Erioglaucine disodium salt 亮蓝

CAS 3844-45-9 MFCD00012141

化学结构图

3844-45-9
SMILES: CCN(Cc1cccc(S(=O)(=O)O)c1)c1ccc(C(=C2C=CC(=[N+](CC)Cc3cccc(S(=O)(=O)[O-])c3)C=C2)c2ccccc2S(=O)(=O)O)cc1.[NaH]

化学属性

Mol. FormulaC37H34Na2N2O9S3
Mol. Weight793
Density1.233
Melting Point283
Solubility可溶
TSCAYes
Stability对光敏感
Appearance 蓝紫色粉末。易溶于水，于水中溶解度 (90℃) 为 50g/L，水溶液呈绿光蓝色，加入氢氧化钠后几乎呈无色，伴有深紫色沉淀出现。可溶于乙醇。于浓硫酸中为橙色，稀释后呈淡黄色。染色时对铜、铁离子敏感，影响色光。

别名和识别编码

Chemical NameErioglaucine disodium salt
CAS Number3844-45-9
Synonym BRILLIANT BLUE E Blue 1206 C.I. 42090 C.I. Acid Blue 9, disodium salt C.I.食品蓝2(42090) CI 42090 Cosmetic Blue Lak D and C blue no.4 DC blue no. 4 ERIOGLAUCINE A ERIOGLAUCINE SODIUM SALT Erioglaucin A Erioglaucine disodium salt F D and C blue #1 FD AND C BLUE NO 1 FD and C Blue 1 FD and C blue No.1 FDC Blue No. 1 FOOD BLUE NO 1 Hexacol Br INTRACID PURE BLUE L Intracid Pure Blue L Japan Blue 1 LAKE BRILLIANT BLUE FCF a.f.blueno.1 acid blue 9 blue 4 blue no. 1 brilliant blue brilliant blue Al (3:1) salt brilliant blue FCF brilliant blue FCF, diammonium salt brilliant blue di
EC Number223-339-8
Beilstein Registry Number14,855
MDL NumberMFCD00012141
PubChem Substance ID19700
Merck Number1373
Chemical Name Translation亮蓝
Reaxys-RN6265690
Wiswesser Line NotationL6Y DYJ AUYR BSWQ&R DN2&1R CSWQ&& DUK2&1R CSWQ &Q&-NA- 2
InChIKeySGHZXLIDFTYFHQ-UHFFFAOYSA-L
InChIInChI=1S/C37H36N2O9S3.2Na/c1-3-38(25-27-9-7-11-33(23-27)49(40,41)42)31-19-15-29(16-20-31)37(35-13-5-6-14-36(35)51(46,47)48)30-17-21-32(22-18-30)39(4-2)26-28-10-8-12-34(24-28)50(43,44)45;;/h5-24H,3-4,25-26H2,1-2H3,(H2-,40,41,42,43,44,45,46,47,48);;/q;2*+1/p-2
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分类

  • {SNA} E-F, Stains & Dyes, A to Z, Stains and Dyes, 细胞生物学, 血液学和组织学
  • Sulfur & Selenium Compounds
  • {Chemicalbook} 染料: 酸性染料: 强酸性染料
  • Pharmaceuticals
  • {SNA} E-F, Hematology and Histology, Stains & Dyes, A to Z, Stains and Dyes
  • Intermediates & Fine Chemicals
  • Aromatics

产品应用

  • 可用于食品中合成色素检测方法的校准和标准化，也可作为工作标准，用于日常分析和检测。

相关文献及参考

  • Hansen, W.H., et al.: Toxicol. Appl. Pharmacol., 8, 29 (1966),
  • Merck: 14,1373
  • Brown, J.P., et al.: Food Cosmetic Toxicol., 18, 1 (1980),
  • Borzelleca, J.F., et al.: Food Chem. Toxicol., 28, 221 (1990),
  • Merck: 14,1373 Beilstein: 14,855

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R33 Danger of cumulative effects 有累积作用的危险
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R52/53
Precautionary statements
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P273 Avoid release to the environment. 避免释放到环境中。
RTECSBQ4725000
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Hazard Codes Xn
Storage condition 常温避光处保存。 常温保存。 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5500 mg/kg/97W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   ZEKBAI Zeitschrift fuer Krebsforschung.  (Berlin, Fed. Rep. Ger.)  V.1-75,
   1903-71.  For publisher information, see JCROD7.  Volume(issue)/page/year:
   64,287,1961

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Parenteral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4580 mg/kg/62W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Gastrointestinal - tumors
   Blood - lymphoma, including Hodgkin's disease
REFERENCE :
   FAONAU FAO Nutrition Meetings Report Series.  (Rome, Italy)  No.?-57,
   1948-77.  Discontinued.  Volume(issue)/page/year: 38B,27,1966

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2 gm/kg/94W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   FAONAU FAO Nutrition Meetings Report Series.  (Rome, Italy)  No.?-57,
   1948-77.  Discontinued.  Volume(issue)/page/year: 38B,27,1966

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 4600 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   ZEKBAI Zeitschrift fuer Krebsforschung.  (Berlin, Fed. Rep. Ger.)  V.1-75,
   1903-71.  For publisher information, see JCROD7.  Volume(issue)/page/year:
   64,287,1961

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 4400 mg/L
REFERENCE :
   GMCRDC Gann Monograph on Cancer Research.  (Plenum Pub. Corp., 233 Spring
   St., New York, NY 10013) No. 11-    1971-  Volume(issue)/page/year:
   27,95,1981

Hazard statements
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。

其他信息

  • 图谱信息:食用色素亮蓝(3844-45-9)红外图谱(IR1) 食用色素亮蓝(3844-45-9)红外图谱(IR2)
  • 所属类别三:饲料添加剂: 饲料着色剂
  • 所属类别二:食品添加剂: 着色剂
  • 色指数:42090
  • 生产方法:由邻磺酸苯甲醛与a-（N-乙基苯氨基）间甲苯磺酸在酸性介质中缩合成隐色体。再经重铬酸钠或二氧化铅氧化得到色素，中和后用硫酸钠盐析，再精制而得。生产中，缩合反应一般需几十
  • 稳定性:Stable. Incompatible with strong oxidizing agents.
  • 易溶于水，水溶液呈蓝色。可溶于甘油，乙醇及丙二醇。耐光性，耐热性，耐酸性，耐碱性均好，对柠檬酸，酒石酸稳定。
  • 上游原料:苯甲醛 --> 重铬酸钾 --> N-苄基苯胺 --> 邻磺酸
  • MOL 文件:2650-18-2.mol
  • 含量分析:按OT-15中方法二测定。条件如下：试样量为1.8～1.9g；缓冲液用15g酒石酸氢钠配制。 每毫升0.1 mol/L TiCl 3 相当于色素物质0.03965 g。
  • 用途一:适用于丝绸、羊毛、锦纶的染色与印花
  • 使用限量:GB 2760-2001(g/kg)：果汁(味)饮料类、碳酸饮料、配制酒、糖果、糕点上彩装、染色樱桃罐头(系装饰用)、青梅、虾(味)片、冰激凌、油炸豆类、冰棍、果冻、雪糕、膨化食品、风味乳饮料、风味酸奶、寿桃包、威化饼干夹心，0.025；红绿丝0.10；固体饮料0.2；糖果包衣、膨化食品、油炸小食品，0.05；可可玉米片(即食早餐谷物)0.015；绿芥末膏0.01。
  • 参考质量标准二:GB7655.1—96(亮蓝) 亮蓝85 亮蓝60 含量/% ≥85.0 ≥60.0 干燥减量/% ≤10 水不溶物/% ≤0.2 ≤0.3 异丙醚萃取物/% ≤0
  • 食用色素亮蓝价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0790 酸性蓝9 Acid Blue 9 25G 380元 2014/06/02 F0147 食品蓝1 Food Blue No. 1 25G 1050元 2010/06/21 229730250 食用色素亮蓝 Erioglaucine disodium salt , pure 25 GR 554元
  • 用途:作为食品和饲料着色剂，我国规定可用于红绿丝中，最大使用量为0.10g/kg；在果汁（味）饮料、碳酸饮料、配制酒、糖果、糕点上彩装、染色樱桃罐头（系装饰用）、青梅、虾（味）片和冰淇淋中，最大使用量0.025g/kg。
  • 用途二:酸性蓝 FG 用于羊毛、蚕丝、锦纶、羊毛混纺织物的染色和羊毛、蚕丝
  • RTECS号:BQ4725000
  • EPA化学物质信息:Benzenemethanaminium, N-ethyl-N-[4-[[4-[ethyl[(3- sulfophenyl)methyl]amino] phenyl](2-sulfophenyl)methylene]- 2,5-cyclohexadien-1-ylidene]- 3-sulfo-, inner salt, disodium salt(3844-45-9)
  • 参考质量标准一:GB 7655.1—1996(亮蓝) 亮蓝85 亮蓝60 含量/% ≥85.0 ≥60.0 干燥减量/% ≤10 - 水不溶物/% ≤O.2 ≤O.3 异丙醚萃取物/% ≤0.3 - 水溶性氯化物和硫酸盐/% ≤4.0 - 副染料/% ≤6.0 - 砷(As)/% ≤0.0001 - 铅(Pb)/% ≤0.001 - 铬(Cr)/% ≤0.005 - 锰(Mn)/% ≤0.005 - GB 7655.2—1996(亮蓝铝色淀) 含量/% ≥10.0 盐酸和氨不溶物/% ≤0.5 水溶性氯化物和硫酸盐/% ≤2.0 干燥失重(135℃，6h)/% ≤30.0 副染料/% 1.2 重金属(以Pb计)/% ≤0.002 砷(As)/% ≤0.0003 钡/% ≤0.05
  • MOL 文件:3844-45-9.mol

系列性分类

  1. Life Science 生命科学
  2. Hematology and Histology 血液学和组织学
  3. Stains and Dyes - Hematology and Histology
  4. Stains & Dyes, A to Z - Stains and Dyes
  5. E-F - Stains & Dyes, A to Z
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. E - Alphabetic
  5. EQ - EZ - E
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonates/Sulfinates - Sulfur Compounds
  1. Analytical & Chromatography 分析化学与色谱
  2. Food Colors by Food Sanitation Law in Japan
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Biochemicals and Reagents
  4. Stains and Dyes
  5. Natural Dyes
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Hematology and Histology
  4. Stains and Dyes
  5. Stains & Dyes, A to Z
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Hemotology and Histology
  4. Stains and Dyes
  5. Stains & Dyes, A to Z

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