Allylboronic Acid Pinacol Ester 烯丙基硼酸频哪醇酯

CAS 72824-04-5 MFCD00013347

化学结构图

72824-04-5
SMILES: CC1(C)OB(CC=C)OC1(C)C

化学属性

Mol. FormulaC9H17BO2
Mol. Weight168
Refractive index1.4250 to 1.4290
Boiling Point50-53
Density0.896
Flash Point46°C(lit.)
TSCANo

别名和识别编码

Chemical NameAllylboronic Acid Pinacol Ester
CAS Number72824-04-5
Alfabeta NameALLYLBORONICACIDPINACOLCYCLICESTER ,
MDL NumberMFCD00013347
Synonym AKOS BRN-1082 Allylboronic acid pinacolate 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, Pinacol allylboronate ALLBORONIC ACID,PINACOL CYCLIC ESTER 2-ALLYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE 烯丙基硼酸频哪醇酯 PINACOL ALLYLBORONATE 丙烯基硼酸邻二叔醇酯 Allylboronic acid pinacol ester, 98+% Allylboronic acid piracol ester 4,4,5,5-Tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane 2-烯丙基-4,4,5,5-四甲基-1,3,2-二氧杂环戊硼烷 2-烯丙基-4,4,5,5-四甲基-1,3,2-二氧环戊硼烷 4,4,5,5-tetramethyl-2-(2-propen-1-yl)-1,3,2-dioxaborolane 4,4,5,5-tetramethyl-2-(2-propenyl)-1,3,2-dioxaborolane Allyl pinacol boronate Pinacolyl 2-propenylboronate 丙烯基硼酸频哪醇酯 丙烯基硼酸邻二叔醇酯R, 98+% 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ALLYLBORONIC ACID, PINACOL CYCLIC ESTER ALLYLBORONIC ACID PINACOL ESTER
PubChem Substance ID87560602
Beilstein Registry Number4244068
Chemical Name Translation烯丙基硼酸频哪醇酯
Reaxys-RN4244068
LabNetwork Molecule IDLN00008794
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分类

  • {SNA} Alkyl Boronate Esters, Boronate Esters, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents

相关文献及参考

  • Reacts with carboxylic acids, in the presence of tri-n-butyltin hydride, to give homoallylic alcohols in good yield: Synthesis, 1573 (2001):
  • Homoallylic alcohols can also be formed by allylboration of aldehydes; the reaction has been found to be accelerated by Lewis acids, e.g. AlCl3 or Sc(OTf)3: J. Am. Chem. Soc., 124, 12414 (2002).

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P370+P378
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Packing GroupIII
UN Number 1993 3272
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Hazard Codes 3
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Hazard Class3
Storage condition Refrigerator <0°C 储存温度2-8°C

其他信息

  • TCI Shanghai:2-烯丙基-4,4,5,5-四甲基-1,3,2-二氧杂硼烷 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane,>;97.0%(GC)(72824-04-5)
  • 海关编码:29310095
  • Alfa Aesar:丙烯基硼酸邻二叔醇酯r,98+% Allylboronic acid pinacol ester, 98+%(72824-04-5)
  • 烯丙基硼酸频哪醇酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A2157 2-烯丙基-4,4,5,5-四甲基-1,3,2-二氧杂环戊硼烷(含稳定剂噻吩嗪) 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) 5G 1390元 2014/06/02 A2157 2-烯丙基-4,4,5,5-四甲基-1,3,2-二氧杂环戊硼烷(含稳定剂噻吩嗪) 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) 1G 455元 2010/06/21 395130010 烯丙基硼酸频哪醇酯 Allylboronic acid pinacol ester 98% 1 GR 449元
  • Hazard Note:Irritant
  • Sigma Aldrich:72824-04-5(sigmaaldrich)
  • MOL 文件:72824-04-5.mol
  • 烯丙基硼酸频哪醇酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 A2157 2-烯丙基-4,4,5,5-四甲基-1,3,2-二氧杂环戊硼烷(含稳定剂噻吩嗪) 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) 5G 1310元 2011/04/16 A2157 2-烯丙基-4,4,5,5-四甲基-1,3,2-二氧杂环戊硼烷(含稳定剂噻吩嗪) 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) 1G 436元 2010/06/21 395130010 烯丙基硼酸频哪醇酯 Allylboronic acid pinacol ester 98% 1 GR 449元
  • Acros Organics:Allylboronic acid pinacol ester, 98%(72824-04-5)
  • MSDS 信息:2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(72824-04-5).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronate Esters 硼酸酯
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronate Esters 硼酸酯
  5. Alkyl Boronate Esters - Boronate Esters
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronate Esters 硼酸酯
  5. Alkyl Boronate Esters - Boronate Esters
  1. Functional Group 官能团索引
  2. boronic acid ester

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