Cadmium oxide 氧化镉

CAS 1306-19-0 MFCD00010921

化学结构图

1306-19-0
SMILES: O=[Cd]

化学属性

Mol. FormulaCdO
Mol. Weight128
Density8.15 g/mL at 25 °C(lit.)
Melting Point1430°
SolubilityPractically insoluble in water. Soluble in dilute acids, slowly soluble in ammonium salts
TSCAYes
Boiling Point1385 ºC
Appearance powder
Stability对空气、湿度敏感

别名和识别编码

Chemical NameCadmium oxide
CAS Number1306-19-0
PubChem Substance ID14782
EC Number215-146-2
MDL NumberMFCD00010921
Merck Number14,1623
Synonym CADMIUM (II) OXIDE CADMIUM OXIDE CADMIUM OXIDE BROWN CADMIUM OXIDE, 99+% CADMIUM OXIDE, 99.99+% METALS BASIS Cadmium monoxide Cadmium oxide Cadmium oxide (CdO) Cadmium oxide, brown Cadmium oxide, ~1 micron, 99.5% metals basis CadmiumOxide99.998% CadmiumOxideGr Cadmiumoxid Cadmiumoxid (stabilisiert) Cadmiumoxid, braun CdO Kadmu tlenek NCI-C02551 aska-rid cadmium (II) oxide cadmium oxide cadmium oxide, hydrate cadmiumfume cadmiumfume(ascd) cadmiummonoxide cadmiumoxide(cdo) caswellno136aa kadmutlenek kadmutlenek(polish) monteponite {} {} {}
Chemical Name Translation氧化镉
Wiswesser Line NotationCD O
LabNetwork Molecule IDLN00193079
InChIInChI=1S/Cd.O
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分类

  • {SNA} Alternative Energy, Cadmium, Catalysis and Inorganic Chemistry, Chemical Synthesis, Dopants, Materials Science, Metal and Ceramic Science, Oxides, Phosphor Materials
  • {SNA} Alternative Energy, Cadmium, Dopants, Materials Science, Metal and Ceramic Science, Oxides, Phosphor Materials
  • {Chemicalbook} 无机化工产品: 无机盐: Ct氧化物
  • {SNA} Alternative Energy, Cadmium, Catalysis and Inorganic Chemistry, Chemical Synthesis, Dopants, Metal and Ceramic Science, Oxides, Phosphor Materials, 材料科学
  • {SA} Cadmium,

产品应用

  • 有机反应催化剂，制造其他镉盐，磷光体，半导体，制造银合金，蓄电池电极，陶瓷釉彩，电器触头。

相关文献及参考

  • Short: III/27d
  • Merck: 14,1623
  • Short: III/23a

安全信息

GHS Symbol
WGK Germany2
Hazard Codes T+,N T T,N,T+
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H330 Fatal if inhaled 吸入致命
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
  • H350 May cause cancer 可能致癌
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
RTECSEV1925000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P203
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P310
  • P301+P316
  • P302+P352
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P354+P338
  • P307+P311
  • P308+P313
  • P308+P316
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P316
  • P317
  • P318
  • P319
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
UN Number 2570 UN 2570 6.1/PG 3 UN2570
Risk Statements
  • R49 May cause cancer by inhalation 吸入会致癌
  • R22 Harmful if swallowed 吞咽有害
  • R48/23/25
  • R26 Very toxic by inhalation 吸入极毒
  • R45 May cause cancer 可能致癌
  • R50/53
  • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
  • R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
Packing GroupIII
Hazard Class6.1
Storage condition 充氩储存 密封保存
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 90 mg/kg
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   BJCAAI British Journal of Cancer.  (Macmillan Press Ltd., Houndmills,
   Basingstoke, Hants. RG21 2XS, UK)  V.1-    1947-  Volume(issue)/page/year:
   20,190,1966

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Primate - monkey
DOSE/DURATION           : 1500 mg/m3/10M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85PDAD "Evaluation of the Impact of Cadmium on the Health of Man", Oxford,
   UK.  Pergamon Press Ltd., 1978  Volume(issue)/pa

{

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human - man
DOSE/DURATION           : 40 ug/m3
TOXIC EFFECTS :
   Cardiac - change in rate
   Vascular - BP elevation not characterized in autonomic section
   Kidney, Ureter, Bladder - other changes
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(i

TYPE OF TEST            : TCLo - Lowe

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 12 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ZDKAA8 Zdravookhranenie Kazakhstana.  Public Health of Kazakhstan.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1941-
   Volume(issue)/page/year: 38(9),18,1978

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human - man
DOSE/DURATION           : 500 ug/m3/5Y-I
TOXIC EFFECTS :
   Sense Organs and Special Senses (Olfaction) - change in sensation of smell
   Kidney, Ureter, Bladder - proteinuria
REFERENCE :
   QJMEA7 Quarterly Journal of Medicine.  (Oxford Univ. Press, Walton St.,
   Oxford OX2 6DP, UK) V.1-    1932-  Volume(issue)/page/year: 38,425,1969

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 183 ug/m3/5H
SEX/DURATION            : female 21 week(s) pre-mating
                          female 1-20 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - viability index (e.g., # alive at day 4
   per # born alive)
   Reproductive - Effects on Newborn - growth statistics (e.g.%, reduced weight
   gain)
REFERENCE :
   TOLED5 Toxicology Letters.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1977-  Volume(issue)/page/year: 22,53,1984

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 91 ug/m3
SEX/DURATION            : female 1-19 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 31(8),25,1987

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 21640 ug/kg
SEX/DURATION            : female 1-19 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - cardiovascular
   (circulatory) system
   Reproductive - Effects on Newborn - weaning or lactation index (e.g., #
   alive at weaning per # alive at day 4)
   Reproductive - Effects on Newborn - growth statistics (e.g.%, reduced weight
   gain)
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see H

其他信息

  • MOL 文件:1306-19-0.mol
  • 能溶于稀酸，缓慢溶
  • {
  • 氧化镉价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 51005260 氧化镉 5g 62元 2011/08/23 10005517 氧化镉 250g 59.9元 2010/05/25 10664 氧化, Puratronic®, 99.998% (metals basis) Cad
  • Alfa Aesar:氧化镉,Puratronic|r,99.998%(metalsbasis) Cadmium oxide, Puratronic, 99.998% (metals basis)(1306-19-0)
  • 用途三:用于镉电镀液、制镉电极、光电管、γ射线照相、陶瓷釉彩颜料、冶金工业的合金制造以及用作制镉盐和镉试剂的原料、催化剂。
  • 毒性:粉尘或烟尘引起急性中毒时，会出现前额部疼痛、眩晕、无力、恶心、上腹部痛，并引起气管炎、支气管炎、肺水肿、胸痛、关节痛、心脏扩大、肝肿大，呕血及血性腹泻。重者由于肺水肿或肺炎而引起死亡。慢性中毒，会使嗅觉降低直至消失，引起镉鼻炎、牙颈部和齿龈变成金黄色(镉环)、头痛眩晕、食欲不振、胃痛恶心、呕吐、消瘦、尿蛋白、鼻出血、黏膜皲裂、慢性咽喉炎、肺气肿、进行性肺硬化、肝肾损害，并伴随有明显的神经衰弱及植物神经官能症，还能引起骨质疏松，重者造成劳动能力丧失。 如有中毒发生应立即将中毒者移至新鲜
  • 参考质量标准:参考标准 指标名称 指标 氧化镉(CdO)/% 70～98 氧化锌(ZnO)/% 1.0～1.5 细度 通过1
  • 防护措施:粉尘或烟尘引起急性中毒时，会出现前额部疼痛、眩晕、无力、恶心、上腹部痛，并引起气管炎、支气管炎、肺水肿、胸痛、关节痛、心脏扩大、肝肿大，呕血及血性腹泻。重者由于肺水肿或肺炎而引起死亡。慢性中毒，会使嗅觉降低直至消失，引起镉鼻炎、牙颈部和齿龈变成金黄色（镉环）、头痛眩晕、食欲不振、胃痛恶心、呕吐、消瘦、尿蛋白、鼻出血、粘膜皲裂、慢性咽喉炎、肺气肿、进行性肺硬化、肝肾损害，并伴随有明显的神经衰弱及植物神经官能症，还能引起骨质疏松，重者造成劳动能力丧失。 如有中毒发生应立即将中毒者移至新鲜空气处，尽量安静，保暖，呼吸道有病状时，应吸入湿热的2%碳酸氢钠溶液，给含苏达或碱性矿泉水的热牛奶。并针对各种症状进行药物治疗。 最高容许浓度0.1mg/m3。 要
  • 能溶于稀酸，缓慢溶于铵盐，几乎不溶于水。在空气中吸收二氧化碳，变成碳酸镉，其色逐渐变白。加热至700℃开始升华。中等毒，半数致死量(大鼠，经口)72mg/kg。有致癌可能性。
  • MSDS 信息:氧化镉(1306-19-0).m
  • 方法一:金属镉氧化法将含镉下脚料加入水和硫酸中，进行搅拌、反应，生成硫酸镉
  • 方法一:金属镉
  • 可燃性危险特性:热分解排出有毒含镉烟雾
  • color:brown
  • Sigma Aldrich:1306-19-0(sigmaaldrich)
  • 上游原料:高锰酸钾 --> 柴油机燃料油 --> 金属镉 --> 聚氨酯泡沫塑料 --> 镉 --> 海绵镉
  • 方法一:金属镉氧化法将含镉下脚料加入水和硫酸中，进行搅拌、反应，生成硫酸镉。将所得粗制溶液控制在浓度为20～25°Bé，Ph值为2～4左右。粗制溶液经压滤后，滤液送至氧化槽中，在80～90℃下加入过氧化氢或高锰酸钾以氧化除铁(Ph值保持在5.4)。氧化后的溶液在70～80℃下，用锌皮置换硫酸镉，使镉以海绵形态自动浮出。分离出海绵镉经水洗、酸洗除锌，再经反复水洗后进行过滤。当所
  • 常规方法:用内衬聚乙烯塑料袋的麻袋或编织袋包装，每袋净重40kg，25kg。或用内衬聚乙烯塑料袋的铁桶包装，每桶重10kg。 贮存于阴凉、通风、干燥的库房中。包装要求完整。不可与强酸、强碱及食用原料共贮混运。运输时应注意防雨淋、防晒。装卸时要轻拿轻放，防止包装破损。 失火时，可用水、砂土、各种灭火器扑救。
  • 方法一:金属镉氧化法将含镉下脚
  • 外观性质:棕红色至棕黑色无定形粉末或立方晶体。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Cadmium 镉
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Oxides 金属氧化物
  4. Cadmium - Oxides
  1. Materials Science 材料科学
  2. Products for Alternative Energy Research
  3. Phosphor Materials - Alternative Energy