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分类

• {SNA} Essential Chemicals, Inorganic Salts, Solutions and Reagents, Research Essentials, Technical Grade
• {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfonic/Sulfinic Acids, Sulfur Compounds
• {SNA} Acids, Acids & Bases, Chemical Synthesis, Inorganic Acids, Synthetic Reagents
• {SNA} Acids,

产品应用

• 医药、农药中间体等。

相关文献及参考

• Reaction with ketones results in oxime sulfates which undergo the Beckmann rearrangement to amides on heating: J. Org. Chem. USSR, 17, 2284 (1981); the conversion of cyclic ketones to lactams can conveniently be carried out as a one-step operation: Synthesis, 537 (1979); J. Org. Chem., 54, 4419 (1989); Org. Synth. Coll., 7, 254 (1988).
• Aromatic rings can be aminated in the presence of AlCl3: J. Am. Chem. Soc., 83, 221 (1961). Reaction is more successful with certain heterocycles, N,N'-dimethyluracil giving the 5-amino-derivative almost quantitatively: Tetrahedron Lett., 2751 (1973).
• Can also provide a source of the reducing agent diimide: Liebigs Ann. Chem., 645, 1 (1962); 721, 240 (1969). For examples of the use of diimide in the reduction of alkenes, see Hydrazine monohydrate, A14005.
• With aqueous NaOH, hydrodeamination of primary amines to alkanes is possible for simple aliphatic amines, amino acids or even peptides: J. Am. Chem. Soc., 100, 341 (1978).
• Can also provide a source of the reducing agent diimide: Liebigs Ann. Chem., 645,
• Aminating agent for nucleophiles. For a review of chemistry, see: Org. Prep. Proced. Int., 14, 265 (1982).
• Aldehydes are converted directly to nitriles: Tetrahedron Lett., 3187 (1974): Helv. Chim. Acta, 59, 2786 (1976).
• Primary and secondary amines are converted to hydrazines: J. Org. Chem., 14, 813 (1949); Chem. Ber., 92, 2521 (1959); pyridine to 1-aminopyridinium salts: Org. Synth. Coll., 5, 43 (1977); benzotriazole to the benzyne precursor 1-aminobenzotriazole: J. Chem. Soc., Chem. Commun., 192, 193 (1965); for preparation of the bis(aminotriazolobenzene), a precursor of "1,4-dibenzyne", see: Tetrahedron Lett., 25, 2073 (1984).
• A one-pot synthesis of aryl or heteroaryl amines from carboxylic acids (as their chlorides) has been reported, equivalent to the Schmidt or Hofmann reactions: Synthesis, 1143 (1990).

安全信息

GHS Symbol

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 140 nmol/disc
REFERENCE :
   CBINA8 Chemico-Biological Interactions.  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1969-  Volume(issue)/page/year:
   7,195,1973

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 1900 umol/L
REFERENCE :
   CBINA8 Chemico-Biological Interactions.  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1969-  Volume(issue)/page/year:
   7,195,1973

其他信息

• 可溶于水，极易吸潮，具腐蚀性。
• MOL 文件:2950-43-8.mol
• TCI Shanghai:羟胺-O-磺酸 Hydroxylamine-O-sulfonic Acid,>;90.0%(T)(2950-43-8)
• 羟胺磺酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0530 羟胺-O-磺酸 Hydroxylamine-O-sulfonic Acid 25G 762元 2014/06/02 H0530 羟胺-O-磺酸 Hydroxylamine-O-sulfonic Acid 500G 6050元 2010/06/21 325940250 羟胺磺酸 Hydroxylamine-O-sulfonic acid 97% 25 GR 857元
• Acros Organics:Hydroxylamine-O-sulfonic acid, 90%(2950-43-8)
• 图谱信息:羟胺磺酸(2950-43-8)红外图谱(IR2) 羟胺磺酸(2950-43-8)红外图谱(IR1)
• 用途一:医药、农药中间体等。
• 海关编码:28111980
• Hazard Note:Irritant
• Alfa Aesar:羟胺-O-磺酸,97% Hydroxylamine-O-sulfonic acid, 97%(2950-43-8)
• MSDS 信息:HOSA(2950-43-8).msds
• 敏感性:Hygroscopic
• F:10-21
• Sigma Aldrich:2950-43-8(sigmaaldrich)
• 下游产品:二甲基乙二醛肟 --> 吡唑并[1,5-a]吡啶-3-羧酸 --> 3-(3-硝基苯基)丙酸