N-Methyl-N-Methylenemethanaminium Chloride N,N-二甲基氯烯亚胺

CAS 30354-18-8 MFCD00011809

化学结构图

30354-18-8
SMILES: [Cl-].C[N+](C)=C

化学属性

Mol. FormulaCH2=N+(CH3)2Cl-
Mol. Weight93.56
Melting Point146-148 °C(lit.)

别名和识别编码

Chemical NameN-Methyl-N-Methylenemethanaminium Chloride
Synonym Böhme's salt Dimethylformiminium chloride Eschenmoser 盐 Methylenedimethylammonium chloride N,N-二甲基氯烯亚胺 Böhme's salt Methylenedimethylammonium chloride Dimethylformiminium chloride Eschenmoser 盐
CAS Number30354-18-8
PubChem Substance ID24871926
EC Number250-142-4
Beilstein Registry Number505955
MDL NumberMFCD00011809
Chemical Name TranslationN,N-二甲基氯烯亚胺
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分类

  • {SNA} C-C Bond Formation, Chemical Synthesis, Others, Synthetic Reagents
  • Building Blocks, Chemical Synthesis, Imines/Amidines, Nitrogen Compounds, Organic Building Blocks
  • {SNA} C-C Bond Formation, Chemical Synthesis, Other Synthetic Reagents for C-C Bond Formation, Synthetic Reagents

相关文献及参考

  • 1. Johnson, T. W.; et al. J. Med. Chem. 54 , 3393, (2011)
  • 2. Percivalle, C.; et al. J. Org. Chem. 76 , 3096, (2011)
  • 3. Huber, K.; et al. Synthesis , 3849, (2010)
  • 4. Trzupek, J. D.; et al. J. Am. Chem. Soc. 132 , 8506, (2010)
  • 5. Liedtke, A. J.; et al. J. Med. Chem. 52 , 4968, (2009)
  • 6. Li, C.; et al. Angew. Chem. Int. Ed. Engl. 46 , 1448, (2007)
  • Beil. 4 ,IV,153
  • FT-NMR 1 (1), 1324:C

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H228 Flammable solid 易燃固体
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xi
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Others - C-C Bond Formation
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Others - C-C Bond Formation
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Imines/Amidines - Nitrogen Compounds

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