(R)-(+)-3-Bromo-2-Methylpropionic Acid Methyl Ester (R)-(+)-3-溴代异丁酸甲酯

CAS 110556-33-7 MFCD00010639

化学结构图

110556-33-7
SMILES: COC(=O)[C@@H](C)CBr

化学属性

Mol. FormulaBrCH2CH(CH3)CO2CH3
Mol. Weight181.03
Refractive indexn20/D 1.455(lit.)
Boiling Point85 °C/37 mmHg(lit.)
Density1.422 g/mL at 25 °C(lit.)
Flash Point73°C(lit.)

别名和识别编码

Chemical Name(R)-(+)-3-Bromo-2-Methylpropionic Acid Methyl Ester
Synonym {uni_hamburg} (R)-3-bromo-2-methyl-propionic acid methyl ester (R)-(+)-3-溴-2-甲基丙酸甲酯 Methyl (R)-(+)-3-bromo-2-methylpropionate R(+)-3-Brom-2-methyl-propionsäuremethylester (+)-(R)-β-溴异丁酸甲酯 (+)-(R)-β-溴异丁酸甲酯 (+)-Methyl (R)-3-bromo-2-methyl propionate
CAS Number110556-33-7
PubChem Substance ID24859486
Beilstein Registry Number1720833
MDL NumberMFCD00010639
Reaxys-RN1720833
Chemical Name Translation(R)-(+)-3-溴代异丁酸甲酯
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Esters, Organic Building Blocks
  • {uni_hamburg} no charge; ester; chiral; 1fragment
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Esters, Organic Building Blocks

相关文献及参考

  • Short: III/38B

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xi
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P337+P313
  • P302+P352+P332+P313+P362+P364
  • P403+P235
Signal word {} {TCI} Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Esters - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Esters - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块

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