Borane triethylamine complex 硼烷-三乙胺络合物

CAS 1722-26-5 MFCD00012423

化学结构图

1722-26-5
SMILES: [BH3-][N+](CC)(CC)CC

化学属性

Mol. FormulaC6H18BN
Mol. Weight115.02
Density0.777
Flash Point-7°C(lit.)
TSCAYes
Melting Point-4--2 °C
Boiling Point97 °C at 12 mmHg
Refractive index1.4420 to 1.4450
SolubilityMAY DECOMPOSE

别名和识别编码

Chemical NameBorane triethylamine complex
Synonym Borane-triethylamine complex {LY} Borane-triethylamine complex {} {LY} Borane-triethylamine complex {} {} {LY} Borane-triethylamine complex {} {} {} {LY} Borane-triethylamine complex {} {} {} {} {LY} Borane-triethylamine complex {} {} {} {} {} {LY} Borane-triethylamine complex {} {} {} {} {} {} {LY} Borane-triethylamine complex {} {} {} {} {} {} {} {LY} Borane-triethylamine complex {} {} {} {} {} {} {} {} {LY} Borane-triethylamine complex {} {} {} {} {} {} {} {} {} {LY} Borane-triethylamine complex {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Borane-triethylamine complex {} {} {} {} {} {} {} {} {} {} {} {LY} Borane-triethylamine complex {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Borane-triethylamine complex {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Borane-triethylamine complex {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Borane-triethylamine complex {} {} {} {
MDL NumberMFCD00012423
CAS Number1722-26-5
EC Number217-022-3
PubChem Substance ID87576963
Reaxys-RN3666989
Chemical Name Translation硼烷-三乙胺络合物
LabNetwork Molecule IDLN01363617
Canonical SMILES[H-][B+3]([H-])([N](CC)(CC)CC)[H-]
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分类

  • {uni_hamburg} no charge; 1fragment
  • {SNA} Boranes, Chemical Synthesis, Reduction, Synthetic Reagents

相关文献及参考

  • Short: III/35A Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Boron-11 and Phosphorus-31 Author: Gupta, R.R.; Jain, M.; Pardasani, P.; Pardasani, R.T.; Pelter, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35A Year: 1997 ISBN: 3-540-60366-2 ISBN: 978-3-540-60366-5 Internet Resource: DOI:10.1007/b53033 RefComment: VIII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
Packing GroupII
UN Number 2924 UN2924
Risk Statements
  • R11 Highly flammable 非常易燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R34 Causes burns 会导致灼伤
Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture Moisture Sensitive Refrigerator {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {
GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H332 Harmful if inhaled 吸入有害
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H312 Harmful in contact with skin 皮肤接触有害
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P304+P340+P312
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P370+P378
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard Codes 3 F,C
Hazard Class3/8

其他信息

  • 三乙胺-硼烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1180 三乙胺硼烷 Triethylamine Borane 25G 656元 2010/06/21 402731000 三乙胺-硼烷 Borane-triethylamine complex 97% 100 GR 2610元 2010/06/21 402730250 三乙胺-硼烷 Borane-triethylamine complex 97% 25 GR 914元
  • TCI Shanghai:三乙基胺 硼烷 Triethylamine Borane,>;90.0%(T)(1722-26-5)
  • 敏感性:Moisture Sensitive
  • Sigma Aldrich:1722-26-5(sigmaaldrich)
  • F:10-21
  • MSDS 信息:Triethylamine borane(1722-26-5).msds
  • 图谱信息:三乙胺-硼烷(1722-26-5)核磁图( 1 HNMR) 三乙胺-硼烷(1722-26-5)红外图谱(IR1) 三乙胺-硼烷(1722-26-5)核磁图( 13 CNMR) 三乙胺-硼烷(1722-26-5)质谱(MS)
  • Alfa Aesar:三乙基氨硼烷,95+%,在氩气保护下储存在ChemSeal密封瓶中密封 Borane-triethylamine complex, 96%, packaged under Argon in resealable ChemSeal™ bottles(1722-26-5)
  • MOL 文件:1722-26-5.mol
  • Acros Organics:硼烷三乙基胺 Borane-triethylamine complex, 97%(1722-26-5)

系列性分类


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