(Bromomethyl)Triphenylphosphonium Bromide 溴甲基三苯基溴化鏻

CAS 1034-49-7 MFCD00011864

化学结构图

1034-49-7
SMILES: BrC[P+](c1ccccc1)(c1ccccc1)c1ccccc1.[Br-]

化学属性

Mol. FormulaC19H17Br2P
Mol. Weight436.13
Melting Point234-236°C
Stability易吸潮

别名和识别编码

Chemical Name(Bromomethyl)Triphenylphosphonium Bromide
Synonym (Bromomethyl)triphenylphosphonium bromide {LY} (Bromomethyl)triphenylphosphonium bromide {} {LY} (Bromomethyl)triphenylphosphonium bromide {} {} {LY} (Bromomethyl)triphenylphosphonium bromide {} {} {} {LY} (Bromomethyl)triphenylphosphonium bromide {} {} {} {} {LY} (Bromomethyl)triphenylphosphonium bromide {} {} {} {} {} {LY} (Bromomethyl)triphenylphosphonium bromide {} {} {} {} {} {} {LY} (Bromomethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {LY} (Bromomethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {LY} (Bromomethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {LY} (Bromomethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} (Bromomethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {LY} (Bromomethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Bromomethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {
Beilstein Registry Number3579901
PubChem Substance ID87564142
CAS Number1034-49-7
EC Number213-857-2
MDL NumberMFCD00011864
Reaxys-RN3579901
Chemical Name Translation溴甲基三苯基溴化鏻
InChIKeyWBYZIDFHOQTQPE-UHFFFAOYSA-N
LabNetwork Molecule IDLN00190491
InChIInChI=1S/C19H17BrP.BrH/c20-16-21(17-10-4-1-5-11-17,18-12-6-2-7-13-18)19-14-8-3-9-15-19;/h1-15H,16H2;1H/q+1;/p-1
Canonical SMILESBrC[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[Br-]
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 2fragments; ionic
  • {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

产品应用

  • Wittig 试剂，用于合成溴烯烃（bromoalkenes） ，也可从醛（aldehydes）合成炔（alkynes）。

相关文献及参考

  • 1. D. Xu, et al., Beilstein J. Org. Chem. 7 , 937-943, (2011)
  • 2. Z. Zheng, et al., J. Agric. Food Chem. 59 , 1171-1177, (2011)
  • 3. M. Yoshino, et al., Heterocycles 81 , 381-394, (2010)
  • 4. J. Banuelos-Prieto, et al., Chem. Eur. J. 16 , 14094-14105, (2010)
  • 5. Z. Du and K. L. Erickson, J. Org. Chem. 75 , 7129-7140, (2010)
  • 6. Y. Li, et al., J. Am. Chem. Soc. 132 , 10374-10382, (2010)
  • Aldrich MSDS 1 , 268:A / Corp MSDS 1 (1), 554:B / FT-IR 1 (2), 546:A / FT-IR 2 (2), 3331:B / FT-NMR 1 (2), 1670:B / RegBook 1 (2), 2275:C / Structure Index 1 , 356:C:2
  • Short: III/35A Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Boron-11 and Phosphorus-31 Author: Gupta, R.R.; Jain, M.; Pardasani, P.; Pardasani, R.T.; Pelter, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35A Year: 1997 ISBN: 3-540-60366-2 ISBN: 978-3-540-60366-5 Internet Resource: DOI:10.1007/b53033 RefComment: VIII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Int

安全信息

Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
WGK Germany3
GHS Symbol
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • TCI Shanghai:溴甲基三苯基溴化磷 (Bromomethyl)triphenylphosphonium Bromide,>;98.0%(T)(1034-49-7)
  • 溴甲基三苯基溴化磷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1206 (溴甲基)三苯基溴化磷 (Bromomethyl)triphenylphosphonium Bromide 5G 596元 2014/06/02 B1206 (溴甲基)三苯基溴化磷 (Bromomethyl)triphenylphosphonium Bromide 25G 1790元 2010/06/21 321480250 溴甲基三苯基溴化磷 (Bromomethyl)triphenylphosphonium bromide 98% 25 GR 1902元
  • F:3-10
  • Sigma Aldrich:1034-49-7(sigmaaldrich)
  • Acros Organics:溴甲基三苯基溴化磷 (Bromomethyl)triphenylphosphonium bromide, 98%(1034-49-7)
  • MOL 文件:1034-49-7.mol
  • 图谱信息:溴甲基三苯基溴化磷(1034-49-7)红外图谱(IR2) 溴甲基三苯基溴化磷(1034-49-7)红外图谱(IR1) 溴甲基三苯基溴化磷(1034-49-7)核磁图( 1 HNMR) 溴甲基三苯基溴化磷(1034-49-7)质谱(MS) 溴甲基三苯基溴化磷(1034-49-7)核磁图( 13 CNMR)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphorus Halides - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Others - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Wittig & Horner-Emmons Reaction
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Phosphonium Compounds

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