N,N'-Bis(salicylidene)ethylenediaminonickel(II) N,N′-二(亚水杨基)乙烯二氨基镍(II)

CAS 14167-20-5 MFCD00012041

化学结构图

14167-20-5
SMILES: C1CN=CC2C=CC=CC=2O[Ni]OC2C=CC=CC=2C=N1 |c:5,7,15,17,t:2,21|

化学属性

Mol. Formula[-CH2N=CHC6H4-2-(O-)]2Ni
Mol. Weight324.99

别名和识别编码

Chemical NameN,N'-Bis(salicylidene)ethylenediaminonickel(II)
Synonym Nickel(II) salen [[α,α'-(Ethylenedinitrilo)di-o-cresolato](2-)]nickel [[2,2'-[1,2-Ethanediylbis[(nitrilo-κN)methylidyne]]bis[phenolato-κO]](2-)]nickel {uni_hamburg} [[α,α'-(Ethylenedinitrilo)di-o-cresolato](2-)]nickel Nickel N,N'-bis(salicylal)ethylenediiminate N,N'-Bis(salicylidene)ethylenediamino-nickel(II) N,N′-二(亚水杨基)乙烯二氨基镍(II) Nickel(II) salen [[2,2'-[1,2-Ethanediylbis[(nitrilo-κN)methylidyne]]bis[phenolato-κO]](2-)]nickel
MDL NumberMFCD00012041
PubChem Substance ID24856287
Chemical Name TranslationN,N′-二(亚水杨基)乙烯二氨基镍(II)
CAS Number14167-20-5
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分类

  • {uni_hamburg}
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Nickel Catalysts
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Nickel

相关文献及参考

  • Short: III/10b Title: Structure Data of Organic Crystals: C 16 ... C 168 Author: Schudt-Weitz, G.; Strell, I. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/10b Year: 1985 ISBN: 3-540-13932-X ISBN: 978-3-540-13932-4 Internet Resource: DOI:10.1007/b19985 RefComment: XIX,652 pages. Hardcover

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P305+P351+P338
  • P308+P313
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P201 Obtain special instructions before use. 使用前获取专门指示。
Signal word Danger
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H350 May cause cancer 可能致癌
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
Hazard Codes T
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R45 May cause cancer 可能致癌
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R42/43

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Nickel - 镍催化剂

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