(2R)-(-)-Glycidyl Tosylate (2R)-(-)-对甲苯磺酸缩水甘油酯

CAS 113826-06-5 MFCD00010834

化学结构图

113826-06-5
SMILES: CC1=CC=C(C=C1)S(=O)(=O)OC[C@@H]1CO1 |&1:12|

化学属性

Mol. FormulaC10H12O4S
Mol. Weight228
Melting Point47.0 to 50.0 deg-C
Flash Point113°(235°F)
TSCANo
Density1.31

别名和识别编码

Chemical Name(2R)-(-)-Glycidyl Tosylate
CAS Number113826-06-5
Alfabeta NameGLYCIDYLTOSYLATE R(())---
MDL NumberMFCD00010834
Synonym (R)-Glycidyl tosylate (R)-(-)-缩水甘油基甲苯磺酸酯 (R)-(-)-Oxiran-2-ylmethyl 4-Methylbenzenesulfonate (2R)-(-)-缩水甘油基对甲苯磺酸酯 (2R)-(-)-对甲苯磺酸缩水甘油酯 (R)-(-)-环氧乙烷-2-甲醇 对甲苯磺酸盐 (R)-(-)-缩水甘油基对甲苯磺酸酯
PubChem Substance ID24878442
Beilstein Registry Number17(5)3,47
Reaxys-RN3592142
EC Number250-023-7
Chemical Name Translation(2R)-(-)-对甲苯磺酸缩水甘油酯
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Epoxides, Organic Building Blocks
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Epoxides, Organic Building Blocks

产品应用

  • Protected Glycidol, used as an intermediate in the preparation of neurochemicals.

相关文献及参考

  • Beilstein:17(5)3,47
  • Shimizu, K., et al.: Bioorg. Med. Chem., 14, 1838 (2006),
  • Qian, L., et al.: ChemMedChem., 1, 376 (2006),

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard Codes T,N
Hazard statements
  • H302+H312+H332
  • H318 Causes serious eye damage 严重伤害眼睛
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H350 May cause cancer 可能致癌
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSRR0510000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P350
  • P302+P352+P312+P362+P364
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P308+P313
  • P332+P313
  • P337+P313
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Safety Statements
  • S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
UN Number UN3077
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R51/53
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
  • R45 May cause cancer 可能致癌
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Packing GroupIII 
TYPE OF TEST            : Mutation test systems - not otherwise specified
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 298,197,1993

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 330 nmol/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 298,197,1993

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Epoxides - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Epoxides - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Simple 3-Membered Ring Compounds 简单三元环化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carboxylic Acids 羧酸

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