Tetramethylammonium triacetoxyborohydride 四甲基三乙酰氧硼氢化铵

CAS 109704-53-2 MFCD00012196

化学结构图

109704-53-2
SMILES: CC(=O)O[BH-](OC(C)=O)OC(C)=O.C[N+](C)(C)C

化学属性

Mol. FormulaC10H22BNO6
Mol. Weight263.10
Melting Point93-98
TSCANo

别名和识别编码

Chemical NameTetramethylammonium triacetoxyborohydride
MDL NumberMFCD00012196
PubChem Substance ID87577312
Beilstein Registry Number8238791
CAS Number109704-53-2
Synonym 四甲基三乙酰氧硼氢化铵
EC Number000-000-0
Reaxys-RN8238791
Chemical Name Translation四甲基三乙酰氧硼氢化铵
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分类

  • {SNA} Borohydrides, Chemical Synthesis, Reduction, Synthetic Reagents

相关文献及参考

  • Reduces ß-hydroxy ketones in 1:1 MeCN_-_AcOH to give 1,3-diols with high anti-stereoselectivity: J. Am. Chem. Soc., 110, 3560 (1988). Under similar conditions, ß-hydroxy oximino ethers are reduced stereoselectively to the hydroxylamine ethers: J. Am. Chem. Soc., 114, 8750 (1992). ɑ-Hydroxy oximino ethers are also reduced to syn-1,2-hydroxyamine derivatives: Tetrahedron Lett., 34, 3271 (1993).

安全信息

GHS Symbol
Precautionary statements
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
  • P231+P232
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P370+P378
  • P422 Store contents under… 存储目录在…之下。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
  • H319 Causes serious eye irritation 严重刺激眼睛
WGK Germany3
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
Hazard Codes 4.3
Risk Statements
  • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Packing GroupII
UN Number 2813
Storage condition Moisture Sensitive 0-10 0-10°C
Hazard Class4.3

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  4. Borohydrides - Reduction
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  4. Borohydrides - Reduction
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Quaternary Ammonium Compounds 季铵化合物
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物

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