Triphenylphosphine Borane 硼烷三苯基膦络合物

CAS 2049-55-0 MFCD00012427

化学结构图

2049-55-0
SMILES: B.c1ccc(P(c2ccccc2)c2ccccc2)cc1

化学属性

Mol. FormulaC18H19BP
Mol. Weight277.13
Melting Point189-191 °C
TSCANo

别名和识别编码

Chemical NameBorane - Triphenylphosphine Complex
MDL NumberMFCD00012427
CAS Number2049-55-0
Synonym Triphenylphosphine Borane {LY} Triphenylphosphine Borane {} {LY} Triphenylphosphine Borane {} {} {LY} Triphenylphosphine Borane {} {} {} {LY} Triphenylphosphine Borane {} {} {} {} {LY} Triphenylphosphine Borane {} {} {} {} {} {LY} Triphenylphosphine Borane {} {} {} {} {} {} {LY} Triphenylphosphine Borane {} {} {} {} {} {} {} {LY} Triphenylphosphine Borane {} {} {} {} {} {} {} {} {LY} Triphenylphosphine Borane {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine Borane {} {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine Borane {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine Borane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine Borane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine Borane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine Borane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine Borane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
PubChem Substance ID6364612
Reaxys-RN4020299
Chemical Name Translation硼烷三苯基膦络合物
Canonical SMILES[H-][B+3]([H-])(P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3)[H-]
InChIInChI=1S/C18H15P.B/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h1-15H;
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分类

  • {SNA} Boranes, Chemical Synthesis, Reduction, Synthetic Reagents

安全信息

Safety Statements
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
Packing GroupII
UN Number
Risk Statements
  • R11 Highly flammable 非常易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture Air & Moisture Sensitive Refrigerator {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moist
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word
Hazard statements
  • H228 Flammable solid 易燃固体
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P231+P232
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P301+P317
  • P302+P350
  • P302+P352
  • P302+P352+P312+P362+P364
  • P304+P312
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P402+P404
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
GHS Symbol
Hazard Class4.3
Hazard Codes

其他信息

  • 敏感性:Air & Moisture Sensitive
  • 硼烷三苯基膦络合物价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1789 硼烷三苯基膦络合物 Triphenylphosphine Borane 25G 1030元 2010/05/25 42969 三苯基膦硼烷复合物 Borane-triphenylphosphine complex 5g 314元
  • TCI Shanghai:硼烷三苯基膦络合物 Triphenylphosphine Borane,>;97.0%(T)(2049-55-0)
  • Sigma Aldrich:2049-55-0(sigmaaldrich)
  • Alfa Aesar:三苯基膦硼烷复合物 Borane-triphenylphosphine complex(2049-55-0)
  • MOL 文件:2049-55-0.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  4. Boranes - Reduction
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  4. Boranes - Reduction
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  1. Functional Group 官能团索引
  2. phosphine

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