Zinc bromide (ZnBr2) 溴化锌

CAS 7699-45-8 MFCD00011294

化学结构图

7699-45-8
SMILES: Br[Zn]Br

化学属性

Mol. FormulaBr2Zn
Mol. Weight225.19
Boiling Point670 °C at 760 mmHg
Melting Point394 °C
TSCAYes
Density4.22
Refractive index1.5452
Solubility可溶, 447 G/100 ML (20 ºC)
Flash Point650°C
Appearance 白色易潮解结晶粉末。相对密度4.5。熔点394℃。沸点650℃。汽化热118 kJ/mol;熔化热16.70 kJ/mol。折射率1.5452(20℃)。易溶于水、醇、乙醚和丙酮,碱金属氢氧化物溶液。 beads
StabilityHygroscopic

别名和识别编码

Chemical NameZinc bromide (ZnBr2)
Synonym Zinc bromide {LY} Zinc bromide {} {LY} Zinc bromide {} {} {LY} Zinc bromide {} {} {} {LY} Zinc bromide {} {} {} {} {LY} Zinc bromide {} {} {} {} {} {LY} Zinc bromide {} {} {} {} {} {} {LY} Zinc bromide {} {} {} {} {} {} {} {LY} Zinc bromide {} {} {} {} {} {} {} {} {LY} Zinc bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zinc bromide {} {} {} {} {} {} {} {} {} {} {LY} Zinc bromide {} {} {} {} {} {} {} {} {} {} {} {LY} Zinc bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zinc bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zinc bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zinc bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zinc bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zinc bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number7699-45-8
PubChem Substance ID10421208
EC Number231-718-4
MDL NumberMFCD00011294
Merck Number1029
Beilstein Registry Number2384789
Chemical Name Translation溴化锌
Wiswesser Line Notation.ZN..E2
LabNetwork Molecule IDLN00163221
Canonical SMILESBr[Zn]Br
InChIInChI=1S/2BrH.Zn/h2*1H;/q;;+2/p-2
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分类

  • {SNA} 30: Zn, Beaded Materials, Catalysis and Inorganic Chemistry, Chemical Synthesis, Crystal Grade Inorganics, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Salts, Ultra-High Purity Materials, Zinc, Zinc Salts, Zn,
  • {S

产品应用

  • 核反应视窗保护屏。制备溴化银胶体乳剂用于照相。

相关文献及参考

  • Merck: 14,10129
  • Short: II/25A
  • Short: II/5
  • For discussion of scope and limitations of its use for selective deprotection of tert-butyl esters in the presence of other acid labile groups, see: J. Org. Chem., 69, 6131 (2004).
  • Short: I

安全信息

GHS Symbol
WGK Germany3
Hazard Codes C,N
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H318 Causes serious eye damage 严重伤害眼睛
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges dust mask type N95 (US), Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSZH1150000
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P352
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P333+P313
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
UN Number 3260
Safety Statements
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R50 Very toxic to aquatic organisms 对水生生物极毒
  • R50/53
  • R51/53
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R22 Harmful if swallowed 吞咽有害
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Packing GroupIII
Hazard Class8
TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - rat Ascites tumor
DOSE/DURATION           : 800 mg/kg
REFERENCE :
   GANNA2 Gann.  Japanese Journal of Cancer Research.  (Tokyo, Japan)  V.1-75,
   1907-84.  For publisher information, see JJCREP.  Volume(issue)/page/year:
   54,155,1963

其他信息

  • 参考质量标准:指标名称 指标 含量(ZnBr2)/%≥ 98.0 碱金属与碱土金属(以硫酸盐计)/%≤ 0.2 盐酸不溶物/%≤ 0.005 铁(Fe)/%≤ 0.001 铅(Pb)/%≤ 0.005 硫酸盐(SO4)/%≤ 0.01
  • 溴化锌价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 20045126 溴化锌;无水溴化锌 100g 30元 2011/04/16 Z0013 溴化锌 Zinc Bromide 300G 458元 2011/04/16 Z0013 溴化锌 Zinc Bromide 25G 343元
  • 水中溶解度(g/100ml):不同温度(℃)时每100毫升水中的溶解克数: 389g/0℃;446g/20℃;528g/30℃;591g/40℃ 618g/60℃;645g/80℃;672g/100℃
  • 用途四:核反应视窗保护屏。制备溴化银胶体乳剂用于照相。
  • 方法一:直接法纯金属锌与精溴在二氧化碳气氛中加热反应,经蒸馏制得溴化锌。其 Zn+Br2→ZnBr2
  • 上游原料:氢溴酸 --> 锌粉 --> 氧化锌
  • Alfa Aesar:溴化锌,ultradry,99.999%(metalsbasis) Zinc bromide, ultra dry, 99.999% (metals basis)(7699-45-8)
  • TCI Shanghai:溴化锌 Zinc Bromide,>;98.0%(T)(7699-45-8)
  • 用途三:化学分析试剂。照相乳剂。制药工业。还用于合成纤维的后处理剂。
  • 用途一:用作海洋油田良好的完井液、固井液,电池电解质等
  • 有强烈的金属味。极易吸湿。1g溶于0.25ml水、0.5ml90%乙醇,溶于乙醚、丙酮和氢氧化碱溶液。溶液对石蕊呈酸性,pH约为4.201。有刺激性。
  • F:3-21
  • 敏感性:Hygroscopic
  • 用途二:用于制药工业和照相业
  • MSDS 信息:Zinc bromide(7699-45-8).msds
  • Sigma Aldrich:7699-45-8(sigmaaldrich)
  • MOL 文件:7699-45-8.mol
  • 毒性:本品能灼伤皮肤,操作时注意防护。
  • Acros Organics:溴化锌 Zinc bromide, anhydrous, extra pure, 98+%(7699-45-8)
  • 下游产品:杂氮双环磷酸酯

系列性分类


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