Thallium(I) Bromide 溴化铊(I)

CAS 7789-40-4 MFCD00011273

化学结构图

7789-40-4
SMILES: Br[TlH2]

化学属性

Mol. FormulaBrTl
Mol. Weight284.29
Density7.5 g/mL at 25 °C(lit.)
Melting PointNo Data Available
TSCAYes
SolubilityPractically insoluble in water
Boiling Point
Appearance beads
Stability易吸潮，对光敏感

别名和识别编码

Chemical NameThallium(I) Bromide
Synonym KRS 5 KRS-5 THALLIUM (OUS) BROMIDE THALLIUM BROMIDE THALLIUM(+1)BROMIDE THALLIUM(I) BROMIDE THALLOUS BROMIDE Thalliam bromide Thallium Bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number7789-40-4
PubChem Substance ID24850374
EC Number232-163-0
MDL NumberMFCD00011273
Merck Number14,9258
Chemical Name Translation溴化铊(I)
Wiswesser Line NotationTL E
LabNetwork Molecule IDLN01305959
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分类

  • {SNA} 81: Tl, Beaded Materials, Catalysis and Inorganic Chemistry, Chemical Synthesis, Crystal Grade Inorganics, Essential Chemicals, Materials Science, Metal and Ceramic Science, Research Essentials, Salts, Thallium, Thallium Salts, Tl, Ultra-High Purity Materials
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Salts, Thallium, Thallium Salts, 材料科学
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals,

相关文献及参考

  • Merck: 14,9258
  • Short: EINECS
  • Short: IV/4
  • Short: LC

安全信息

GHS Symbol
WGK Germany3
Hazard Codes T+,N
Hazard statements
  • H330 Fatal if inhaled 吸入致命
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H300 Fatal if swallowed 吞食致命
  • H300+H330
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Signal word Danger
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S13 Keep away from food, drink and animal foodstuffs 远离食品、饮料和动物饲料保存；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
UN Number UN 1707 6.1/PG 2 UN1707
Risk Statements
  • R51/53
  • R26/28 Very toxic by inhalation and if swallowed 吸入及吞食都有剧毒
  • R33 Danger of cumulative effects 有累积作用的危险
Storage condition Hygroscopic N/A N/A℃ No Data Available 易吸潮，避光保存
Packing GroupII
Hazard Class6.1
RTECSXG3850000
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 29 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Gastrointestinal - hypermotility, diarrhea
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv.
   Toxicology of New Industrial Chemical Substances.  For English translation,
   see TNICS*.  (Izdatel'stvo Meditsina, Moscow, USSR)  No.1-    1961-
   Volume(issue)/page/year: 2,94,1961

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 29 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   YAKUD5 Gekkan Yakuji.  Pharmaceuticals Monthly.  (Yakugyo Jihosha, Inaoka
   Bldg., 2-36 Jinbo-cho, Kanda, Chiyoda-ku, Tokyo 101, Japan)  V.1-   1959-
   Volume(issue)/page/year: 22,291,1980

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 35 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,110,1982

其他信息

  • 可燃性危险特性:不可燃物质; 受热产生有毒溴化物和含铊化物烟雾
  • MSDS 信息:溴化铊(7789-40-4).msds
  • Sigma Aldrich:7789-40-4(sigmaaldrich)
  • 毒性分级:剧毒
  • 类别:有毒物品
  • 急性毒性:口服- 大鼠 LDL0: 35 毫克/ 公斤; 口服- 小鼠 LDL0: 29 毫克/ 公斤
  • 职业标准:TLA-TWA 0.1 毫克 (铊)/ 立方米
  • MOL 文件:7789-40-4.mol
  • Alfa Aesar:溴化铊(I),ultradry,99.999%(metalsbasis) Thallium(I) bromide, ultra dry, 99.998% (metals basis)(7789-40-4)
  • 敏感性:Hygroscopic
  • 储运特性:库房通风低温干燥; 与碱、酸类、食品添加剂分开存放
  • 水中溶解度:0.04%，溶于醇，不溶于丙酮。
  • 水中溶解度(g/100ml):不同温度(℃)时每100毫升水中的溶解克数: 2.2×10-2/30℃;3.2×10-2/10℃;4.8×10-2/20℃;6.8×10-2/30℃;9.7×10-2/40℃ 0.117g/60℃
  • Acros Organics:Thallium(I) bromide, 99%(7789-40-4)
  • 外观性质:黄白色结晶性粉末。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Thallium - Catalysis and Inorganic Chemistry
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Thallium - Catalysis and Inorganic Chemistry
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Crystal Grade Inorganics 晶体级无机物
  4. Thallium Crystal Grade Inorganics

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