Ammonium L-(+)-tartrate L-酒石酸铵

CAS 3164-29-2 MFCD00013073

化学结构图

3164-29-2
SMILES: O=C([O-])C(O)C(O)C(=O)[O-].[NH4+].[NH4+]

化学属性

Mol. FormulaC4H12N2O6
Mol. Weight184.15
Density1.601
SolubilitySoluble in water, alcohol
TSCAYes
Appearance crystalline 酒石酸铵(3164-29-2)为无色结晶体。相对密度为1.061。易溶于水，在20℃水中溶解度为38.65%，在60℃水中为46.52%；极微溶于醇。受热分解。露置空气中将逐渐放出氨而呈酸性反应。
Stability对湿度敏感
Boiling Point318.08 °C at 760 mmHg

别名和识别编码

Chemical NameAmmonium L-(+)-tartrate
Synonym L-Tartaric acid (diammonium) {LY} L-Tartaric acid (diammonium) {} {LY} L-Tartaric acid (diammonium) {} {} {LY} L-Tartaric acid (diammonium) {} {} {} {LY} L-Tartaric acid (diammonium) {} {} {} {} {LY} L-Tartaric acid (diammonium) {} {} {} {} {} {LY} L-Tartaric acid (diammonium) {} {} {} {} {} {} {LY} L-Tartaric acid (diammonium) {} {} {} {} {} {} {} {LY} L-Tartaric acid (diammonium) {} {} {} {} {} {} {} {} {LY} L-Tartaric acid (diammonium) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Tartaric acid (diammonium) {} {} {} {} {} {} {} {} {} {} {LY} L-Tartaric acid (diammonium) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Tartaric acid (diammonium) {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Tartaric acid (diammonium) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Tartaric acid (diammonium) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-Tartaric acid (diammonium) {} {} {} {} {} {} {}
CAS Number3164-29-2
PubChem Substance ID2724224
Beilstein Registry Number6120352
EC Number221-618-9
MDL NumberMFCD00013073
Chemical Name TranslationL-酒石酸铵
Wiswesser Line NotationQVYQYQVQ &ZH 2
LabNetwork Molecule IDLN02124371
InChIInChI=1S/C4H6O6.2H3N/c5-1(3(7)8)2(6)4(9)10;;/h1-2,5-6H,(H,7,8)(H,9,10);2*1H3
Canonical SMILESO=C(O)[C@H](O)[C@@H](O)C(O)=O.N.N
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分类

  • {SNA} BioXtra Buffers, Biochemicals and Reagents, Buffers A to Z, Chelators, 生物缓冲液
  • {SNA} Alphabetical, BioUltra Buffers, Biochemicals and Reagents, Biological Buffers, Chelators, Molecular Biology, Optimization Reagent
  • {SNA} BioXtra Buffers, Buffers A to Z,

产品应用

  • 测定铅、镍、磷和铌等的掩蔽剂。作分析试剂和有机合成中间体。

相关文献及参考

  • Beilstein: 3,IV,1218

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
RTECSWW8050000
Safety Statements
Risk Statements
  • R52/53
Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 113 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBAMAK "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." (Leipzig,
   Ger. Dem. Rep.)  Volume(issue)/page/year: 4,1289,1935

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1130 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBAMAK "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." (Leipzig,
   Ger. Dem. Rep.)  Volume(issue)/page/year: 4,1289,1935

Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激

其他信息

  • 用途三:测定铅、镍、磷和铌等的掩蔽剂。作分析试剂和有机合成中间体。
  • 用途一:用于制药工业等
  • 方法一:（1）用酒石酸与碳酸铵作用而得将酒石酸溶于水中，慢慢加入碳酸铵，直至溶液对酚酞呈弱碱性。煮沸20-30min。于水浴上蒸发，当出现结晶薄膜时迅速过滤，将滤液冷却，过滤，结晶体在40℃干燥，即得成品。产率为80%。（2）使酒石酸和氨在乙醇中反应将氨气通入酒石酸的乙醇溶液中，生成无定形粉末状沉淀。过滤，用乙醇和乙醚洗涤，干燥即得成品。
  • 图谱信息:酒石酸铵(3164-29-2)红外图谱(IR1) 酒石酸铵(3164-29-2)红外图谱(IR2) 酒石酸铵(3164-29-2)Raman光谱
  • MSDS 信息:2,3-Dihydroxybutanedioic acid diammonium salt(3164-29-2).msds
  • 下游产品:盐霉素
  • 上游原料:氢氧化铵 --> 氨 --> 4-氯苯甲醛 --> 碳酸铵 --> 左旋酒石酸 --> 酒石酸 --> DL-酒石酸 --> 酚酞
  • 水中溶解度(g/100ml):不同温度(℃)时每100毫升水中的溶解克数: 45g/0℃;55g/10℃;63g/20℃;70.5g/30℃;76.5g/40℃ 86.9g/60℃
  • MOL 文件:3164-29-2.mol
  • Sigma Aldrich:3164-29-2(sigmaaldrich)
  • 酒石酸铵价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30012518 酒石酸铵 500g 161元 2010/06/21 211810050 酒石酸铵 L(+)-Tartaric acid diammonium salt 99% 5 GR 151元 2010/06/21 211810010 酒石酸铵 L(+)-Tartaric acid diammonium salt 99% 1 KG 1588元
  • 用途二:作分析试剂和有机合成中间体。
  • Acros Organics:L(+)-Tartaric acid diammonium salt, 99%(3164-29-2)
  • 比旋光度:32.4 ° (c=1.84, H2O)
  • Alfa Aesar:L-酒石酸铵,99% Ammonium L-(+)-tartrate, 98%(3164-29-2)
  • 易风化，在空气中失去氨。溶于水，不溶于醇及丙酮。碱性。150°升华并分解。一般商品常制成25%溶液。

系列性分类

  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Chelators - Biochemicals and Reagents
  1. Life Science 生命科学
  2. Biological Buffers 生理缓冲剂
  3. BioUltra Buffers - Biological Buffers
  4. Alphabetical - BioUltra Buffers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Oximes - Nitrogen Compounds
  1. Life Science 生命科学
  2. Proteomics 蛋白质组学
  3. Protein Structural Analysis - Proteomics
  4. X-Ray Crystallography - Protein Structural Analysis
  5. Optimization Reagents - X-Ray Crystallography
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. BioChemika Ultra
  4. Crystallization
  1. Functional Group 官能团索引
  2. alpha-hydroxyacid
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Centrifugation Media

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