(Carbethoxymethyl)triphenylphosphonium bromide 乙氧甲酰基甲基三苯基溴化鏻

CAS 1530-45-6 MFCD00011835

化学结构图

1530-45-6
SMILES: CCOC(=O)C[P+](c1ccccc1)(c1ccccc1)c1ccccc1.[Br-]

化学属性

Mol. FormulaC22H22BrO2P
Mol. Weight429.29
Melting Point145-150°C
TSCANo
Density1.505
Stability易吸潮

别名和识别编码

Chemical Name(Carbethoxymethyl)triphenylphosphonium bromide
Synonym (2-Ethoxy-2-oxoethyl)triphenylphosphonium bromide {LY} (2-Ethoxy-2-oxoethyl)triphenylphosphonium bromide {} {LY} (2-Ethoxy-2-oxoethyl)triphenylphosphonium bromide {} {} {LY} (2-Ethoxy-2-oxoethyl)triphenylphosphonium bromide {} {} {} {LY} (2-Ethoxy-2-oxoethyl)triphenylphosphonium bromide {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)triphenylphosphonium bromide {} {} {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Ethoxy-2-oxoethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Beilstein Registry Number3581273
PubChem Substance ID73731
CAS Number1530-45-6
EC Number216-230-1
MDL NumberMFCD00011835
Reaxys-RN3581273
Chemical Name Translation乙氧甲酰基甲基三苯基溴化鏻
InChIKeyVJVZPTPOYCJFNI-UHFFFAOYSA-M
Wiswesser Line Notation2OV1PR&R&R &E &5/13
LabNetwork Molecule IDLN00190334
InChIInChI=1S/C22H22O2P.BrH/c1-2-24-22(23)18-25(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h3-17H,2,18H2,1H3;1H/q+1;/p-1
Canonical SMILESO=C(OCC)C[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[Br-]
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分类

  • {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

相关文献及参考

  • For reaction with trifluoroacetic anhydride and triethylamine, followed by pyrolysis as a route to perfluoroalkyl acetylenes, see: Org. Synth. Coll., 9, 436 (1998):
  • For reaction with trifluoroacetic anhydride and triethylamine, followed by pyrolysis as a route to perfluoroalkyl acetylenes, see: Org. Synth. Coll., 9, 436 (1998):
  • Beilstein: 16,IV,980

安全信息

Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
WGK Germany3
GHS Symbol
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
RTECSTA2299500
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition RT, stored under nitrogen {LY} RT, stored under nitrogen {} {LY} RT, stored under nitrogen {} {} {LY} RT, stored under nitrogen {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 25 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#12281

其他信息

  • 海关编码:29310095
  • Sigma Aldrich:1530-45-6(sigmaaldrich)
  • Alfa Aesar:(乙氧基羰基甲基）三苯基溴化膦,98+% (Ethoxycarbonylmethyl)triphenylphosphonium bromide, 98+%(1530-45-6)
  • F:9
  • Acros Organics:(羰乙氧基甲基)三苯基溴化磷 (Carbethoxymethyl)triphenylphosphonium bromide, 98%(1530-45-6)
  • TCI Shanghai:乙氧甲酰甲基三苯基溴化膦 Ethoxycarbonylmethyl(triphenyl)phosphonium Bromide,>;98.0%(T)(1530-45-6)
  • 乙氧甲酰基甲基三苯基溴化膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 E0407 乙氧羰基甲基(三苯基)溴化膦 Ethoxycarbonylmethyl(triphenyl)phosphonium Bromide 25G 409元 2014/06/02 E0407 乙氧羰基甲基(三苯基)溴化膦 Ethoxycarbonylmethyl(triphenyl)phosphonium Bromide 250G 2170元 2010/06/21 108300250 乙氧甲酰基甲基三苯基溴化膦 (Carbethoxymethyl)triphenylphosphonium bromide 98% 25 GR 323元
  • MOL 文件:1530-45-6.mol
  • MSDS 信息:(Carbethoxymethyl)triphenylphosphonium bromide(1530-45-6).msds
  • 乙氧甲酰基甲基三苯基溴化膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 E0407 乙氧羰基甲基(三苯基)溴化膦 Ethoxycarbonylmethyl(triphenyl)phosphonium Bromide 25G 451元 2011/04/16 E0407 乙氧羰基甲基(三苯基)溴化膦 Ethoxycarbonylmethyl(triphenyl)phosphonium Bromide 250G 2360元 2010/06/21 108300250 乙氧甲酰基甲基三苯基溴化膦 (Carbethoxymethyl)triphenylphosphonium bromide 98% 25 GR 323元
  • 图谱信息:乙氧甲酰基甲基三苯基溴化膦(1530-45-6)红外图谱(IR1) 乙氧甲酰基甲基三苯基溴化膦(1530-45-6)红外图谱(IR2) 乙氧甲酰基甲基三苯基溴化膦(1530-45-6)核磁图( 1 HNMR) 乙氧甲酰基甲基三苯基溴化膦(1530-45-6)核磁图( 13 CNMR) 乙氧甲酰基甲基三苯基溴化膦(1530-45-6)质谱(MS)
  • 外观性质:白色晶体。熔点：145-150 °C
  • 敏感性:Hygroscopic

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphorus Halides - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Wittig & Horner-Emmons Reaction
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Phosphonium Compounds

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