Tetrabutylphosphonium bromide 四丁基溴化鏻

CAS 3115-68-2 MFCD00011853

化学结构图

3115-68-2
SMILES: CCCC[P+](CCCC)(CCCC)CCCC.[Br-]

化学属性

Mol. FormulaC16H36BrP
Mol. Weight339.34
Melting Point99-104°C
TSCAYes
Flash Point290°C
SolubilityCA 70 G/100 ML
Stability对热敏感,易吸潮
Appearance 白色至类白色晶体,熔点99-104℃

别名和识别编码

Chemical NameTetrabutylphosphonium bromide
MDL NumberMFCD00011853
CAS Number3115-68-2
PubChem Substance ID76564
Beilstein Registry Number4160474
EC Number221-487-8
Synonym Tetrabutylphosphonium bromide {LY} Tetrabutylphosphonium bromide {} {LY} Tetrabutylphosphonium bromide {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {} {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {} {} {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {}
Reaxys-RN4160474
Chemical Name Translation四丁基溴化鏻
Wiswesser Line Notation4P4&4&4 &E
LabNetwork Molecule IDLN00198966
InChIInChI=1S/C16H36P.BrH/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1
Canonical SMILESCCCC[P+](CCCC)(CCCC)CCCC.[Br-]
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分类

  • {SNA} Chemical Synthesis, Phase Transfer Catalysts, Phosphonium Salts, Synthetic Reagents

产品应用

  • A useful synthetic reagent used in proteomics research.

相关文献及参考

  • Has been used as an ionic liquid solvent in the regioselective O-alkylation of C/O ambident nucleophiles: Tetrahedron Lett., 33, 4435 (1992); see Tetra-n-butyl­ammonium bromide, A10249.
  • Quaternary phosphonium salt, useful as a phase-transfer catalyst at high temperatures, at which nitrogen analogues tend to undergo elimination (see Appendix 2), e.g. as catalyst for the dealkoxycarbonylation of malonates and ß-keto esters by heating in stearic acid: Synthesis, 320 (1985).

安全信息

RTECSTA2417000
WGK Germany1
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Packing GroupIII
UN Number UN3464 3462 UN 3464 6.1/PG 3 2811
Risk Statements
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R24 Toxic in contact with skin 与皮肤接触有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr
GHS Symbol
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H310 Fatal in contact with skin 皮肤接触致命
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P302+P350
  • P302+P352
  • P302+P352+P310+P361+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard Codes Xn T;Xn 6.1
Hazard Class6.1
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >3 mg/m3/1H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXCYAC Toxicology.  (Elsevier Scientific Pub. Ireland, Ltd., POB 85,
   Limerick, Ireland) V.1-    1973-  Volume(issue)/page/year: 24,245,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#03131

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 700 mg/kg
TOXIC EFFECTS :
   Behavioral - ataxia
   Lungs, Thorax, or Respiration - dyspnea
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   TXCYAC Toxicology.  (Elsevier Scientific Pub. Ireland, Ltd., POB 85,
   Limerick, Ireland) V.1-    1973-  Volume(issue)/page/year: 24,245,1982

其他信息

  • 图谱信息:四丁基溴化(3115-68-2)红外图谱(IR1) 四丁基溴化(3115-68-2)质谱(MS) 四丁基溴化(3115-68-2)红外图谱(IR2) 四丁基溴化(3115-68-2)核磁图( 13 CNMR) 四丁基溴化(3115-68-2)核磁图( 1 HNMR)
  • 溶解度:70%水、20%甲醇、80%2-丙醇、50%甲苯。
  • 海关编码:29310095
  • 敏感性:Hygroscopic
  • Sigma Aldrich:3115-68-2(sigmaaldrich)
  • Acros Organics:四丁基溴化膦 Tetrabutylphosphonium bromide, 98%(3115-68-2)
  • 四丁基溴化价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1124 四丁基溴化磷 Tetrabutylphosphonium Bromide 25G 247元 2014/06/02 T1124 四丁基溴化磷 Tetrabutylphosphonium Bromide 500G 1940元 2010/06/21 183015000 四丁基溴化 Tetrabutylphosphonium bromide 98% 500 GR 1626元
  • TCI Shanghai:四丁基溴化磷 Tetrabutylphosphonium Bromide,>;99.0%(T)(3115-68-2)
  • Alfa Aesar:四正丁基溴化膦,typically95% Tetra-n-butylphosphonium bromide, typically 95%(3115-68-2)
  • MOL 文件:3115-68-2.mol
  • MSDS 信息:Tetrabutylphosphonium bromide(3115-68-2).msds

系列性分类


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