ETHYLMERCURY CHLORIDE 氯化乙基汞

CAS 107-27-7 MFCD00013593

化学结构图

107-27-7
SMILES: CC[Hg]Cl

化学属性

Mol. FormulaC2H5ClHg
Mol. Weight265.11
Melting Point192.5℃
Density3.482
Solubility微溶于水,不溶于冷水,溶于乙醇、乙醚。
TSCANo

别名和识别编码

Chemical NameEthylmercury chloride
MDL NumberMFCD00013593
PubChem Substance ID7862
CAS Number107-27-7
EC Number203-478-0
Synonym {uni_hamburg} chloroethyl-mercur emcond 氯化乙基汞 CERESAN(R) 氯化汞乙酯 Chloroethylmercury Ethylmercury chloride ETHYL MERCURIC CHLORIDE, 250MG, NEAT Monoethylmercury chloride Ethylquecksilberchlorid Emcon D Mercury,chloroethyl- Criptodin Äthylenquecksilberchlorid Cryptodine 乙基氯化汞 Mercuric ethyl chloride EMC Granosan ETHYLMERCURY(II) CHLORIDE Ceresan 西力生 Ethylmercuric chloride Chlorethylquecksilber C2H5HgCl Ganozan CHLOROETHYLMERCURY Ethyl mercuric chloride Granozan ETHYLMERCURY CHLORIDE MERCURY (II) ETHYL CHLORIDE Mercury, chloroethyl- ETHYLMERCURIC CHLORIDE Ethylmerkurichlorid Ceresan (fungicide) Cryptodin
Merck Number14,3826
Chemical Name Translation氯化乙基汞
Wiswesser Line NotationG-HG-2
Beilstein Registry Number4123092
InChIInChI=1S/C2H5.ClH.Hg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1
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分类

  • Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chemical Synthesis, Chromatography, E, E-G, EQ - EZ, Environmental Standards, Fungicides, Mercury compounds, Organomercury, Organometallic Reagents, Pesticides, Pesticides & Metabolites
  • {uni_hamburg} no charge; metal-organic; 1fragment

产品应用

  • 在农业上曾是一种重要杀菌剂,有剧毒,易导致公害

相关文献及参考

  • Short: III/35C4
  • Short: III/35D5
  • Merck:14,3826

安全信息

Hazard statements
  • H330 Fatal if inhaled 吸入致命
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H310 Fatal in contact with skin 皮肤接触致命
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H300 Fatal if swallowed 吞食致命
RTECSOV9800000
GHS Symbol
Signal word Danger
Hazard Codes T+,N
WGK Germany3
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Safety Statements
  • S13 Keep away from food, drink and animal foodstuffs 远离食品、饮料和动物饲料保存;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
UN Number 2025 UN2025
Risk Statements
  • R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有剧毒
  • R50/53
  • R33 Danger of cumulative effects 有累积作用的危险
Packing GroupII
Hazard Class6.1
Restrict 剧毒化学品
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 16 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   OCRAAH Organometallic Chemistry Reviews, Section A: Subject Reviews.
   (Lausanne, Switzerland)  V.3-8, 1968-72.  For publisher information, see
   JORCAI.  Volume(issue)/page/year: 3,137,1968

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TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PHJOAV Pharmaceutical Journal.  (Pharmaceutical Soc. of Great Britain, 1
   Lambeth High St., London, SE1 7JN, UK)  V.131-    1933-
   Volume(issue)/page/year: 185,361,1960

TYPE OF TEST

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 5 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,1199,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 40 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TAGTBR Trudy Azerbaidzhanskogo Nauchno-Issledovatel'skogo Instituta Gigieny
   Truda i Professional'nykh Zabolevanii.  Transactions of the Azerbaidzhan
   Scientific Research Institute of Labor Hygiene and Occupational Diseases.

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Inhalation
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 100 ppm
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 53,219,1978

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 2500 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 290,281,1993

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - E

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Unreported
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 920 ug/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 53,219,1978

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 3 mmol/L
REFERENCE :
   MJDHDW Mukogawa Joshi Daigaku Kiyo, Shokumotsu-hen.  Bulletin of Mukogawa
   Women's University, Food Science Series.  (Mukogawa Joshi Daigaku, 6-46,
   Ikebiraki-cho, Nishinomiya, Hyogo-ken, Japan) No.19-    1972-
   Volume(issue)/page/year: 28,F39,1980

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Human HeLa cell
DOSE/DURATION           : 1 mg/L
REFERENCE :
   JJEMAG Japanese Journal of Experimental Medicine.  (Kinokuniya Book-Stores
   of America Co., Ltd., West Bldg., Japan Cultural and Trade Center, 1581
   Webster St., San Francisco, CA 94115) V.7-    1928- Volume(issue)/page/year:
   39,47,1969

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 5600 ug/kg
SEX/DURATION            : male 28 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - growth statistics (e.g.%, reduced weight
   gain)
REFERENCE :
   TIVSAI Trudy, VNIIVS.  Transactions of the All-Union Scientific Research
   Institute of Veterinary Sanitation.  (VNIIVS, Moscow, USSR)  V.11-    1957-
   Volume(issue)/page/year: 46,157,1973

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 9 mg/kg
SEX/DURATION            : female 14 day(s) pre-mating
                          female 1-22 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Fertility - pre-implantation mortality (e.g. reduction in
   number of implants per female; total number of implants per corpora lutea)
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   TIVSAI Trudy, VNIIVS.  Transactions of the All-Union Scientific Research
   Institute of Veterinary Sanitation.  (VNIIVS, Moscow, USSR)  V.11-    1957-
   Volume(issue)/page/year: 46,157,1973

其他信息

  • 可燃性危险特性:遇明火、高热可燃; 遇光或热分解有毒含汞化物气体
  • 灭火剂:水、泡沫、砂土、二氧化碳
  • 外观性质:白、黄、灰、棕色粉末或结晶, 遇热有挥发性, 遇光易分解。
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类、食品添加剂分开存放
  • MSDS 信息:氯化乙基汞(107-27-7).msds
  • 类别:农药
  • 毒性分级:剧毒
  • MOL 文件:107-27-7.mol
  • 白色有光泽的叶片状晶体,能升华,不溶于水,微溶于乙醚,稍溶于冷乙醇、油和其他有机溶剂,溶于热乙醇和10%氢氧化内溶液,遇日光分解 熔点:192.5℃
  • Alfa Aesar:氯化乙基汞 Ethylmercury chloride(107-27-7)
  • 能升华,不溶于水,微溶于乙醚,稍溶于冷乙醇、油和其他有机溶剂,溶于热乙醇和10%氢氧化内溶液,遇日光分解
  • 爆炸物危险特性:0
  • 刺激数据:眼- 兔子 0.05 毫克/ 24小时 重度
  • 图谱信息:氯化乙基汞(107-27-7)Raman光谱 氯化乙基汞(107-27-7)红外图谱(IR1) 氯化乙基汞(107-27-7)红外图谱(IR2)
  • Sigma Aldrich:107-27-7(sigmaaldrich)
  • 职业标准:TWA 0.01 毫克 (汞)/立方米; STEL 0.03 毫克 (汞)/立方米
  • 急性毒性:口服-大鼠 LD50: 40 毫克/公斤; 口服-小鼠 LD50: 56 毫克/公斤

系列性分类


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