Tungsten Trioxide 氧化钨(VI)

CAS 1314-35-8 MFCD00011466

化学结构图

1314-35-8
SMILES: O=[W](=O)=O

化学属性

Mol. FormulaO3W
Mol. Weight231.84
Density7.16
Melting Point1470-1475 °C
SolubilityInsoluble in water and acids. Soluble in hot alkalies. Slightly soluble in HF
TSCAYes
Refractive index1.3678
Boiling Point1837 °C at 760 mmHg
Stability对湿度敏感
Appearance powder

别名和识别编码

Chemical NameTungsten Trioxide
Synonym Tungsten trioxide {LY} Tungsten trioxide {} {LY} Tungsten trioxide {} {} {LY} Tungsten trioxide {} {} {} {LY} Tungsten trioxide {} {} {} {} {LY} Tungsten trioxide {} {} {} {} {} {LY} Tungsten trioxide {} {} {} {} {} {} {LY} Tungsten trioxide {} {} {} {} {} {} {} {LY} Tungsten trioxide {} {} {} {} {} {} {} {} {LY} Tungsten trioxide {} {} {} {} {} {} {} {} {} {LY} Tungsten trioxide {} {} {} {} {} {} {} {} {} {} {LY} Tungsten trioxide {} {} {} {} {} {} {} {} {} {} {} {LY} Tungsten trioxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tungsten trioxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tungsten trioxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tungsten trioxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tungsten trioxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tungs
CAS Number1314-35-8
EC Number215-231-4
Beilstein Registry Number2384789
MDL NumberMFCD00011466
Merck Number14,9817
PubChem Substance ID24852293
Chemical Name Translation氧化钨(VI)
Wiswesser Line Notation.WO..O3
LabNetwork Molecule IDLN01306722
Canonical SMILESO=[W](=O)=O
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分类

  • {SNA} 74: W, Metal and Ceramic Science, Nanomaterials, Nanoparticles: Materials by Application, Nanoparticles: Oxides, Nitrides, and Other Ceramics, Nanopowders and Nanoparticle Dispersions, Oxides, Phosphors and Phosphor Hosts, Tungsten, 材料科学
  • {SNA} Metal and Ceramic Science, Oxides, Tungsten,

产品应用

  • 可用作制金属钨的原料,制造硬质合金、刀具、模具和拉钨丝,也可用于粉末冶金,还可用于X射线屏及防火织物,以及用作陶瓷器的着色剂和分析试剂等。蓝色氧化钨用作生产钨粉,掺杂钨粉,钨条、钨杆、....和硬质合金等。黄色氧化钨用于电渡和生产其它钴产品、气压计、比重计

相关文献及参考

  • Merck: 14,9817
  • Short: III/12a
  • Short: III/24C
  • Short: III/24D

安全信息

Signal word
GHS Symbol
WGK Germanynwg
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Precautionary statements
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
RTECSYO7760000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn
Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1059 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - excitement
   Behavioral - muscle weakness
REFERENCE :
   HYSAAV Hygiene and Sanitation (USSR).  English translation of GISAAA.
   (Springfield, VA)  1964-71. Discontinued.  Volume(issue)/page/year:
   31(7-9),197,1966

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 48(7),71,1983

其他信息

  • Acros Organics:三氧化钨 Tungsten(VI) oxide, 99+%(1314-35-
  • F:21
  • 上游原料:氢氧化钠 --> 氨 --> (T-4)-钨酸钠 --> WO --> CI --> 钨精矿
  • 毒性:接触钨化合物使人的上呼吸道和深部呼吸道受到刺激,受粉尘作用患支气管哮喘,胃肠道功能紊乱。对皮肤有刺激作用,使皮肤上出现小结节和鳞屑。在美国钨及可溶性钨化合物(按钨计)的最高容许浓度为1 mg/m 3 ,不溶性钨化合
  • 下游产品:磷钨酸 --> 钨 --> 钼标准溶液 --> 钨酸钙
  • Sigma Aldrich:1314-35-8(sigmaaldrich)
  • 三氧化钨制取:煅烧仲钨酸铵或钨酸得到黄色粉末状三氧化钨的纯钨化合物制取方法。 钨酸(H2WO4)在673K温度下便开始大量脱水:H2WO4—→WO3+H2O↑ 但在773~873K温度下煅烧的产物仍含有小于0.5%的水,在973~1023K温度下煅烧产物的水含量才小于0.1%。 仲钨酸铵(APT)在高于523K的温度下便可分解:5(NH4)2O·12WO3·nH2O—→12WO3+10NH3↑ +(n+5) H2O↑ 在873K温度下便可完全分解成WO3。 中国将三氧化钨分为三级,即一级、二级和三级,其纯度相应为99.95%、99.9%和99.5%。用于生产钨制品的WO3的粒度一般用松装密度 (g/cm3) 或比表面(m2/g)表示,粒度越细,松装密度越小,比表面越大。仲钨酸铵或钨酸的粒度越粗,煅烧温度越高则煅烧所得WO3的粒度也越粗。一般煅烧仲钨酸铵所得到的WO3粒度大于煅烧钨酸所得到的WO3粒度,生产中的煅烧制度需根据对产品的粒度要求来制定。 仲钨酸铵或钨酸的煅烧作业通常在回转管状煅烧炉中进行,炉管由不锈钢制成,管外用电阻丝加热,煅烧时炉管不断旋转,转速约为2.5r/min。钨酸的煅烧温度为1023~1123K,仲钨酸铵的煅烧温度为873~973K,具体煅烧温度的选择则视对产品的要求而定。 参考资料:中国冶金百科全书总编辑委员会
  • 用途四:可用作制金属钨的原料,制造硬质合金、刀具、模具和拉钨丝,也可用于粉末冶金,还可用于X射线屏及防火织物,以及用作陶瓷器的着色剂和分析试剂等。蓝色氧化钨用作生产钨粉,掺杂钨粉,钨条、钨杆、....和硬质合金等。黄色氧化钨用于电渡和生产其它钴产品、气压计、比重计
  • 用途一:用作分析试剂,也用于金属钨、钨盐的制备
  • Alfa Aesar:氧化钨(VI),Puratronic|r,99.998%(metalsbasisexcludingMo),Mo100ppm Tungsten(VI) oxide, Puratronic, 99.998% (metals basis excluding Mo), Mo 100ppm(1314-35-8)
  • 参考质量标准:国家标准GB 3457—82 指标名称 指标 FWO3-1 FWO3-2 FWO3-3 WO3/%≥ 99.95 99.9 99.5 铅(Pb)/%≤ 0.0005 0.001 - 铋(Bi)/%≤ 0.0005 0.001 - 锡(Sn)/%≤ 0.0005 0.001 - 锑(Sb)/%≤ 0.001 0.001 - 砷(As)/%≤ 0.002 0.002 0.010 铁(Fe)/%≤ 0.003 0.005 0.010 铝(AI)/%≤ 0.001 0.001 0.002 硅(Si)/%≤0.002 0.003 0.008 镍(Ni)/%≤ 0.0007 0.002 - 钙(Ca)/%≤ 0.002 0.003 (Ca+Mg)0.015 镁(Mg)/%≤ 0.001 0.004 (Mg+Ca)0.015 钾(K)/%≤ 0.002 0.002 (K+Na)0.015 钠(Na)/%≤ 0.002 0.004 (Na+K)0.015 铜(Cu)/%≤ 0.0007 0.001 - 锰(Mn)/%≤ 0.001 0.002 - 钼(Mo)/%≤ 0.005 0.03 0.10 磷(P)/%≤ 0.0007 0.004 0.015 硫(S)/%≤ 0.001 0.001 0.007 氯化残渣/%≤ - - 0.07 煅烧损失/%≤ 0.5 0.5 0.5
  • 外观性质:黄色粉末。

系列性分类