(S)-(-)-2-(Methoxymethyl)-1-Pyrrolidinecarboxaldehyde (S)-(-)-2-(甲氧基甲基)-1-吡咯烷甲醛

CAS 63126-45-4 MFCD00010279

化学结构图

63126-45-4
SMILES: COC[C@@H]1CCCN1C=O

化学属性

Mol. FormulaC7H13NO2
Mol. Weight143.19
Refractive indexn20/D 1.4755(lit.)
Boiling Point67 °C/0.25 mmHg(lit.)
Density1.057 g/mL at 25 °C(lit.)

别名和识别编码

Chemical Name(S)-(-)-2-(Methoxymethyl)-1-Pyrrolidinecarboxaldehyde
Synonym (S)-(-)-1-甲酰基-2-(甲氧基甲基)吡咯烷 (S)-(-)-2-(甲氧基甲基)-1-吡咯烷甲醛 (S)-(-)-1-甲酰基-2-(甲氧基甲基)吡咯烷 (S)-(-)-2-(甲氧基甲基)吡咯烷-1-甲醛 (S)-(-)-2-(甲氧基甲基)吡咯烷-1-甲醛
CAS Number63126-45-4
PubChem Substance ID87573124
Beilstein Registry Number21(5)1,85
MDL NumberMFCD00010279
Reaxys-RN3538262
Chemical Name Translation(S)-(-)-2-(甲氧基甲基)-1-吡咯烷甲醛
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Pyrrolidines
  • {SA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Heterocyclic Building Blocks, Pyrrolidines

相关文献及参考

  • Aldrich MSDS 1 , 1187:C / Corp MSDS 1 (2), 2256:D / RegBook 1 (1), 527:G / Sigma FT-IR 1 (2), 712:B / Vapor Phase 3 , 571:B
  • Beil. 21 ,V,1,85
  • Fieser 10 ,259

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P337+P313
  • P302+P352+P332+P313+P362+P364
Signal word Warning
Storage condition 0-10 0-10°C
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Heterocyclic Building Blocks - Chiral Building Blocks
  5. Pyrrolidines - Heterocyclic Building Blocks

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