Potassium Formate 甲酸钾

CAS 590-29-4 MFCD00013100

化学结构图

590-29-4
SMILES: O=C[O-].[K+]

化学属性

Mol. FormulaHCOOK
Mol. Weight84.12
Melting Point165-168
Density1.91
SolubilitySoluble in water
TSCAYes
Stability易吸潮
Appearance 易溶于水,无毒无腐蚀。 熔点165-168℃,密度 1.560 ;g/mL ;at 20 ;°C

别名和识别编码

Chemical NamePotassium Formate
Synonym Formic acid, potassium salt Formic acid, potassium salt (1:1) Kaliumformiat POTASSIUM FORMATE POTASSIUM FORMATE SOLUTION 14M Potassium formate Potassium formate, pract., 96% aluminum formate ammonium formate ammonium tetraformate calcium formate chromic formate cobalt(II) formate dihydrate cobaltous formate cupric formate f formate formatedepotassium formic acid formic acid potassium salt formic acid, 14C-labeled formic acid, aluminum salt formic acid, ammonium (2:1) salt formic acid, ammonium (4:1) salt formic acid, ammonium salt formic acid, cadmium salt formic acid, calcium salt formic acid, cesium salt formic acid, cobalt (+2) salt
MDL NumberMFCD00013100
CAS Number590-29-4
PubChem Substance ID2735122
Beilstein Registry Number3623272
EC Number209-677-9
Merck Number14,7633
Chemical Name Translation甲酸钾
Wiswesser Line NotationVHO &-KA-
LabNetwork Molecule IDLN00196591
InChIInChI=1S/CH2O2.K/c2-1-3;/h1H,(H,2,3);/q;+1/p-1
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分类

  • {SNA} Alphabetical, BioUltra Buffers, Optimization Reagents, X-Ray Crystallography, 分子生物学, 生化试剂, 生物缓冲液, 蛋白质组学, 蛋白质结构分析
  • {SNA} Chemical Synthesis, Inorganic Salts, Potassium, Synthetic Reagents
  • {uni_hamburg} no charge; carboxylate; 2fragments; ionic
  • {SN

相关文献及参考

  • Merck:14,7633 Beilstein: 2,IV,14
  • Short: IV/1a
  • Short: IV/1b
  • Merck:14,7633
  • Short: IV/4

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
RTECSLQ9625000
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 无毒无害。易吸潮,密封保存。 Hygroscopic
Hazard Codes Xi
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 5500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ZERNAL Zeitschrift fuer Ernaehrungswissenschaft.  (Dr. Dietrich Steinkopff
   Verlag, Postfach 111008, D-6100 Darmstadt 11, Fed. Rep. Ger.)  V.1- 1960- 
   Volume(issue)/page/year: 9,332,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 95 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ZERNAL Zeitschrift fuer Ernaehrungswissenschaft.  (Dr. Dietrich Steinkopff
   Verlag, Postfach 111008, D-6100 Darmstadt 11, Fed. Rep. Ger.)  V.1- 1960- 
   Volume(issue)/page/year: 9,332,1969

GHS Symbol
Signal word
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激

其他信息

  • MOL 文件:590-29-4.mol
  • Alfa Aesar:甲酸钾,99% Potassium formate, 99% (water less than 2%)(590-29-4)
  • 下游产品:2,4-二氯苯甲酸 --> 2-巯基-5-甲基-1,3,4-噻二唑 --> 羟基丙酮
  • 概述:常温下为无色透明液体或者白色固体,极易吸潮,具有还原性,能与强氧化剂反应,密度为1.9100g/cm3 ,易溶于水, 饱和溶液比重为1.58 g/cm3,无毒无腐蚀。将一氧化碳与氢氧化钾一起加热可以合成甲酸钾,进一步酸化和蒸馏得到了 甲酸。
  • Acros Organics:甲酸钾 Potassium formate, pract., 96%(590-29-4)
  • 用途一:主要用于配制含水油井加注液
  • 图谱信息:甲酸钾(590-29-4)Raman光谱 甲酸钾(590-29-4)红外图谱(IR1) 甲酸钾(590-29-4)红外图谱(IR2)
  • 敏感性:Hygroscopic
  • Sigma Aldrich:590-29-4(sigmaaldrich)
  • 甲酸钾价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30155618 甲酸钾;蚁酸钾 500g 178元 2010/06/21 418221000 甲酸钾 Potassium formate 96%, pract. 100 GR 520元 2010/06/21 418225000 甲酸钾 Potassium formate 96%, pract. 500 GR 553元
  • MSDS 信息:Formic acid potassium salt(590-29-4).msds
  • 水中溶解度(g/100ml):不同温度(℃)时每100毫升水中的溶解克数: 313g/10℃;337g/20℃;361g/30℃;398g/40℃ 471g/60℃;580g/80℃;658g/90℃
  • 饱和溶液比重为1.58 g/cm3;固体为白色结晶性粉末,极易吸潮,具有还原性,能与强氧化剂反应,易溶于水,无毒无腐蚀。
  • TSCA:Yes

系列性分类


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