(Chloromethyl)triphenylphosphonium chloride (氯甲基)三苯基氯化鏻

CAS 5293-84-5 MFCD00011867

化学结构图

5293-84-5
SMILES:

化学属性

Mol. FormulaC19H17Cl2P
Mol. Weight347.22
Melting Point262-264 °C

别名和识别编码

Chemical Name(Chloromethyl)triphenylphosphonium chloride
Synonym (Chloromethyl)triphenylphosphonium chloride {LY} (Chloromethyl)triphenylphosphonium chloride {} {LY} (Chloromethyl)triphenylphosphonium chloride {} {} {LY} (Chloromethyl)triphenylphosphonium chloride {} {} {} {LY} (Chloromethyl)triphenylphosphonium chloride {} {} {} {} {LY} (Chloromethyl)triphenylphosphonium chloride {} {} {} {} {} {LY} (Chloromethyl)triphenylphosphonium chloride {} {} {} {} {} {} {LY} (Chloromethyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Chloromethyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {LY} (Chloromethyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {LY} (Chloromethyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Chloromethyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} {} {LY} (Chloromethyl)triphenylphosphonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {LY} (Chloromethyl)triphenylphosphonium chloride {} {} {} {}
Beilstein Registry Number3599784
PubChem Substance ID197823
CAS Number5293-84-5
EC Number226-139-9
MDL NumberMFCD00011867
Reaxys-RN3599784
Chemical Name Translation(氯甲基)三苯基氯化鏻
InChIKeySXYFAZGVNNYGJQ-UHFFFAOYSA-M
Wiswesser Line NotationG1PR&R&R &G
LabNetwork Molecule IDLN00198479
InChIInChI=1S/C19H17ClP.ClH/c20-16-21(17-10-4-1-5-11-17,18-12-6-2-7-13-18)19-14-8-3-9-15-19;/h1-15H,16H2;1H/q+1;/p-1
Canonical SMILESC1=CC=C(C=C1)[P+](CCl)(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-]
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 2fragments; ionic
  • {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

相关文献及参考

  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa
  • 3. S. Sankararaman, Sci. Synth. 43 , 435-467, (2008)
  • Fieser 7 ,62 / Fieser 8 ,98
  • Short: III/35A Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Boron-11 and Phosphorus-31 Author: Gupta, R.R.; Jain, M.; Pardasani, P.; Pardasani, R.T.; Pelter, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35A Year: 1997 ISBN: 3-540-60366-2 ISBN: 978-3-540-60366-5 Internet Resource: DOI:10.1007/b53033 RefComment: VIII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.
  • 1. K. F. Khaled, Appl. Surf. Sci. 230 , 307-318, (2004)
  • 6. E. Alcazar, et al., Org. Lett. 6 , 3877-3880, (2004)
  • FT-IR 1 (2), 545:D / FT-IR 2 (2), 3330:D / FT-NMR 1 (2), 1670:A / RegBook 1 (2), 2275:A / Structure Index 1 , 356:A:2
  • 2. C. Lichtenberg, et al., Eur. J. Inorg. Chem. 20 , 3117-3124, (2011)
  • 4. H. Miyauchi, et al., Tetrahedron 63 , 5940-5953, (2007)
  • 5. A. Lindenschmidt, Sci. Synth. 25 , 237-275, (2007)

安全信息

Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P337+P313
  • P302+P352+P332+P313+P362+P364
WGK Germany3
GHS Symbol
Signal word Warning {} {} {} {} {} {} {} {TCI}
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
RTECSTA1882000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 32 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#04073

Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moist

其他信息

  • Sigma Aldrich:5293-84-5(sigmaaldrich)
  • Acros Organics:(氯甲基)三苯基氯化磷 (Chloromethyl)triphenylphosphonium chloride, tech., 95%(5293-84-5)
  • 图谱信息:(氯甲基)三苯基氯化磷(5293-84-5)质谱(MS) (氯甲基)三苯基氯化磷(5293-84-5)红外图谱(IR1) (氯甲基)三苯基氯化磷(5293-84-5)红外图谱(IR2)
  • (氯甲基)三苯基氯化磷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1009 (氯甲基)三苯基氯化磷 (Chloromethyl)triphenylphosphonium Chloride 5G 547元 2014/06/02 C1009 (氯甲基)三苯基氯化磷 (Chloromethyl)triphenylphosphonium Chloride 25G 1600元 2010/06/21 109530050 (氯甲基)三苯基氯化磷 (Chloromethyl)triphenylphosphonium chloride 95%, tech. 5 GR 553元
  • TCI Shanghai:氯甲基三苯基氯化磷 (Chloromethyl)triphenylphosphonium Chloride,>;98.0%(T)(5293-84-5)
  • MOL 文件:5293-84-5.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphorus Halides - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Others - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Wittig & Horner-Emmons Reaction
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Phosphonium Compounds

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