Ruthenium Carbonyl 十二羰基三钌
CAS 15243-33-1 MFCD00011209
化学结构图
SMILES: [Ru].[Ru].[Ru].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
化学属性
| Mol. Formula | C12O12Ru3 |
|---|---|
| Mol. Weight | 639.33 |
| Melting Point | 150 |
| Solubility | Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone. Solutions undergo some decomposition on strong heating |
| TSCA | Yes |
| Appearance | orange xtl. |
别名和识别编码
| Chemical Name | Ruthenium Carbonyl |
|---|---|
| Synonym | Triruthenium Dodecacarbonyl {LY} Triruthenium Dodecacarbonyl {} {LY} Triruthenium Dodecacarbonyl {} {} {LY} Triruthenium Dodecacarbonyl {} {} {} {LY} Triruthenium Dodecacarbonyl {} {} {} {} {LY} Triruthenium Dodecacarbonyl {} {} {} {} {} {LY} Triruthenium Dodecacarbonyl {} {} {} {} {} {} {LY} Triruthenium Dodecacarbonyl {} {} {} {} {} {} {} {LY} Triruthenium Dodecacarbonyl {} {} {} {} {} {} {} {} {LY} Triruthenium Dodecacarbonyl {} {} {} {} {} {} {} {} {} {LY} Triruthenium Dodecacarbonyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triruthenium Dodecacarbonyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triruthenium Dodecacarbonyl {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triruthenium Dodecacarbonyl {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triruthenium Dodecacarbonyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triruthenium Do |
| MDL Number | MFCD00011209 |
| PubChem Substance ID | 87558750 |
| CAS Number | 15243-33-1 |
| EC Number | 239-287-4 |
| Reaxys-RN | 14281346 |
| Chemical Name Translation | 十二羰基三钌 |
| InChIKey | NQZFAUXPNWSLBI-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00239128 |
| Canonical SMILES | [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Ru]1[Ru][Ru]1 |
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分类
- {SA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Ru Catalysts, Ruthenium, Vapor Deposition Precursors
- {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Ru Catalysts, Ruthenium, Ruthenium Catalysts,
- {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Ru Catalysts, Ruthenium, Ruthenium Catalysts, Vapor Deposition Precursors, 材
产品应用
- 羰基团的前提和H-转移催化剂。用于芳香族硝基复合物至氨基甲酸盐的还原性羰基化。
相关文献及参考
- Short: III/35D5
- On heating under pressure with norbornene and CO, alkynes undergo aromatization to give condensed hydroquinones: Organometallics, 17, 766 (1998). For reaction scheme, see 2-Hexyne, B22405.
- 1,6-Enynes undergo cyclocondensation with CO under pressure, to give bicyclo[3.3.0]octenones: J. Org. Chem., 62, 3762 (1997):
- FT-IR 2 (3), 4592:B / FT-IR 1 (2), 1299:D / RegBook 1 (2), 3143:B
安全信息
WGK Germany3
GHS Symbol
Hazard statements
- H228 Flammable solid 易燃固体
- H332 Harmful if inhaled 吸入有害
Hazard Codes
4.1
F,Xn
Xn
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word
Warning
UN Number
3178
Precautionary statements
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P312+P362+P364
- P304+P340+P312
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
Safety Statements
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
Risk Statements
- R11 Highly flammable 非常易燃
- R20 Harmful by inhalation 吸入有害
- R23 Toxic by inhalation 吸入有毒
Packing GroupIII
Hazard Class4.1
Storage condition
RT, stored under nitrogen
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其他信息
- Sigma Aldrich:15243-33-1(sigmaaldrich)
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