Ethyldichlorophosphine Ethyldichlorophosphine,
CAS 1498-40-4 MFCD00013617
化学结构图
SMILES: CCP(Cl)Cl
化学属性
| Mol. Formula | C2H5Cl2P |
|---|---|
| Mol. Weight | 130.94 |
| Refractive index | n20/D 1.495(lit.) |
| Boiling Point | 112 °C(lit.) |
| Density | 1.26 g/mL at 25 °C(lit.) |
| Flash Point | 91°F |
| Appearance | colorless liq. |
| Stability | air sensitive, moisture sensitive |
别名和识别编码
| Chemical Name | 98% |
|---|---|
| Synonym | {uni_hamburg} 二氯化乙膦 Dichlor-ethylfosfin Ethylphosphonigsäuredichlorid Phosphine, dichloroethyl- Dichlor-ethylphosphin dichloro(ethyl)phosphine Ethyldichlorophosphine Ethylphosphonous dichloride Dichlor(ethyl)phosphan Dichloroethylphosphine TL 373 ethylphosphinyl dichloride dichloroethylphosphane Ethyl phosphonous dichloride Phosphonous dichloride, ethyl- dichloroethyl-phosphine dichloroethylphosphine Ethyl dichlorophosphine ethylphosphinous acid dichloride ethyl-dichloro-phosphine Ethylphosphorus dichloride |
| MDL Number | MFCD00013617 |
| CAS Number | 1498-40-4 |
| PubChem Substance ID | 15157 |
| EC Number | 216-096-4 |
| Chemical Name Translation | Ethyldichlorophosphine, |
| Wiswesser Line Notation | GPG2 |
| Beilstein Registry Number | 0906709 |
| InChIKey | JHNJGLVSPIMBLD-UHFFFAOYSA-N |
| InChI | InChI=1S/C2H5Cl2P/c1-2-5(3)4/h2H2,1H3 |
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分类
- {uni_hamburg} no charge; 1fragment
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphorus Precursors
相关文献及参考
- Short: II/25B Title: Structure Data Of Free Polyatomic Molecules: Molecules containing One or Two Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25B Year: 1999 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-63645-5 ISBN: 978-3-540-63645-8 Internet Resource: DOI:10.1007/b68834 RefComment: IX, 512 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
- Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
- Short: III/31a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D .
安全信息
GHS Symbol
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P222 Do not allow contact with air. 不要与空气接触。
- P231 Handle under inert gas. 在惰性气体中操作。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P242 Use only non-sparking tools. 只能使用无火花工具。
- P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P302+P334
- P302+P335+P334
- P302+P361+P354
- P303+P361+P353
- P304+P340
- P305+P351+P338
- P305+P354+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P316
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P370+P378
- P403+P235
- P405 Store locked up. 上锁保管。
- P422 Store contents under… 存储目录在…之下。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
- S6 Keep under ... (inert gas to be specified by the manufacturer) 将该物质保存在生产厂家指定的惰性气体中；
- R14 Reacts violently with water 遇水会猛烈反应
- R17 Spontaneously flammable in air 在空气中能够自燃
- R34 Causes burns 会导致灼伤
TYPE OF TEST : LCLo - Lowest published lethal concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 1990 mg/m3/10M TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NDRC** National Defense Research Committee, Office of Scientific Research and Development, Progress Report. Volume(issue)/page/year: NDCrc-132,SEP1942
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