Diphenylacetyl Chloride 二苯基乙酰氯

CAS 1871-76-7 MFCD00013655

化学结构图

1871-76-7
SMILES: O=C(Cl)C(c1ccccc1)c1ccccc1

化学属性

Mol. FormulaC14H11ClO
Mol. Weight230.69
Melting Point51.0 to 55.0 deg-C
TSCANo
Boiling Point175-176 °C/17 mmHg(lit.)
Flash Point>110 ºC

别名和识别编码

Chemical NameDiphenylacetyl Chloride
MDL NumberMFCD00013655
CAS Number1871-76-7
EC Number217-493-5
Merck Number14,3316
Beilstein Registry Number9(3)3300
PubChem Substance ID74637
Synonym 2,2-DIPHENYLACETYL CHLORIDE 2,2-Diphenylacetyl chloride 2,2-diphenylacetylchloride Acetyl chloride, diphenyl- Benzeneacetyl chloride, alpha-phenyl- DIPHENYLACETYL CHLORIDE DIPHENYLACETYL CHLORIDE, TECH., 90% DPAC Diphenylacetic acid chloride Diphenylacetyl Diphenylacetyl Chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Alfabeta NameDIPHENYLACETYLCHLORIDE
Reaxys-RN1211588
Chemical Name Translation二苯基乙酰氯
Wiswesser Line NotationGVYR&R
LabNetwork Molecule IDLN00183582
InChIInChI=1S/C14H11ClO/c15-14(16)13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,13H
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分类

  • {SNA} Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks

相关文献及参考

  • Sugars have been protected as diphenylacetyl (DPA) esters by reaction with the acid chloride in pyridine. Removal was by photobromination with NBS and reaction with thiourea: Synthesis, 97 (1994).
  • Precursor of diphenylketene by dehydrohalogenation with triethylamine: Org. Synth. Coll., 6, 549 (1988). Compare Benzil monohydrazone, A18457.

安全信息

RTECSAO6750000
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
Packing GroupIII
UN Number UN 3261 8/PG 2 UN3261 3261
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
Storage condition +4°C 4℃ Moisture Sensitive
GHS Symbol
WGK Germany2
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Precautionary statements
  • P303+P361+P353+P310+P363
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P405 Store locked up. 上锁保管。
  • P304+P340
  • P303+P361+P353
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
Signal word Danger
Hazard Codes C
Warnings IRRITANT
Hazard Class8 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 4700 mg/kg
TOXIC EFFECTS :
   Behavioral - changes in motor activity (specific assay)
   Behavioral - ataxia
REFERENCE :
   GNAMAP Gigiena Naselennykh Mest.  Hygiene in Populated Places. (Izdatel'stvo
   Zdorov'ya, Kiev, USSR) V.7-    1967- Volume(issue)/page/year: 17,48,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 6330 mg/kg
TOXIC EFFECTS :
   Behavioral - changes in motor activity (specific assay)
   Behavioral - ataxia
REFERENCE :
   GNAMAP Gigiena Naselennykh Mest.  Hygiene in Populated Places. (Izdatel'stvo
   Zdorov'ya, Kiev, USSR) V.7-    1967- Volume(issue)/page/year: 17,48,1978

其他信息

  • 海关编码:29163900
  • Sigma Aldrich:1871-76-7(sigmaaldrich)
  • MOL 文件:1871-76-7.mol
  • 二苯基乙酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 L0017102 二苯乙酰氯，98+％ 50g 1764元 2011/04/16 D2763 二苯基乙酰氯 Diphenylacetyl Chloride 5G 378元 2011/04/16 D2763 二苯基乙酰氯 Diphenylacetyl Chloride 25G 1130元
  • MSDS 信息:Diphenylacetyl chloride(1871-76-7).msds
  • 下游产品:双苯酰草胺
  • 敏感性:Moisture Sensitive
  • TCI Shanghai:二苯基乙酰氯 Diphenylacetyl Chloride,>;98.0%(GC)(T)(1871-76-7)
  • Acros Organics:二苯基乙酰氯 Diphenylacetylchloride, 97.50%(1871-76-7)
  • Alfa Aesar:二苯基乙酰氯,90+% Diphenylacetyl chloride, 90+%(1871-76-7)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Acid Halides 酸性卤化物(酰氯等)
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Acid Halides 酸性卤化物(酰氯等)
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Aryl 芳基卤代烃
  1. Acyl halide
  2. acyl chloride

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