Ammonium hexafluorosilicate 六氟硅酸铵

CAS 16919-19-0 MFCD00010887

化学结构图

16919-19-0
SMILES: [NH4+].[NH4+].F[Si-2](F)(F)(F)(F)F

化学属性

Mol. Formula(NH4)2SiF6
Mol. Weight178
Density2.01 g/mL at 25 °C(lit.)
Melting Pointdec.
SolubilitySlightly soluble in water. Insoluble in alcohol, acetone
TSCAYes

别名和识别编码

Chemical NameAmmonium hexafluorosilicate
Synonym AMMONIUM FLUOSILICATE ammonium fluoro epapesticidechemicalcode075301 {Chemical Diammonium fluosilicate ((NH4)2SiF6) caswellno043 Diammonium fluosilicate Silicate(2-),hexafluoro-,diammonium Ammonium fluorosilicate ((NH4)2SiF6) Ammonium silicon fluoride Ammonium silicofluoride Ammoniumhexafluorsilikat AMMONIUM SILICOFLUORIDE LPE 6 Diammonium hexafluorosilicate(2-) diammonio hexafluorosilicate diammoniumsiliconhexafluoride 六氟硅酸铵 Ammonium silicon diammoniumfluorosilicate Diammonium fluorosilicate Ammonium fluorosilicate Ammonium fluosilicate Ammonium silicfluoride diammoniumhexafluorosilicate 六氟硅 {Chemica
MDL NumberMFCD00010887
PubChem Substance ID24863149
EC Number240-968-3
CAS Number16919-19-0
Merck Number14,527
Chemical Name Translation六氟硅酸铵
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分类

  • {SNA} Ammonium Salts, Essential Chemicals, Metal and Ceramic Science, NH3, Research Essentials, Salts, Ultra-High Purity Materials, 材料科学
  • {uni_hamburg} no charge; 3fragments; ionic
  • {SNA} Ammonium Salts, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Salts,

相关文献及参考

  • Short: III/35F Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Silicon-29 Author: Marsmann, H.C.; Uhlig, F.; Gupta, R.R.; Lechner, M.D.; Mikhova, B.M. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35F Year: 2008 Keyword: NMR; Si-29; chemical shifts; coupling constants; nuclear magnetic resonance; silicon-29 ISBN: 978-3-540-45277-5 (print) ISBN: 978-3-540-45278-2 (electronic) Internet Resource: DOI: 10.1007/978-3-540-45278-2 RefComment: X, 463 p. 40 illus., Hardcover RefComment: Written for: Scientists and engineers in the fields of physics, chemistry, and physical chemistry who intend to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, oriented by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment, i.e. the structure and interaction of the molecules. NMR is now the leading technique and a powerful tool for the investigation of the structure and interaction of molecules. The present Landolt-Börnstein volume III/35 "Nuclear Magnetic Resonance (NMR) Data" is therefore of major interest to all scientists and engineers who intend to use NMR to study the structure and the binding of molecules. Volume III/35 ''NMR-Data'' is divided into several subvolumes and parts. Subvolume III/35A contains the nuclei B-11 and P-31, subvolume III/35B contains the nuclei F-19 and N-15, subvolume III/35C contains the nucleus H-1, subvolume III/35D contains the nucleus C-13, subvolume III/35E contains the nucleus O-17, subvolume III/35F contains the nucleus Si-29, and subvolume III/35G contains the nucleus Se-77. More nuclei will be presented later.
  • Short: EINECS Title: EINECS (European Inventory of Existin

安全信息

WGK Germany2
Precautionary statements
  • P301+P310
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
Signal word Danger
Hazard statements
  • H301+H311+H331
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
RTECSVV7800000
GHS Symbol
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Packing GroupIII
UN Number UN2854 2854 UN 2854 6.1/PG 3
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
Hazard Codes T
Hazard Class6.1
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Amphibian - frog
DOSE/DURATION           : 224 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CRSBAW Comptes Rendus des Seances de la Societe de Biologie et de Ses
   Filiales.  (SPPIF, B.P.22, F-41353 Vineuil, France)  V.1-    1849-
   Volume(issue)/page/year: 124,133,1937

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 150 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CRSBAW Comptes Rendus des Seances de la Societe de Biologie et de Ses
   Filiales.  (SPPIF, B.P.22, F-41353 Vineuil, France)  V.1-    1849-
   Volume(issue)/page/year: 124,133,1937

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCNSA6 National Academy of Sciences, National Research Council,
   Chemical-Biological Coordination Center, Review.  (Washington, DC)
   Volume(issue)/page/year: 5,27,1953

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 70 mg/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - flaccid paralysis without anesthesia
   (usually neuromuscular blockage)
   Behavioral - ataxia
   Behavioral - muscle contraction or spasticity
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 53

其他信息

  • 用途一:用作分析试剂,也用于防腐剂的制备
  • 外观性质:白色结晶或结晶性粉末,无臭。
  • 参考质量标准:参考标准 指标名称 指标 外观 白色结晶 氟硅酸铵[(NH4)2SiF6]/%≥ 98 氟硅酸(H2SiF6)/%≤ 0.3 硫酸盐(以SO4 2- 计)/%≤ 0.6 水分/%\≤ 0.6 水不溶物/%≤ 0.5
  • MOL 文件:16919-19-0.mol
  • 方法一:中和法萤石粉、硅砂与硫酸反应制得氟硅酸(参见氟硅酸),再用氨中和至Ph8左右,趁热压滤,除去不溶性杂质,然后经浓缩、结晶、离心分离、干燥,制得氟硅酸铵成品。其 H2SiF6+2NH4OH→(NH4)2SiF6+2H2O
  • 水中溶解度(g/100ml):每100毫升水中的溶解克数: 18.6g/20℃
  • Hazard Note:Toxic
  • Sigma Aldrich:16919-19-0(sigmaaldrich)
  • MSDS 信息:六氟硅酸铵(16919-19-0).msds
  • 用途四:镂刻玻璃,杀虫剂,热焊接助熔剂。
  • 上游原料:碳酸氢铵 --> 氟硅酸 --> 硅砂 --> 萤石粉
  • 用途二:用于消毒剂、防腐剂、杀虫剂等的制备
  • 用途三:用作酿造工业的消毒剂、玻璃蚀刻剂、纺织品的防蛀剂、木材防腐剂。也用于轻金属浇铸、电镀、由绿砂中提钾及制取入造冰晶石和氯酸铵等;在化学分析中还用于钡盐测定。
  • Alfa Aesar:六氟硅酸铵,Puratronic|r,99.999%(metalsbasis) Ammonium hexafluorosilicate, Puratronic, 99.999% (metals basis)(16919-19-0)
  • 氟硅酸铵价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 81001118 氟硅酸铵 500g 58元 2011/08/23 81001128 氟硅酸铵 500g 53元 2010/05/25 43184 六氟硅酸, Puratronic®, 99.999% (metals basis) Ammonium hexafluorosilicate, Puratronic®, 99.999% (metals basis) 10g 538元
  • 毒性:参见氟硅酸钠。
  • TSCA:Yes

系列性分类


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