1-Fluoropyridinium Triflate 1-氟吡啶三氟甲磺酸盐
CAS 107263-95-6 MFCD00013458
化学结构图
SMILES: F[n+]1ccccc1.O=S(=O)([O-])C(F)(F)F
化学属性
| Mol. Formula | C6H5F4NO3S |
|---|---|
| Mol. Weight | 247 |
| Melting Point | 185-186 |
| TSCA | No |
别名和识别编码
| Chemical Name | 1-Fluoropyridinium Triflate |
|---|---|
| CAS Number | 107263-95-6 |
| Alfabeta Name | FLUOROPYRIDINIUMTRIFLUOROMETHANESULFONATE N- |
| MDL Number | MFCD00013458 |
| Synonym | PYRIDINIUM,1-FLUORO-TRIFLUOROMETHANESULFONIC ACID(1:1) 1-氟吡啶三氟甲磺酸盐 三氟甲磺酸N-吡啶鎓 N-氟吡啶三氟甲磺酸盐 N-FLUOROPYRIDINIUM TRIFLATE 1-FLUOROPYRIDINIUM TRIFLATE, TECH 三氟甲磺酸 N-吡啶鎓 N-Fluoropyridiniumtrifluoromethanesulphonate99% N-Fluoropyridinium triflate N-FLUOROPYRIDINIUM TRIFLUOROMETHANESULFONATE Pyridinium, 1-fluoro-, salt with trifluoromethanesulfonic acid (1:1) 1-FLUOROPYRIDINIUM TRIFLUOROMETHANESULFONATE 1-FLUOROPYRIDINIUM TRIFLATE N-Fluoropyridinium trifluoromethanesulphonate 99% 1-Fluoropyridinium Triflate [Fluorinating Reagent] 1-Fluoropyridinium·trifluoromethanesulfonic acid anion N-FLUOROPYRIDINIUM TRIFLUOROMETHANESULPHONATE 1-Fluoropyridinium Trifluoromethanesulfonate [Fluorinating Reagent] |
| PubChem Substance ID | 2724576 |
| Beilstein Registry Number | 4222821 |
| Reaxys-RN | 4222821 |
| Chemical Name Translation | 1-氟吡啶三氟甲磺酸盐 |
| InChI | InChI=1S/C5H5FN.CHF3O3S/c6-7-4-2-1-3-5-7;2-1(3,4)8(5,6)7/h1-5H;(H,5,6,7)/q+1;/p-1 |
| LabNetwork Molecule ID | LN01742352 |
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分类
- {SNA} Chemical Synthesis, Fluorination, Fluorination Reagents, Synthetic Reagents
相关文献及参考
- Reagent for electrophilic fluorination:
- Alkyl or silyl enol ethers give ɑ-fluoro ketones: Tetrahedron Lett., 27, 3271, 4465 (1986); Org. Synth. Coll., 8, 286 (1993). For regioselective mono-ɑ-fluorination of steroids bearing several silyl enol ether groups, see: J. Am. Chem. Soc., 112, 8563 (1990).
- For a review of electrophilic N-F fluorinating agents, see: Chem. Rev., 96, 1737 (1996).
安全信息
GHS Symbol
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P301+P330+P331+P310
- P303+P361+P353
- P303+P361+P353+P310+P363
- P304+P340
- P305+P351+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H318 Causes serious eye damage 严重伤害眼睛
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R35 Causes severe burns 会导致严重灼伤
其他信息
- Alfa Aesar:N-氟吡啶三氟甲磺酸盐,95% N-Fluoropyridinium trifluoromethanesulfonate, 95%(107263-95-6)
- Sigma Aldrich:107263-95-6(sigmaaldrich)
- 三氟甲磺酸N-吡啶鎓价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 F0327 1-氟吡啶三氟甲烷磺酸盐[氟化试剂] 1-Fluoropyridinium Trifluoromethanesulfonate [Fluorinating Reagent] 5G 1010元 2011/04/16 F0327 1-氟吡啶三氟甲烷磺酸盐[氟化试剂] 1-Fluoropyridinium Trifluoromethanesulfonate [Fluorinating Reagent] 25G 3520元 2010/06/21 259925000 三氟甲磺酸N-吡啶鎓 N-Fluoropyridinium triflate 95% 500 MG 1225元
- TCI Shanghai:1-氟代吡啶三氟甲烷磺酸盐[氟化试剂] 1-Fluoropyridinium Trifluoromethanesulfonate [Fluorinating Reagent],>;96.0%(T)(107263-95-6)
- Hazard Note:Irritant
- MOL 文件:107263-95-6.mol
- F:10-21
- 敏感性:Moisture Sensitive
- Acros Organics:N-Fluoropyridinium triflate, 95%(107263-95-6)
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