Manganese(II) chloride 无水二氯化锰

CAS 7773-01-5 MFCD00011114

化学结构图

7773-01-5
SMILES: [Cl-].[Cl-].[Mn+2]

化学属性

Mol. FormulaMnCl2
Mol. Weight125.84
Density1.01 g/mL at 20 °C
Melting Point652 °C(lit.)
TSCAYes
Boiling Point1190°C
SolubilityVery soluble in water, alcohol. Insoluble in ether
Flash Point1190°C
Appearance flakes
Stability易吸潮

别名和识别编码

Chemical NameManganese(II) chloride
Synonym Manganese (chloride) {LY} Manganese (chloride) {} {LY} Manganese (chloride) {} {} {LY} Manganese (chloride) {} {} {} {LY} Manganese (chloride) {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {} {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {} {} {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {} {} {} {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Manganese (chloride) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number7773-01-5
PubChem Substance ID10313134
EC Number231-791-2
MDL NumberMFCD00011114
Merck Number14,5728
Chemical Name Translation无水二氯化锰
LabNetwork Molecule IDLN00222920
InChIInChI=1S/2ClH.Mn/h2*1H;/q;;+2/p-2
Canonical SMILESCl[Mn]Cl
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分类

  • {SNA} 10.00 g/L, AAS, AAS Concentrates, Additional Standards, Analytical Standards, Single Solution, Spectroscopy, 分析/色谱
  • {SNA} Manganese Salts, Materials Science, Metal and Ceramic Science, Salts
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis,

产品应用

  • 通过 MnCl2 氧化及同时进行的 NaOMe 促进型聚集来合成一种新型高自旋六核 Mn(III) 原子簇化合物 [NaMn6(OMe)12(dbm)6]+。该原子簇化合物具有全新的环状结构，在基态时具有 24 个不成对电子。1还用于形成可用于自由基环化反应的活性 Mn(0) 物质。

相关文献及参考

  • Merck: 14,5728

安全信息

GHS Symbol
WGK Germany1
Hazard Codes Xn
Hazard statements
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H318 Causes serious eye damage 严重伤害眼睛
  • H302 Harmful if swallowed 吞食有害
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H301 Toxic if swallowed 吞食有毒
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves Eyeshields, Faceshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) Eyeshields, Faceshields, Gloves
RTECSOO9625000
Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P305+P351+P338+P310
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P337+P313
  • P305+P351+P338
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P312+P330
Signal word Danger Warning
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R52 Harmful to aquatic organisms 对水生生物有害
  • R48/22
  • R25 Toxic if swallowed 吞咽有毒
Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture Hygroscopic {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture
UN Number UN3288 UN 3288 6.1/PG 3
Packing GroupIII

其他信息

  • Alfa Aesar:无水氯化锰(II),anhydrous,97% Manganese(II) chloride, anhydrous, 97%(7773-01-5)
  • 职业标准:TWA 0.2 毫克(锰)/立方米
  • 图谱信息:氯化锰(7773-01-5)红外图谱(IR1)
  • 储运特性:库房低温, 通风, 干燥; 与食品原料分开存放
  • 灭火剂:水, 二氧化碳, 干粉, 砂土
  • 水中溶解度(g/100ml):不同温度(℃)时每100毫升水中的溶解克数: 63.4g/0℃;68.1g/10℃;73.9g/20℃;80.8g/30℃;88.5g/40℃ 109g/60℃;113g/80℃;114g/90℃;115g/100℃
  • 用途二:营养增补剂(锰强化剂)。
  • 外观性质:玫瑰色立方形晶体，微有潮解性。
  • 敏感性:Hygroscopic
  • 有很强吸湿性，650℃熔融，650℃以上升华，在空气中加热即释放出氯化氢气体并生成四氧化三锰。溶于水、醇，不溶于醚。
  • 方法一:将菱锰矿与盐酸反应，经中和并除去铁、钙等杂质而得。 将软锰矿与盐酸反应，经除杂而得。
  • 类别:有毒物质
  • 用途三:用作有机物氯化催化剂，油漆催干剂和汽油抗震剂原料。用于饲料辅助剂、分析试剂、染料和颜料制造。镁合金、铝合金冶炼，棕黑色砖瓦生产以及制药和干电池制造。在农业上还用作微量元素肥料。
  • 可燃性危险特性:可燃, 火场排出含锰辛辣刺激烟雾
  • Acros Organics:氯化锰 Manganese(II) chloride, anhydrous, 80 mesh, 99+%(7773-01-5)
  • 上游原料:二氧化锰 --> 碳酸锰 --> 锰
  • 用途一:用于铝合金冶炼、有机氯化物触媒、染料和颜料的制造，以及用于制药和干电池等
  • Sigma Aldrich:7773-01-5(sigmaaldrich)
  • 氯化锰价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 20026118 氯化锰 500g 26元 2010/06/21 223610500 氯化锰 Manganese(II) chloride 99+%, anhydrous, 80 mesh 50 GR 1342元 2010/06/21 223610100 氯化锰 Manganese(II) chloride 99+%, anhydrous, 80 mesh 10 GR 431元
  • 毒性分级:高毒
  • 下游产品:钛 --> 2-苯基苄胺
  • MOL 文件:7773-01-5.mol
  • 急性毒性:口服- 大鼠 LD50 250 毫克/ 公斤; 口服- 小鼠 LD50: 1031 毫克/公斤
  • MSDS 信息:氯化锰(7773-01-5).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Manganese - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Manganese - Catalysis and Inorganic Chemistry
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Ultra-High Purity Materials - Metal and Ceramic Science
  1. Life Science 生命科学
  2. Molecular Biology 分子生物学
  3. Molecular Biology Reagents - Molecular Biology
  4. Biochemicals - Molecular Biology Reagents
  1. Life Science 生命科学
  2. Molecular Biology 分子生物学
  3. Molecular Biology Reagents - Molecular Biology
  4. Biochemicals - Molecular Biology Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Spectroscopy - Analytical Standards
  4. AAS - Spectroscopy
  5. AAS Concentrates - AAS
  6. 10.00 g/L - AAS Concentrates
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Spectroscopy - Analytical Standards
  4. AAS - Spectroscopy
  5. AAS Concentrates - AAS
  6. 10.00 g/L - AAS Concentrates
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Spectroscopy - Analytical Standards
  4. AAS - Spectroscopy
  5. AAS Concentrates - AAS
  6. 1.00 g/L - AAS Concentrates
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Crystal Grade Inorganics 晶体级无机物
  4. Manganese - Crystal Grade Inorganics
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Salts 金属盐
  4. Manganese Salts - Salts
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Magnesium
  1. Metal Chloride
  2. Manganese