3-oxetanemethanol {} {} {} {} {} {} {} {} {} {} {} {
PubChem Substance ID137837
Beilstein Registry Number102773
EC Number000-000-0
Reaxys-RN102773
Chemical Name Translation3-甲基-3-羟甲基氧杂环丁烷
InChIKeyNLQMSBJFLQPLIJ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00174216
InChIInChI=1S/C5H10O2/c1-5(2-6)3-7-4-5/h6H,2-4H2,1H3
Canonical SMILESC(C1(COC1)C)O
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分类

  • {SNA} Alcohols, Asymmetric Synthesis, Building Blocks, C2 to C6, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Organic Building Blocks, Oxetanes, Oxygen Compounds

相关文献及参考

  • Beilstein:17(3/4)1128
  • Reacts with nucleophiles to give 2-substituted 2-methyl-1,3-propanediols; e.g. dialkylamines, on heating under pressure at 180o, give 2-(N,N-dialkylaminomethyl)-2-methylpropane-1,3-diols, and aqueous hydrogen halides give the corresponding 2-halomethyl compounds: Liebigs Ann. Chem., 365 (1973).
  • Valuable protecting agent for carboxylic acids, introduced by Corey. The oxetane ester, formed from the acid chloride, rearranges with BF3 etherate to the bridged 2,6,7-trioxabicyclo[2.2.2]octane [OBO] orthoester, stable to strong bases and nucleophiles, e.g. Grignards, but readily cleaved by mild acid, followed by saponification of the ester: J. Am. Chem. Soc., 103, 4618 (1991); 106, 2735 (1984); Tetrahedron Lett., 23, 1651 (1982); 24, 5571 (1983); 27, 2199 (1986):

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard statements
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
Signal word Warning
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
Hazard Codes Xi
Risk Statements
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 3-甲基-3-羟甲基氧杂环丁烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 M1136 3-甲基-3-氧杂环丁烷甲醇 3-Methyl-3-oxetanemethanol 5G 284元 2011/04/16 M1136 3-甲基-3-氧杂环丁烷甲醇 3-Methyl-3-oxetanemethanol 25G 851元 2010/06/21 240840100 3-甲基-3-羟甲基氧杂环丁烷 3-Methyl-3-oxetanemethanol 98% 10 GR 492元
  • 3-甲基-3-羟甲基氧杂环丁烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M1136 3-甲基-3-氧杂环丁烷甲醇 3-Methyl-3-oxetanemethanol 5G 260元 2014/06/02 M1136 3-甲基-3-氧杂环丁烷甲醇 3-Methyl-3-oxetanemethanol 25G 785元 2010/06/21 240840100 3-甲基-3-羟甲基氧杂环丁烷 3-Methyl-3-oxetanemethanol 98% 10 GR 492元
  • Alfa Aesar:3-甲基-3-氧杂环丁烷甲醇,97% 3-Methyl-3-oxetanemethanol, 97%(3143-02-0)
  • TCI Shanghai:3-甲基-3-氧杂环丁烷甲醇 3-Methyl-3-oxetanemethanol,>;96.0%(GC)(3143-02-0)
  • Sigma Aldrich:3143-02-0(sigmaaldrich)
  • MOL 文件:3143-02-0.mol
  • Acros Organics:3-Methyl-3-oxetanemethanol, 98%(3143-02-0)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Mercury - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Alcohols - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Alcohols - Oxygen Compounds
  6. C2 to C6 - Alcohols
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Alcohols - Oxygen Compounds
  6. C2 to C6 - Alcohols
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Simple 4-Membered Ring Compounds

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