Diallyl maleate 马来酸二烯丙酯

CAS 999-21-3 MFCD00010763

化学结构图

999-21-3
SMILES: C=CCOC(=O)/C=C\C(=O)OCC=C

化学属性

Mol. FormulaC10H12O4
Mol. Weight196.20
Density1.074
Refractive index1.4660 to 1.4700
Vapor Density6.6 (vs air)
Boiling Point263.7°C at 760 mmHg
Vapor Pressure4 mmHg ( 25 °C)
Melting Point-47°C
Flash Point>110°C
TSCAYes

别名和识别编码

Chemical NameDiallyl maleate
Synonym Diallyl maleate {LY} Diallyl maleate {} {LY} Diallyl maleate {} {} {LY} Diallyl maleate {} {} {} {LY} Diallyl maleate {} {} {} {} {LY} Diallyl maleate {} {} {} {} {} {LY} Diallyl maleate {} {} {} {} {} {} {LY} Diallyl maleate {} {} {} {} {} {} {} {LY} Diallyl maleate {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} Diallyl maleate {} {} {} {} {} {} {} {} {} {LY} Diallyl maleate {} {} {} {} {} {} {} {} {} {} {LY} Diallyl maleate {} {} {} {} {} {} {} {} {} {} {} {LY} Diallyl maleate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diallyl maleate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diallyl maleate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diallyl maleate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diallyl maleate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diallyl maleate {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00010763
CAS Number999-21-3
EC Number213-658-0
Beilstein Registry Number1725954
PubChem Substance ID5354266
Reaxys-RN1725954
Chemical Name Translation马来酸二烯丙酯
Wiswesser Line Notation1U2OV1U1VO2U1
LabNetwork Molecule IDLN01742910
InChIInChI=1S/C10H12O4/c1-3-7-13-9(11)5-6-10(12)14-8-4-2/h3-6H,1-2,7-8H2/b6-5-
Canonical SMILESC=CCOC(/C=C\C(OCC=C)=O)=O
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分类

  • {uni_hamburg} no charge; ester; 1fragment
  • {SNA} Allyl Monomers, Monomers, Polymer Science, 材料科学
  • {SNA} Allyl Monomers, Materials Science, Monomers, Polymer Science

产品应用

  • 有机中间体。

相关文献及参考

  • Short: III/38B
  • Short: EINECS
  • Short: IV/20B
  • Short: IV/18B
  • Beilstein:2(4)2214

安全信息

Signal word Danger Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R20/21 Harmful by inhalation and in contact with skin 吸入及与皮肤接触有害
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P330
  • P302+P352+P312+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P332+P313
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H312 Harmful in contact with skin 皮肤接触有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSON0700000
Packing GroupIII
UN Number 2810 UN2810
Hazard Codes 6.1 Xn
Hazard Class6.1 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1150 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 31,60,1949

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 31,60,1949

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 160 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   SCCUR* Shell Chemical Company.  Unpublished Report.  (2401 Crow Canyon Rd.,
   San Romon, CA 94583)  Volume(issue)/page/year: -,3,1961

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 493 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   SCCUR* Shell Chemical Company.  Unpublished Report.  (2401 Crow Canyon Rd.,
   San Romon, CA 94583)  Volume(issue)/page/year: -,3,1961

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 用途一:有机中间体。
  • Sigma Aldrich:999-21-3(sigmaaldrich)
  • 上游原料:二氯甲烷 --> 对甲苯磺酸 --> 马来酸酐 --> 铜 --> 丙烯醇
  • 刺激性。溶于甲醇。
  • 方法一:顺丁烯二酸酐与丙烯醇在硫酸催化下酯化而得。原料消耗定额：顺丁烯二酸酐625kg/t、丙烯醇832kg/t。
  • 图谱信息:马来酸二烯丙酯(Z)-2-丁烯二酸,二-2-丙烯基酯 (999-21-3)红外图谱(IR2) 马来酸二烯丙酯(Z)-2-丁烯二酸,二-2-丙烯基酯 (999-21-3)核磁图( 13 CNMR) 马来酸二烯丙酯(Z)-2-丁烯二酸,二-2-丙烯基酯 (999-21-3)红外图谱(IR1) 马来酸二烯丙酯(Z)-2-丁烯二酸,二-2-丙烯基酯 (999-21-3)Raman光谱 马来酸二烯丙酯(Z)-2-丁烯二酸,二-2-丙烯基酯 (999-21-3)质谱(MS)
  • 蒸气密度:6.6 (vs air)
  • Alfa Aesar:顺丁二烯酸二烯丙酯,95% Diallyl maleate, 95%(999-21-3)
  • 外观性质:无色至淡黄色液体。
  • MSDS 信息:马来酸二烯丙酯(999-21-3).msds
  • 蒸气压:4 mm Hg ( 25 °C)
  • TCI Shanghai:(Z)-2-丁烯二酸,二-2-丙烯基酯(含稳定剂氢醌) Diallyl Maleate (stabilized with HQ),>;97.0%(GC)(999-21-3)
  • MOL 文件:999-21-3.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  6. C10 to C11 - Esters
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Monomers - Polymer Science
  4. Allyl Monomers - Monomers

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